公开(公告)号：US20150152249A1

公开(公告)日：2015-06-04

申请号：US14450799

申请日：2014-08-04

申请人： Bridgestone Corporation

发明人： William L. Hergenrother ,  Walter Tomaszewski ,  Ashley Hilton ,  Michael Hayes ,  James H. Pawlow ,  Terrence E. Hogan

IPC分类号： C08K7/06

CPC分类号： C08K7/06 ,  B29C66/71 ,  B29C66/74283 ,  B29D30/38 ,  B29D2030/383 ,  B29D2030/483 ,  B60C1/00 ,  B60C2009/0014 ,  B60C2009/0021 ,  C08G77/26 ,  C08G77/28 ,  C08L21/00 ,  C09D183/08 ,  C09J183/08 ,  D07B1/0666 ,  Y02P20/582 ,  Y10T428/31663 ,  B29K2021/00

摘要： Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water.

公开(公告)号：US20140378597A1

公开(公告)日：2014-12-25

申请号：US14375295

申请日：2012-07-24

申请人： Guy Buytaert ,  Dieter Wemel ,  Patricia Reis

发明人： Guy Buytaert ,  Dieter Wemel ,  Patricia Reis

IPC分类号： D02G3/48 ,  B21C1/02 ,  C08J5/04 ,  C08K3/08 ,  C08K3/04 ,  D02G3/12 ,  B60C9/00

CPC分类号： D02G3/48 ,  B21C1/02 ,  B32B15/015 ,  B60C9/0007 ,  B60C2009/0014 ,  C08K3/08 ,  C09D5/38 ,  C09D7/61 ,  C22C9/04 ,  C22C38/00 ,  C22C38/001 ,  C22C38/02 ,  C22C38/04 ,  C22C38/42 ,  C22C38/44 ,  C25D3/12 ,  C25D3/22 ,  C25D3/38 ,  C25D5/10 ,  C25D5/48 ,  C25D5/50 ,  D07B1/066 ,  D07B1/0666 ,  D07B2201/2011 ,  D07B2201/2043 ,  D07B2205/3089 ,  D07B2501/2046 ,  D07B2801/18

摘要： An elongated steel element adapted for the reinforcement of rubber products is covered with a ternary or quaternary alloy coating of copper-M-zinc. M is one or two metals selected from the group consisting of cobalt, nickel, tin, indium, manganese, iron, bismuth and molybdenum. The copper content inside the coating ranges from 58 weight percent to 75 weight percent, the content of said one or two metals inside the coating ranges from 0.5 weight percent to 10 weight percent, the remainder is zinc and unavoidable impurities. The one or two metals are present throughout the coating. The phosphorus is present on and/or in the coating in an amount ranging from 0.3 milligram per square meter to 1 milligram per square meter of the coating. The coating further lacks triazole residues. Good results for under cure adhesion have been obtained. Furthermore, a corresponding method for manufacturing such an elongated steel element is disclosed.

摘要翻译： 用于加强橡胶制品的细长钢元件用铜-M-锌的三元或四元合金涂层覆盖。 M是选自钴，镍，锡，铟，锰，铁，铋和钼中的一种或两种金属。 涂层中的铜含量为58重量％至75重量％，涂层内的一种或两种金属的含量为0.5重量％至10重量％，其余为锌和不可避免的杂质。 一个或两个金属存在于整个涂层中。 磷存在于涂层上和/或涂层中，其含量范围为每平方米0.3毫克至1毫克涂层。 该涂层还缺乏三唑残基。 已经获得了良好的固化粘合性能。 此外，公开了用于制造这种细长钢件的相应方法。

公开(公告)号：US08794282B2

公开(公告)日：2014-08-05

申请号：US12347086

申请日：2008-12-31

申请人： William L. Hergenrother ,  Walter Tomaszewski ,  Ashley Hilton ,  Michael Hayes ,  James H. Pawlow ,  Terrence E. Hogan

发明人： William L. Hergenrother ,  Walter Tomaszewski ,  Ashley Hilton ,  Michael Hayes ,  James H. Pawlow ,  Terrence E. Hogan

IPC分类号： C08G77/28 ,  C08L21/00 ,  B60C1/00

CPC分类号： C08K7/06 ,  B29C66/71 ,  B29C66/74283 ,  B29D30/38 ,  B29D2030/383 ,  B29D2030/483 ,  B60C1/00 ,  B60C2009/0014 ,  B60C2009/0021 ,  C08G77/26 ,  C08G77/28 ,  C08L21/00 ,  C09D183/08 ,  C09J183/08 ,  D07B1/0666 ,  Y02P20/582 ,  Y10T428/31663 ,  B29K2021/00

摘要： Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water.

