PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORK MATERIALS
    43.
    发明申请
    PROCESS FOR PREPARING POROUS METAL-ORGANIC FRAMEWORK MATERIALS 有权
    制备多孔金属有机框架材料的方法

    公开(公告)号:US20120091064A1

    公开(公告)日:2012-04-19

    申请号:US13336396

    申请日:2011-12-23

    CPC classification number: C07C51/418 C07C63/307

    Abstract: The present invention relates to a method for producing a porous metal-organic framework material comprising the stepreacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

    Abstract translation: 本发明涉及多孔金属 - 有机骨架材料的制造方法,该方法包括使具有至少一种至少二齿的有机化合物的至少一种铜化合物的液相中的反应混合物反应,该有机化合物可通过配位与 铜在非水溶剂的存在下,所述至少一种至少二齿的有机化合物衍生自具有至少三个羧基的多元羧酸,并且所述反应在大气压下高于80℃进行。

    Copper Containing ZSM-34, OFF And/Or ERI Zeolitic Material For Selective Reduction Of NOx
    44.
    发明申请
    Copper Containing ZSM-34, OFF And/Or ERI Zeolitic Material For Selective Reduction Of NOx 审中-公开
    含有ZSM-34,OFF和/或ERI沸石材料用于选择性还原NOx的铜

    公开(公告)号:US20120014866A1

    公开(公告)日:2012-01-19

    申请号:US13183616

    申请日:2011-07-15

    Abstract: Described is a copper containing ZSM-34, OFF and/or ERI zeolitic material having a silica to alumina mole ratio ranging from about 4 to about 50 and a copper content, reported as CuO, ranging from about 1 to about 10 wt.-%, based on the total weight of the calcined zeolitic material, and having an alkali metal content, reported as the metal oxide, ranging from about 0.7 to about 1.5 wt.-%, wherein the 750° C.-aged copper containing ZSM-34, OFF and/or ERI zeolitic material exhibits NO conversion at 200° C. of at least about 75% and at 450° C. of at least about 90%, measured at a gas hourly volume based space velocity of 30000 h−1 under steady state conditions at maximum NH3-slip conditions in a gas mixture of 500 ppm NO, 500 ppm NH3, 10% O2, 5% H2O, balance N2.

    Abstract translation: 描述了一种含有ZSM-34,OFF和/或ERI沸石材料,其二氧化硅与氧化铝的摩尔比为约4至约50,铜含量为CuO,为约1至约10重量% ,基于煅烧的沸石材料的总重量,并且具有报告为金属氧化物的碱金属含量为约0.7至约1.5重量%,其中750℃的含有ZSM-34的老化铜 ,OFF和/或ERI沸石材料在200℃下表现出至少约75%至450℃的NO转化率为至少约90%,其以基于时间的体积空间速度为30000h -1测量, 在500ppm NO,500ppm NH 3,10%O 2,5%H 2 O,余量N 2的气体混合物中最大NH3滑移条件下的稳态条件。

    Closing system for motor vehicles
    47.
    发明授权
    Closing system for motor vehicles 有权
    汽车关闭系统

    公开(公告)号:US08053922B2

    公开(公告)日:2011-11-08

    申请号:US10451182

    申请日:2001-11-28

    Applicant: Ulrich Müller

    Inventor: Ulrich Müller

    Abstract: The invention relates to a closing system for motor vehicles involving access authorization and driving authorization by means of a control unit provided with means of communication. Said communication means comprise a stationary transmitter-receiver unit in the vehicle and a mobile transmitter-receiver unit in a wireless hand telephone (10). The control unit monitors the data transferred during said communication for access or driving authorization and activates or deactivates the corresponding systems if authorization is valid. The hand telephone (10) contains an SIM card (15) for telephonic network operation. In order to use the closing system in a quick and comfortable manner, the SIM card (15) is also a carrier for the access and driving authorization data. (16). A bi-directional local communication hands-free system operating in the GHz range is also used in the motor vehicle. Said telephonic local communication is also used for transmitting access and/or driving authorization data (16).

