公开(公告)号：US4777268A

公开(公告)日：1988-10-11

申请号：US26426

申请日：1987-03-16

Applicant: Pochen Chu ,  Larry A. Green ,  Michael E. Landis

Inventor： Pochen Chu ,  Larry A. Green ,  Michael E. Landis

IPC: C07C2/08 ,  C07C2/10 ,  C07D307/89

CPC classification number: C07C2/10 ,  C07C2/08 ,  C01P2002/02 ,  C01P2002/22 ,  C01P2002/70 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/78 ,  C01P2006/12 ,  C01P2006/42 ,  C01P2006/80 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/12

Abstract: A process and catalyst are disclosed for selectively oxidizing alkylaromatics, e.g., o-xylene, to oxygenated aromatics, e.g., phthalic anhydride. The catalyst of the process comprises a layered titanate which contains interspathic polymeric silica and a heavy metal element, e.g., vanadium.

Abstract translation: 公开了一种方法和催化剂，用于将烷基芳族化合物例如邻二甲苯氧化成氧化芳族化合物，例如邻苯二甲酸酐。 该方法的催化剂包括层状钛酸盐，其含有间质聚合物二氧化硅和重金属元素，例如钒。

公开(公告)号：US4740649A

公开(公告)日：1988-04-26

申请号：US1134

申请日：1987-01-07

Applicant: Pochen Chu ,  William E. Garwood

Inventor： Pochen Chu ,  William E. Garwood

IPC: B01J29/40 ,  B01J29/80 ,  C07C2/12 ,  C10G11/05 ,  C07C2/68

CPC classification number: C07C2/12 ,  B01J29/40 ,  C10G11/05 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/80 ,  C07C2529/40

Abstract: Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.

Abstract translation: 包含芳族化合物的原料通过异构化，烷基化，歧化或烷基转移转化为含有芳族化合物的产物，其与原料相比，催化剂不同于通过在水存在下使高硅沸石与酸性无机氧化物反应而制备。

公开(公告)号：US4665253A

公开(公告)日：1987-05-12

申请号：US792346

申请日：1985-10-29

Applicant: Pochen Chu ,  William E. Garwood

Inventor： Pochen Chu ,  William E. Garwood

IPC: B01J29/40 ,  B01J29/80 ,  C07C2/12 ,  C10G11/05 ,  C07C2/68 ,  C07C5/22

CPC classification number: C07C2/12 ,  B01J29/40 ,  C10G11/05 ,  B01J2229/26 ,  B01J2229/36 ,  B01J2229/42 ,  B01J29/80 ,  C07C2529/40

Abstract: Feedstock comprising aromatic compounds is converted by isomerization, alkylation, disproportionation or transalkylation to product comprising aromatic compounds which differs from the feedstock over catalyst having been prepared by reacting a high-silica zeolite with an acidic inorganic oxide in the presence of water.

公开(公告)号：US4606901A

公开(公告)日：1986-08-19

申请号：US805491

申请日：1985-12-05

Applicant: Pochen Chu ,  Albin Huss, Jr. ,  James C. Vartuli

Inventor： Pochen Chu ,  Albin Huss, Jr. ,  James C. Vartuli

IPC: C01B39/02 ,  C01B33/28

CPC classification number: C01B33/2876 ,  Y10S423/22 ,  Y10S423/29

Abstract: Agglomerated crystalline zeolites are deagglomerated by treating the zeolite during its formation or shortly thereafter. The particles are contacted with additional basic solution when crystallization is near completion to effect deagglomeration.

Abstract translation: 聚集的结晶沸石通过在其形成期间或之后不久处理沸石而被解团聚。 当结晶接近完成时，颗粒与附加的碱性溶液接触以实现解聚。

公开(公告)号：US4605787A

公开(公告)日：1986-08-12

申请号：US742375

申请日：1985-06-10

Applicant: Pochen Chu ,  Guenter H. Kuehl

Inventor： Pochen Chu ,  Guenter H. Kuehl

IPC: C07C41/06 ,  C07C41/36 ,  C07C41/05

CPC classification number: C07C41/36 ,  C07C41/06

Abstract: Process for the preparation of alkyl tert-alkyl ethers which comprises reacting a primary alcohol with an olefin having a double bond on a tertiary carbon atom in the presence of an acidic zeolite catalyst. Removal of any excess alcohol from the reaction product is accomplished by passing the reaction product through a bed of small pore zeolite.

Abstract translation: 烷基叔烷基醚的制备方法，其包括在酸性沸石催化剂存在下使伯醇与叔碳原子上具有双键的烯烃反应。 通过使反应产物通过小孔沸石床来实现从反应产物中除去过量的醇。

公开(公告)号：US4601993A

公开(公告)日：1986-07-22

申请号：US661632

申请日：1984-10-17

Applicant: Pochen Chu ,  Jeffrey H. Yen

Inventor： Pochen Chu ,  Jeffrey H. Yen

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/80 ,  C10G45/64 ,  C10G73/02 ,  B01J29/32

CPC classification number: C10G45/64 ,  B01J29/80

Abstract: Hydrocarbon lubricating oil feedstocks are dewaxed by passing the waxy feedstock over a catalyst bed containing a mixture of medium pore zeolite and large pore zeolite catalysts havig a Constraint Index less than 2 and having hydroisomerization activity in the presence of a hydrogenation component.

