Abstract:
Processes which include: (a) providing a gas phase comprising hydrogen chloride; (b) oxidizing the hydrogen chloride in a reactor to form a product gas comprising chlorine, unreacted hydrogen chloride and water, the reactor having structural parts with inner surfaces that are contacted during oxidation by one or both of the gas phase and the product gas; (c) cooling the process gas; (d) separating the unreacted hydrogen chloride and water from the product gas; (e) drying the product gas; and (f) separating the chlorine from the product gas; wherein the inner surfaces of the reactor structural parts that are contacted during oxidation by one or both of the gas phase and the product gas are comprised of a nickel material having a nickel content of at least 60 wt. %, are described.
Abstract:
A method for joining clad metal plates having a protective layer (27), e.g. titanium, and a substrate layer (28), e.g. carbon steel, includes firstly removing margins (29) of protective layer along edges of the clad metal plates to be joined. The substrate layers are then welded together to form an exposed substrate weld (31). Covering material (38) of the same type as the protective layer (27) is then located along the exposed substrate weld (31) to a level substantially flush with an outer surface of the protective layer (27). The substrate layer (28) is heated prior to welding the covering material so that the covering material is pre-stressed when cooled. The method may be used to fabricate reaction vessels having seams that do not stand proud of the remainder of the interior surface of the vessel. The low profile seams are less susceptible to erosion than has been the case in the past so that longer-life vessels can be produced. The invention encompasses vessels such as autoclaves, crucibles and reaction vessels formed of clad plate joined by the method.
Abstract:
A method for manufacturing an ultrahard compact includes assembling a mass of ultrahard material with a mass of substrate material such that the mass of ultrahard material extends radially outward a greater extent than the substrate material to compensate for a difference in the radial shrinkage of the ultrahard material compared to the substrate material during a sintering process. The method may further includes subjecting the assembled compact to a high pressure high temperature process that results in the forming of an ultrahard compact including an ultrahard layer integrally bonded with a substrate.
Abstract:
It is to propose an internal member for a plasma treating vessel having excellent resistances to chemical corrosion and plasma erosion under an environment containing a halogen gas and an advantageous method of producing the same, which is a member formed by covering a surface of a substrate with a multilayer composite layer consisting of a metal coating formed as an undercoat, Al2O3 film formed on the undercoat as a middle layer and Y2O3 sprayed coating formed on the middle layer as a top coat.
Abstract:
The present invention provides a novel process for preparing hydrogenated nitrile rubbers comprising subjecting nitrile rubbers in a spinning disk reactor to hydrogenation. The present process is less demanding with regard to its reaction conditions, like e.g. the hydrogen pressure to be applied, compared to known processes and significantly reduces the cost of the hydrogenation process and in particular the equipment cost.
Abstract:
It is disclosed a process for the production of titanium dioxide comprising the following steps: (a) a titanium ore containing iron, preferably ilmenite, is reacted with an aqueous NH4F solution; (b) the aqueous suspension thus obtained is filtered with consequent separation of a sludge fraction, which contains ammonium fluoroferrates, and a filtrate fraction, which contains ammonium fluorotitanates; (c) the filtrate fraction thus obtained is subjected to an hydrolysis reaction; (d) the thus-obtained solid component is subjected to a thermal hydrolysis reaction. The plant and the reactors for performing the above process are also disclosed.
Abstract:
An electromagnetic susceptor for chemical processing having a matrix material that surrounds a non-matrix material that is made from a material that is different from the matrix material, the matrix material is constructed of a sintered ceramic material having lower dielectric losses compared to the non-matrix material, the non-matrix material initially absorbs electromagnetic energy applied to the electromagnetic susceptor to a greater extent than the matrix material, and the non-matrix material produces subsequent heat in the matrix material.
Abstract:
Fluorine generation systems are provided that can include, in exemplary embodiments, a reactor configured to decompose a fluorine-comprising material. The reactor can include a plurality of chambers with at least one of the chambers being configured to receive the fluorine-comprising material. The chamber includes sidewalls with the exterior of the sidewalls being at least partially encompassed by heating elements. The system can also include a fluorine reservoir coupled to the reactor with the reservoir configured to receive fluorine upon the decomposition of the fluorine-comprising materials. Fluorine-generation processes are provided that can include, in exemplary embodiments, decomposing pellets of a fluorine-comprising material with the pellets having an average size of from about 1.0 mm to about 3.0 mm. Processes can also include decomposing a composition comprising manganese-fluoride.
Abstract:
The invention relates to a method of protecting equipment intended to operate at high temperature in the presence of a fluid containing at least one hydrocarbon and/or carbon monoxide against corrosion by metal dusting, method in which pieces of the equipment are made from an alloy containing nickel, iron, chromium and/or aluminum, and in which said pieces of the equipment are protected from said corrosion by a protective coating. This method is characterized in that said equipment pieces protected in this way are connected to each other by means of joining pieces, said joining pieces being protected beforehand by a protective coating over at least part of their surface intended to be brought into contact with said fluid at high temperature, and in that each of the connections intended to be subjected to said corrosion is produced by external welding of the ends of the joining piece with said pieces of equipment.
Abstract:
A coated susceptor of electromagnetic energy for chemical processing made of a matrix material that surrounds a non-matrix material that is made from a material that is different from the matrix material, in which the matrix material is constructed of material having lower dielectric losses compared to the non-matrix material, the non-matrix material initially absorbs electromagnetic energy applied to the electromagnetic susceptor to a greater extent than the matrix material, the non-matrix material produces subsequent heat in the matrix material, and the surface of the susceptor is coated with a material that interacts with applied electromagnetic energy of at least one frequency and initially absorbs electromagnetic energy and produces heat.