    Abstract translation: 本发明涉及一种机动车辆的关闭系统,其涉及通过具有通信手段的控制单元进行访问授权和驾驶授权。 所述通信装置包括车辆中的固定发射机 - 接收机单元和无线手机电话机(10)中的移动发射机 - 接收机单元。 控制单元监视在所述通信期间传送的数据以进行访问或驾驶授权,如果授权有效,则激活或停用对应的系统。 手机(10)包含用于电话网络操作的SIM卡(15)。 为了以快速舒适的方式使用关闭系统,SIM卡(15)也是访问和驾驶授权数据的载体。 (16)。 在机动车辆中也使用在GHz范围内工作的双向本地通信免提系统。 所述电话本地通信也用于发送接入和/或驾驶授权数据(16)。

    PROCESS FOR THE PREPARATION OF ZEOLITES HAVING B-CHA STRUCTURE
    49.
    发明申请
    PROCESS FOR THE PREPARATION OF ZEOLITES HAVING B-CHA STRUCTURE 有权
    制备具有B-CHA结构的沸石的方法

    公开(公告)号:US20110142755A1

    公开(公告)日:2011-06-16

    申请号:US12950137

    申请日:2010-11-19

    Abstract: The present invention relates to a process for the preparation of zeolites having B-CHA framework structure and a composition comprising the molar ratio (n SiO2):B2O3, wherein n is at least 10, the process comprising (i) preparation of an aqueous solution containing at least one source for B2O3, at least one source for SiO2, at least one source of seeding crystals of chabazite structure, at least one organic structure directing agent (SDA) other than Tetramethylammonium hydroxide (TMAOH), acting as a template for the B-CHA structure, and Tetramethylammonium hydroxide (TMAOH), wherein the SDA or mixtures thereof are employed in such amounts that the aqueous solution in (i) exhibits a molar ratio of SDA:TMAOH of 0.01 to 5; (ii) hydrothermal crystallization of the aqueous solution according to (i); wherein the ratio of the [molar ratio (SiO2:B2O3)] of the gel composition:[molar ratio (SiO2:B2O3)] of the crystalline product having the chabazite structure is greater than 0.5. The present invention also relates to the zeolitic materials obtainable and/or obtained by this process as well as to a zeolitic material as such, having framework structure B-CHA, having a composition comprising the molar ratio (n SiO2):B2O3, wherein n is at least 10, and wherein the ratio of the [molar ratio (SiO2:B2O3)] of the gel composition:[molar ratio (SiO2:B2O3)] of the crystalline product having the chabazite structure is greater than 0.5.

    Abstract translation: 本发明涉及一种制备具有B-CHA骨架结构的沸石和包含摩尔比(n SiO 2):B 2 O 3,其中n至少为10的组合物的方法,该方法包括(i)制备水溶液 含有至少一种B 2 O 3源,至少一种SiO 2源,至少一种菱沸石结晶晶体源,至少一种除氢氧化四甲基铵(TMAOH)以外的有机结构导向剂(SDA),作为 B-CHA结构和四甲基氢氧化铵(TMAOH),其中SDA或其混合物的用量使得(i)中的水溶液的SDA:TMAOH的摩尔比为0.01至5; (ii)根据(i)的水溶液的水热结晶; 其中具有菱沸石结构的结晶产物的凝胶组成:[摩尔比(SiO 2 :B 2 O 3)]的[摩尔比(SiO 2 :B 2 O 3)]的比率大于0.5。 本发明还涉及通过该方法获得和/或获得的沸石材料以及具有骨架结构B-CHA的沸石材料,其具有包含摩尔比(n SiO 2):B 2 O 3的组成,其中n 为至少10,并且其中具有菱沸石结构的结晶产物的凝胶组成:[摩尔比(SiO 2 :B 2 O 3)]的[摩尔比(SiO 2 :B 2 O 3)]的比率大于0.5。

Patent Agency Ranking