Abstract:
A process for the production of stable, agglomerate-free, low viscosity graft copolymer dispersions through radical polymerization of ethylenically unsaturated monomers in the presence of a base polyol, a macromer, an enol ether of a specific formula, and optionally, an organic solvent. These enol ethers correspond to the general formula:A=CH--O--Rwherein:A represents a di-valent residue of the formula ##STR1## R represents an aliphatic hydrocarbon radical having 1 to 18 carbon atoms, a cycloaliphatic hydrocarbon radical having 5 to 10 carbon atoms, or a substituted or unsubstituted benzyl radical;andR' represents a hydrogen atom or an aliphatic hydrocarbon radical having 1 to 8 carbon atoms.
Abstract:
Liquid bromine-containing alkoxylation products of butyne-(1,4)-diol which are storage stable are produced. More specifically, 1.5 to 2.5 mols alkylene oxide are reacted with each mol of butyne-(1,4)-diol present at elevated temperature in the presence of a catalyst. The catalyst is selected from (1) thioethers having a molecular weight of up to 5000 obtained by adding a mercaptan and/or mercaptoalcohol to an unsaturated hydrocarbon and/or (2) thioethers other than those of (1) having a molecular weight of from 500 to 5000 and/or (3) alkali metal chlorides. This alkoxylation product is then reacted with bromine at -10.degree. to 80.degree. C. The bromide is reoxidized with aqueous hydrogen peroxide solution, stabilized with a relatively non-volatile epoxide and dehydrated. The product thus obtained is particularly useful in the production of flame resistant isocyanate addition products such as polyurethane foams.
Abstract:
Superconducting fiber bundle which contains a multiplicity of carrier fibers such as, for instance, carbon fibers, boron fibers, steel fibers coated with a superconducting layer of a niobium compound of the general formula NbC.sub.x N.sub.y O.sub.z (x+y+z less than or equal to 1), said superconducting layer formed of fine-grained B1-structure niobium compound, the mean grain size of which is between 3 and 50 nm, and the layer thickness of the superconducting layer is between 100 and 2000 nm, characterized by the feature that the superconducting layer contains occlusions of insulating material uniformly distributed, between the B1-structure niobium compound grains, or that in the superconducting layer, occlusions of insulating material are deposited on all grain boundaries of the B1-structure niobium compound drains, independently of their spatial orientation, or that in the superconducting layer, occlusions or insulating material are deposited at grain boundaries of the B1-structure niobium compound grains with definite spatial orientation within the superconducting layer, or that the superconductive material of niobium compound contains an additional element which increases the conductivity.
Abstract translation:含有多种载体纤维例如碳纤维,硼纤维,涂覆有通式NbC x N y O z的铌化合物超导层的钢纤维(x + y + z小于或等于1)的超导纤维束 ),所述超细层由细粒度的B1结构铌化合物形成,其平均晶粒尺寸在3和50nm之间,超导层的层厚度在100和2000nm之间,其特征在于, 超导层包含均匀分布的绝缘材料的夹层,B1结构的铌化合物晶粒之间或在超导层中,绝缘材料的闭塞物沉积在B1结构铌化合物排水管的所有晶界上,与它们的空间取向无关 ,或在超导层中,夹层或绝缘材料沉积在B1结构铌化合物gr的晶界处 在超导层内具有确定的空间取向,或者铌化合物的超导材料含有增加导电性的附加元素。
Abstract:
The present invention is concerned with a hydrocurable composition suitable for use as coatings, adhesives or grouts. The composition contains oxazolidine compounds and free isocyanate group containing prepolymers. The prepolymers are obtained by the reaction of polyisocyanates with special types of dispersions wherein the dispersed phase is synthesized in situ in a dispersing media of polyhydroxyl compounds. The dispersed phase may be a free radical addition polymer, an aminoplast polycondensate or a polyisocyanate addition product. In the last case, the non-isocyanate reactants used to form the dispersed phase are substantially more reactive with isocyanates than the dispersing media. An especially preferred composition is based on urethane oxazolidines and prepolymers of aliphatic or cycloaliphatic isocyanates with dispersions of isocyanate hydrazine or hydrazine hydrate condensates in polyhydroxy-polyethers having molecular weights of 200 to 16,000.
Abstract:
The invention relates to a method of making branched polysiloxane-polyoxyalkylene copolymers and to their use as stabilizers in the production of polyurethane foam plastics. The copolymers are made by reacting specified organopolysiloxanes with polyisocyanates, heat treating the NCO-containing addition products to cause branching and reacting the branched NCO-containing addition products with monofunctional polyethers. The copolymers can be used to stabilize polyurethane foam reaction mixtures.
Abstract:
A method for starting an internal combustion engine that is operated with a fuel mixture made of at least two types of fuel. An injection of the fuel into combustion chambers of the internal combustion engine occurs starting at a predefined pressure threshold of the fuel in a fuel supply according to a high-pressure starting mode, and also according to a low-pressure starting mode if the predefined pressure threshold is no longer met. The pressure threshold is selected as a function of the mixture ratio of the fuel types in the fuel mixture. In this way it can be achieved that differences can be taken into consideration in the optimal mixture formation of the fuel types.
Abstract:
A method for starting an internal combustion engine that is operated with a fuel mixture made of at least two types of fuel. An injection of the fuel into combustion chambers of the internal combustion engine occurs starting at a predefined pressure threshold of the fuel in a fuel supply according to a high-pressure starting mode, and also according to a low-pressure starting mode if the predefined pressure threshold is no longer met. The pressure threshold is selected as a function of the mixture ratio of the fuel types in the fuel mixture. In this way it can be achieved that differences can be taken into consideration in the optimal mixture formation of the fuel types.
Abstract:
In a method for operating a direct-injection internal combustion engine, a position of at least one piston inside a cylinder in which the combustion engine is at a standstill is determined; and a starting cylinder into which fuel is injected first is selected for a start following the standstill. An instantaneous charge of the starting cylinder is determined as a function of a duration of the standstill of the combustion engine. A distance (d) between the piston of the starting cylinder and a specified position of the piston is calculated. A minimum distance of the piston of the selected cylinder is determined as a function of the instantaneous charge; and another cylinder is selected as starting cylinder if the distance (d) between the piston of the starting cylinder and the specified position is less than the minimum distance.
Abstract:
To achieve a reliable and exhaust-optimized combustion starting already from the beginning of a combustion phase in the startup of an internal combustion engine, the internal combustion engine is brought to a target speed by an electric motor in a drag phase, the target speed being higher than the previously known starting speed. The target speed corresponds approximately to an idling speed assigned to the internal combustion engine, for example. After exceeding the starting speed, first a mixture enrichment is determined, taking into account a prevailing state of a wall film here in particular. Only after reaching the target speed is the fuel metered and does the combustion take place in the combustion phase. The fuel is metered here in particular on the basis of the mixture enrichment determined after exceeding the starting speed.
Abstract:
The invention relates to long-chain polyether polyols having a content of primary OH groups of 40 to 95 mol-% and a total content of oxyethylene units of >25 wt. % as well as a process for their production by DMC-catalysed polyaddition of an ethylene oxide (EO)/propylene oxide (PO) mixture in the weight ratio of 40:60 to 95:5 as an end block to starter compounds having active hydrogen atoms.