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    SITU HYDROCARBON UPGRADING WITH FLUID GENERATED TO PROVIDE STEAM AND HYDROGEN
    43.
    发明申请
    SITU HYDROCARBON UPGRADING WITH FLUID GENERATED TO PROVIDE STEAM AND HYDROGEN 审中-公开
    发动机提供蒸汽和氢气的SITU碳氢化合物

    公开(公告)号：US20120073810A1

    公开(公告)日：2012-03-29

    申请号：US13239018

    申请日：2011-09-21

    申请人： Scott Macadam ,  James P. Seaba ,  Wayne Reid Dreher, JR. ,  Joe D. Allison

    发明人： Scott Macadam ,  James P. Seaba ,  Wayne Reid Dreher, JR. ,  Joe D. Allison

    IPC分类号： E21B43/24

    CPC分类号： E21B43/305 ,  E21B43/2406

    摘要： Methods and apparatus relate to recovery of in situ upgraded hydrocarbons by injecting steam and hydrogen into a reservoir containing the hydrocarbons. A mixture output generated as water is vaporized by direct contact with flow from fuel-rich combustion provides the steam and hydrogen. The steam heats the hydrocarbons facilitating flow of the hydrocarbons and reaction of the hydrogen with the hydrocarbons to enable hydroprocessing prior to recovery of the hydrocarbons to surface.

    摘要翻译： 方法和装置涉及通过将蒸汽和氢气注入含有烃的储层中回收原位升级的烃。 通过与富燃燃烧的流体直接接触而产生的水产生的混合物产生蒸汽和氢。 蒸汽加热烃促进烃的流动和氢气与烃的反应，以便在将烃回收到表面之前进行加氢处理。

    Water-Forming Hydrogenation Reactions Utilizing Enhanced Catalyst Supports and Methods of Use
    44.
    发明申请
    Water-Forming Hydrogenation Reactions Utilizing Enhanced Catalyst Supports and Methods of Use 有权
    使用增强的催化剂载体和使用方法的水形成氢化反应

    公开(公告)号：US20110230572A1

    公开(公告)日：2011-09-22

    申请号：US13016745

    申请日：2011-01-28

    申请人： Joe D. Allison ,  Byron G. Johnson

    发明人： Joe D. Allison ,  Byron G. Johnson

    IPC分类号： C07C27/00 ,  C01B31/20 ,  C01B17/16 ,  C07C41/09 ,  C07C1/00

    CPC分类号： B01J23/70 ,  B01J21/005 ,  B01J21/04 ,  B01J21/12 ,  B01J23/005 ,  B01J23/40 ,  B01J23/63 ,  B01J23/89 ,  B01J35/023 ,  B01J35/1014 ,  B01J35/1061 ,  B01J37/0045 ,  B01J37/0207 ,  C08F8/04 ,  C10G2/33 ,  C10G3/42 ,  C10G3/48 ,  C10G3/50 ,  C10G45/04 ,  Y02P30/20

    摘要： Improved reaction efficiencies are achieved by the incorporation of enhanced hydrothermally stable catalyst supports in various water-forming hydrogenation reactions or reactions having water-containing feeds. Examples of water-forming hydrogenation reactions that may incorporate the enhanced hydrothermally stable catalyst supports include alcohol synthesis reactions, dehydration reactions, hydrodeoxygenation reactions, methanation reactions, catalytic combustion reaction, hydrocondensation reactions, and sulfur dioxide hydrogenation reactions. Advantages of the methods disclosed herein include an improved resistance of the catalyst support to water poisoning and a consequent lower rate of catalyst attrition and deactivation due to hydrothermal instability. Accordingly, higher efficiencies and yields may be achieved by extension of the enhanced catalyst supports to one or more of the aforementioned reactions.

    摘要翻译： 通过在各种成水氢化反应中加入增强的水热稳定的催化剂载体或含有含水进料的反应来实现提高的反应效率。 可以引入增强的水热稳定催化剂载体的成水氢化反应的实例包括醇合成反应，脱水反应，加氢脱氧反应，甲烷化反应，催化燃烧反应，缩水反应和二氧化硫氢化反应。 本文公开的方法的优点包括催化剂载体对水中毒的改善的耐受性以及随之而来的较低的催化剂消耗速率和由于水热不稳定性而失活。 因此，通过将增强的催化剂载体延伸到一个或多个上述反应可以实现更高的效率和收率。

    SULFIDED FISCHER-TROPSCH CATALYST
    45.
    发明申请
    SULFIDED FISCHER-TROPSCH CATALYST 有权
    硫化FISCHER-TROPSCH催化剂

    公开(公告)号：US20110124751A1

    公开(公告)日：2011-05-26

    申请号：US12951580

    申请日：2010-11-22

    申请人： Douglas E. Fjare ,  Joe D. Allison

    发明人： Douglas E. Fjare ,  Joe D. Allison

    IPC分类号： C07C1/04 ,  B01J27/02

    CPC分类号： B01J23/75 ,  B01J35/002 ,  B01J37/14 ,  B01J37/18 ,  B01J37/20 ,  C10G2/332

    摘要： Methods and compositions relate to a Fischer-Tropsch catalyst utilized to convert syngas into paraffins. The catalyst includes a given amount of sulfur content from contact of a catalytic supported metal with sulfur. Subsequent activation of the catalyst prepares the catalyst to be used for conversion of the syngas. The sulfur content maintained in the catalyst after being activated influences selectivity to paraffins over olefins and oxygenates.

