Production of ethylbenzene
    49.
    发明授权
    Production of ethylbenzene 失效
    生产乙苯

    公开(公告)号:US5118894A

    公开(公告)日:1992-06-02

    申请号:US732265

    申请日:1991-07-18

    Applicant: Quang N. Le

    Inventor: Quang N. Le

    Abstract: Ethylbenzene is produced by the alkylation of benzene with ethylene in the presence of an alkylation catalyst which comprises an inorganic, non-layered, porous, crystalline phase aluminosilicate material whcih exhibits a benzene adsorption capacity of greater than about 15 grams benzene per 100 grams at 50 torr and 25.degree. C. In its preferred catalytic form, the crystalline material has a uniform, hexagonal arrangement of pores with diameters of at least about 13 .ANG. and exhibiting, after calcination, an X-ray diffraction pattern with at least one d-spacing greater than about 18 A and a hexagonal electron diffraction pattern that can be indexed with a d.sub.100 value greater than about 18 .ANG. which corresponds to at least one peak in the X-ray diffraction pattern. The process is typically carried out at a temperatue of 200.degree. to 1000.degree. F. but the catalyst provides sufficient activity for the reaction to be carried out at temperatures below 700.degree. F. Liquid phase operation is preferred, giving a lower yield of polyethylated products. The use of the selected catalyst also results in a reduction of the xylene impurity level.

    Abstract translation: 在烷基化催化剂存在下,通过苯与乙烯的烷基化生产乙苯,该烷基化催化剂包含无机,非分层,多孔的结晶相铝硅酸盐材料,其在50℃下表现出大于约15克苯/ 100克的苯吸附能力 托和25℃。在其优选的催化形式中,结晶材料具有均匀的六边形排列的孔,其直径至少​​约为13,并且在煅烧之后表现出具有至少一个d间距的X射线衍射图 大于约18的六边形电子衍射图案和可以对应于X射线衍射图中的至少一个峰值的d100值大于约18的折射率的六角形电子衍射图案。 该方法通常在200至1000°F的温度下进行,但催化剂提供足够的活性以使反应在低于700°F的温度下进行。优选液相操作,从而降低聚乙烯化产物的产率 。 使用所选择的催化剂也导致二甲苯杂质水平的降低。

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