摘要翻译： 还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷（氨基AMS）和/或氨基辅AMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂，用于将线粘附到橡胶原料上。 氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用，并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂，例如但不限于钴，树脂 和高硫含量。 特别地，使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能，以获得足够的粘合，其耐受在时间上的劣化，特别是电阻 热老化和/或热氧化老化，特别是在水存在下的腐蚀。

公开(公告)号：US20140110034A1

公开(公告)日：2014-04-24

申请号：US14125898

申请日：2012-06-12

申请人： Atsushi Tanno ,  Noboru Takada ,  Susumu Imamiya

发明人： Atsushi Tanno ,  Noboru Takada ,  Susumu Imamiya

IPC分类号： B60C9/16 ,  B29D30/08

CPC分类号： B60C9/16 ,  B29D30/06 ,  B29D30/08 ,  B29D30/70 ,  B29D2030/383 ,  B60C9/18 ,  B60C9/28 ,  B60C2009/0014 ,  B60C2009/286 ,  B60C2011/0025 ,  C09J183/06 ,  C23C22/50 ,  Y02T10/862 ,  Y10T152/10207 ,  Y10T152/10765 ,  Y10T152/10774 ,  Y10T152/10855

摘要： A pneumatic tire includes: an annular structure that is cylindrical and metal where at least an outer side surface in the radial direction is a rough surface; a tread rubber layer that will become a tread portion provided along a circumferential direction of the annular structure on an outer side of the annular structure; and a carcass portion including fibers covered with rubber, provided on at least both sides in a direction parallel to a center axis of the cylindrical structure including the annular structure and the tread rubber layer.

摘要翻译： 一种充气轮胎包括：圆柱形和金属的环形结构，至少在径向的外侧表面是粗糙表面; 胎面橡胶层，其将成为在环形结构的外侧沿着环形结构的圆周方向设置的胎面部; 以及包括橡胶覆盖的纤维的胎体部分，至少设置在与包括所述环形结构的所述圆筒形结构和所述胎面橡胶层的中心轴平行的方向上的至少两侧。

公开(公告)号：US20130133804A1

公开(公告)日：2013-05-30

申请号：US13305825

申请日：2011-11-29

申请人： Samy Laroussi Mzabi ,  Claude Ernest Felix Boes ,  Gilles Joseph Henri Bertemes ,  Etienne Besnoin ,  Patrick François Willems

发明人： Samy Laroussi Mzabi ,  Claude Ernest Felix Boes ,  Gilles Joseph Henri Bertemes ,  Etienne Besnoin ,  Patrick François Willems

IPC分类号： B60C9/00 ,  B05D3/00 ,  B60C15/00 ,  B05D3/06 ,  B60C9/02 ,  B60C9/18

CPC分类号： B60C5/00 ,  B29B15/08 ,  B29D30/38 ,  B29D30/48 ,  B29D2030/383 ,  B29D2030/481 ,  B60C9/00 ,  B60C2009/0014 ,  D07B1/0606 ,  D07B5/005 ,  D07B2401/2095 ,  D07B2501/2046

摘要： A method forms an adhesion joint between a cord and a rubber matrix. The method includes the steps of providing a cord having an initial relatively smooth surface, texturing the smooth surface such that the resulting surface is rougher than the initial surface of the cord, and inserting the cord into a rubber matrix such that the resulting surface provides enhanced adhesion to the rubber matrix compared to the adhesion of the initial surface to the rubber matrix.

摘要翻译： 一种方法形成帘线和橡胶基质之间的粘合接头。 该方法包括以下步骤：提供具有初始相对平滑表面的帘线，使光滑表面纹理化，使得所得表面比帘线的初始表面更粗糙，并将帘线插入橡胶基质中，使得所得表面提供增强的 与初始表面与橡胶基体的粘附力相对于橡胶基体的粘附。