    摘要翻译： 方法和组合物涉及用于将合成气转化为石蜡的费 - 托催化剂。 催化剂包括由催化负载金属与硫接触的给定量的硫含量。 催化剂的随后活化制备用于合成气转化的催化剂。 激活后保持在催化剂中的硫含量影响链烷烃对烯烃和含氧化合物的选择性。

    Methanation Reaction Methods Utilizing Enhanced Catalyst Formulations and Methods of Preparing Enhanced Methanation Catalysts
    49.
    发明申请
    Methanation Reaction Methods Utilizing Enhanced Catalyst Formulations and Methods of Preparing Enhanced Methanation Catalysts 有权
    使用增强催化剂配方的甲烷化反应方法和制备增强甲烷化催化剂的方法

    公开(公告)号：US20120238647A1

    公开(公告)日：2012-09-20

    申请号：US13421118

    申请日：2012-03-15

    申请人： Scott A. Scholten ,  Joe D. Allison ,  Brian C. Dunn

    发明人： Scott A. Scholten ,  Joe D. Allison ,  Brian C. Dunn

    IPC分类号： C07C27/00

    CPC分类号： C07C9/04 ,  B01J21/08 ,  B01J23/866 ,  B01J35/023 ,  B01J37/0036 ,  B01J37/009 ,  B01J37/031 ,  B01J37/08 ,  B01J37/18 ,  C07C1/12 ,  C07C2523/26 ,  C07C2523/755

    摘要： Enhanced mixed metal catalysts are provided which allow high conversions of carbon dioxide to methane, in some cases up to about 100% conversion. Methods of preparing enhanced mixed metal catalysts comprise a series of steps involving combining nickel and chromium salts with a nucleation promoter in a base environment to form a gel, allowing the gel to digest to form a solid and a mother liquor, isolating the solid, washing the solid, drying the solid, and thermally treating the solid to form a nickel-chromium catalyst. Methanation processes using the catalysts are also provided. The enhanced mixed metal catalysts provide more efficient conversion and lower operating temperatures for carbon dioxide methanation when compared to conventional methanation catalysts. Additionally, these enhanced catalyst formulations allow realization of higher value product from captured carbon dioxide.

    摘要翻译： 提供了增强的混合金属催化剂，其允许二氧化碳高达甲烷的转化率，在一些情况下高达约100％的转化率。 制备增强的混合金属催化剂的方法包括一系列步骤，包括将镍和铬盐与基础环境中的成核促进剂结合以形成凝胶，使凝胶消化形成固体和母液，分离固体，洗涤 固体，干燥固体，并对固体进行热处理以形成镍 - 铬催化剂。 还提供了使用催化剂的甲烷化方法。 与常规甲烷化催化剂相比，增强的混合金属催化剂提供了更有效的转化和降低二氧化碳甲烷化的操作温度。 此外，这些增强的催化剂配方允许从捕获的二氧化碳实现更高价值的产物。

    IN SITU CATALYTIC UPGRADING
    50.
    发明申请
    IN SITU CATALYTIC UPGRADING 审中-公开
    在现场催化升级

    公开(公告)号：US20120227966A1

    公开(公告)日：2012-09-13

    申请号：US13410891

    申请日：2012-03-02

    申请人： Wayne Reid Dreher, JR. ,  Joe D. Allison ,  Wendell P. Menard ,  Thomas J. Wheeler

    发明人： Wayne Reid Dreher, JR. ,  Joe D. Allison ,  Wendell P. Menard ,  Thomas J. Wheeler

    IPC分类号： E21B43/24 ,  E21B43/12

    CPC分类号： E21B43/243 ,  E21B36/04 ,  E21B43/305

    摘要： A system and method for in situ upgrading of crude oil is provided. The system includes at least one injection well, at least two first production wells, and at least one second production well. The at least one injection well has a vertical portion and a plurality of non-vertical portions connected to the vertical portion. The at least two first production wells are preferably equi-spaced and each has a horizontal portion with a first axial direction, wherein each said horizontal portion of the first production wells is horizontally spaced apart. The at least one second production well has a horizontal portion with a second axial direction. The catalytic reactor is placed at the horizontal portion of the at least one second production well such that oil coming through the second production well will first go through the catalytic reactor for hydroprocessing.

    摘要翻译： 提供了原油原位升级的系统和方法。 该系统包括至少一个注入井，至少两个第一生产井和至少一个第二生产井。 至少一个注入井具有连接到垂直部分的垂直部分和多个非垂直部分。 所述至少两个第一生产井优选为等间隔的，并且每个具有第一轴向方向的水平部分，其中第一生产井的每个所述水平部分水平间隔开。 所述至少一个第二生产井具有具有第二轴向方向的水平部分。 将催化反应器放置在至少一个第二生产井的水平部分，使得通过第二生产井的油将首先经过用于加氢处理的催化反应器。