Abstract translation: 通过将含蜡原料通过含有中等孔沸石和大孔沸石催化剂的混合物的催化剂床，使烃润滑油原料脱蜡，达到小于2的约束指数，并且在氢化组分存在下具有加氢异构化活性。

公开(公告)号：US4526879A

公开(公告)日：1985-07-02

申请号：US520746

申请日：1983-08-05

Applicant: Francis G. Dwyer ,  Pochen Chu

Inventor： Francis G. Dwyer ,  Pochen Chu

IPC: B01J29/40 ,  C01B39/40 ,  C01B33/28

CPC classification number: C01B39/40 ,  B01J29/40 ,  B01J2229/26 ,  B01J2229/42 ,  Y10S423/22

Abstract: As synthesized by conventional technique, zeolite ZSM-5 is crystallized in the presence of substantial amount of tetraalkylammonium cations, the alkyl groups of which contain 2 to 5 carbon atoms, such as, for example, tetrapropylammonium. When synthesized in the conventional way, ZSM-5 contains tetraalkylammonium cations as well as a substantial amount of sodium ions. To obtain a more catalytically active form of ZSM-5, the sodium ions must be exchanged to very low levels. By synthesizing zeolite ZSM-5 according to the present method, i.e., in the presence of a combination of an amine and a halide in the presence of a mutual solvent and with a specifically defined reaction mixture composition, ZSM-5 having different organic nitrogen-containing cations but the same crystal structure as conventionally prepared ZSM-5 is obtained. The ZSM-5 prepared in accordance herewith is very low in sodium content as synthesized and has a crystal size of from about 0.05 microns to about 20 microns.

Abstract translation: 如通过常规技术合成的，沸石ZSM-5在存在大量四烷基铵阳离子（其烷基含有2至5个碳原子的四烷基铵阳离子）存在下结晶，例如四丙基铵。 当以常规方式合成时，ZSM-5含有四烷基铵阳离子以及大量的钠离子。 为了获得更具催化活性的ZSM-5形式，钠离子必须交换到非常低的水平。 通过根据本发明的方法合成沸石ZSM-5，即在相互溶剂存在下，在胺和卤化物的组合存在下，与特定定义的反应混合物组合物，具有不同有机氮气的ZSM-5， 得到与常规制备的ZSM-5相同的晶体结构。 根据本文制备的ZSM-5的钠含量非常低，并且具有约0.05微米至约20微米的晶体尺寸。

公开(公告)号：US4513092A

公开(公告)日：1985-04-23

申请号：US594583

申请日：1984-03-29

Applicant: Pochen Chu ,  Francis G. Dwyer

Inventor： Pochen Chu ,  Francis G. Dwyer

IPC: C07C1/26 ,  B01J29/76 ,  B01J37/04 ,  C07B61/00 ,  C07C1/00 ,  C07C17/00 ,  C07C17/10 ,  C07C17/152 ,  C07C17/154 ,  C07C67/00 ,  B01J29/30

CPC classification number: B01J37/04 ,  C07C17/10 ,  C07C17/152

Abstract: A dual-function chlorination-condensation catalyst composition consisting essentially of (a) Deacon-type catalyst comprising cupric halide, alkaline earth halide and/or alkali metal halide, and/or rare earth metal halide and (b) crystalline aluminosilicate zeolite catalyst, such as ZSM-5 type.

Abstract translation: 一种双功能氯化 - 缩合催化剂组合物，主要由（a）包含卤化铜，碱土金属卤化物和/或碱金属卤化物和/或稀土金属卤化物和（b）结晶硅铝酸盐沸石催化剂的Deacon型催化剂组成， 作为ZSM-5型。

公开(公告)号：US4481173A

公开(公告)日：1984-11-06

申请号：US443497

申请日：1982-11-22

Applicant: Pochen Chu

Inventor： Pochen Chu

IPC: C10G11/02 ,  B01J29/035 ,  B01J29/04 ,  B01J29/40 ,  C01B37/02 ,  C01B39/04 ,  C01B39/06 ,  C01B39/36 ,  C01B39/42 ,  C07C1/00 ,  C07C2/12 ,  C07C2/66 ,  C07C2/76 ,  C07C2/86 ,  C07C5/27 ,  C07C5/41 ,  C07C6/12 ,  C07C15/00 ,  C07C15/02 ,  C07C67/00 ,  C10G11/00 ,  C10G47/16 ,  C01B33/28

CPC classification number: B01J29/40 ,  C01B37/02 ,  C01B39/365 ,  Y10S423/29

Abstract: The alkali metal content of zeolite ZSM-11 in its as-synthesized form is reduced by crystallizing the zeolite from a solution containing a source of benzyltrimethyl ammonium ions.

Abstract translation: 通过从含有苄基三甲基铵离子源的溶液中使沸石结晶来降低其合成形式的沸石ZSM-11的碱金属含量。

公开(公告)号：US4410452A

公开(公告)日：1983-10-18

申请号：US375078

申请日：1982-05-05

Applicant: Pochen Chu ,  Francis G. Dwyer ,  Albin Huss

Inventor： Pochen Chu ,  Francis G. Dwyer ,  Albin Huss

IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  B01J37/06 ,  B01J29/06 ,  B01J29/28

CPC classification number: B01J29/40 ,  B01J37/06 ,  B01J2229/26 ,  B01J2229/42 ,  B01J29/65 ,  B01J29/70

Abstract: A method of removing the organic cation from an organic cation-containing zeolite which comprises contacting the zeolite at low temperatures with an aqueous sodium hypochlorite solution.

Abstract translation: 一种从含有机阳离子的沸石中除去有机阳离子的方法，其包括在低温下使沸石与次氯酸钠水溶液接触。