公开(公告)号：US20120159919A1

公开(公告)日：2012-06-28

申请号：US13382141

申请日：2010-07-05

申请人： Jacques Gauthier ,  Henri Barguet ,  Sandra Boisseau ,  Thibaud Pottier

发明人： Jacques Gauthier ,  Henri Barguet ,  Sandra Boisseau ,  Thibaud Pottier

IPC分类号： D02G3/12 ,  D02G3/48 ,  D02G3/36 ,  B60C9/18

CPC分类号： D07B1/0613 ,  B60C2009/0014 ,  D07B1/062 ,  D07B1/0626 ,  D07B5/12 ,  D07B7/145 ,  D07B2201/1032 ,  D07B2201/1068 ,  D07B2201/2011 ,  D07B2201/2023 ,  D07B2201/2025 ,  D07B2201/2028 ,  D07B2201/203 ,  D07B2201/2032 ,  D07B2201/2039 ,  D07B2201/2046 ,  D07B2201/2059 ,  D07B2201/2061 ,  D07B2201/2062 ,  D07B2201/2081 ,  D07B2205/2075 ,  D07B2205/3021 ,  D07B2205/306 ,  D07B2205/3067 ,  D07B2205/3071 ,  D07B2205/3075 ,  D07B2205/3089 ,  D07B2207/4072 ,  D07B2401/2005 ,  D07B2401/201 ,  D07B2401/2025 ,  D07B2501/2046 ,  D07B2801/12 ,  D07B2801/24 ,  D07B2801/16 ,  D07B2801/18

摘要： Multistrand metal cord of K×(L+M) construction, which can especially be used for reinforcing tire belts for industrial vehicles, consisting of K elementary strands assembled in a helix, with a helix pitch PK, each elementary strand: consisting of a cord (10) having two layers (Ci, Ce) of L+M construction, rubberized in situ, comprising an inner layer (Ci) consisting of L wires (11) of diameter d1, L varying from 1 to 4, and an outer layer (Ce) of M wires (12), M being equal to or greater than 5, of diameter d2, which are assembled in a helix with a pitch p2 around the inner layer (Ci); and having the following characteristics (d1, d2 and p2 being expressed in mm): 0.10

摘要翻译： K×（L + M）结构的多股金属线，特别可用于加工用于工业车辆的轮胎带，由以螺旋形组装的K个基本线组成，具有螺旋间距PK，每条基本线由绳索 （10），其具有L + M构造的两层（Ci，Ce），原位胶化，包括由直径为d1的L线（11），从1变为4的L线（11）和外层 M线（12）的M（Ce），M等于或大于5的直径d2，它们以围绕内层（Ci）的间距p2组装成螺旋线; 并且具有以下特性（d1，d2和p2以mm表示）：0.10

公开(公告)号：US07162902B2

公开(公告)日：2007-01-16

申请号：US11053867

申请日：2005-02-10

申请人： Ryuzo Oosawa ,  Tadasi Honna ,  Hisakatsu Hara

发明人： Ryuzo Oosawa ,  Tadasi Honna ,  Hisakatsu Hara

IPC分类号： B21C9/00 ,  B21C3/02

CPC分类号： D07B1/0666 ,  B60C9/0007 ,  B60C9/02 ,  B60C9/2006 ,  B60C2009/0014 ,  D07B2205/3089 ,  Y10T428/12438 ,  Y10T428/12562 ,  Y10T428/12924 ,  Y10T428/2958 ,  D07B2801/18

摘要： This invention relates to steel wires and steel cords used as a reinforcement for rubber articles such as pneumatic tire, industrial belt and the like, particularly steel wires and steel cords having an excellent adhesion property to rubber, in which an amount of phosphorus included as an oxide in a surface layer region from a brass plated surface applied to a circumferential face of a wire up to a depth of 5 nm in a radial direction of the wire is controlled to not more than 1.5 atomic %, whereby an excellent adhesion property between steel cord and coating rubber can be provided even when an adhesion promoter conventionally added in a coating rubber composition for the steel cord is reduced or is not added.

摘要翻译： 本发明涉及用作橡胶制品例如充气轮胎，工业皮带等的钢丝绳和钢丝帘线，特别是具有优异的橡胶密合性的钢丝和钢丝帘线，其中包含的磷的量为 在施加到线的圆周面的黄铜镀层的表面层区域中，氧化物在线材的径向上达到5nm的深度被控制为不大于1.5原子％，由此钢的粘合性优异 即使通常添加在钢帘线用涂料橡胶组合物中的粘合促进剂减少或不添加，也可以提供帘线和涂布橡胶。

公开(公告)号：US20050147818A1

公开(公告)日：2005-07-07

申请号：US11053867

申请日：2005-02-10

申请人： Ryuzo Oosawa ,  Tadashi Honna ,  Hisakatu Hara

发明人： Ryuzo Oosawa ,  Tadashi Honna ,  Hisakatu Hara

IPC分类号： B60C9/00 ,  B60C9/02 ,  B60C9/20 ,  D07B1/06 ,  B32B9/00

CPC分类号： D07B1/0666 ,  B60C9/0007 ,  B60C9/02 ,  B60C9/2006 ,  B60C2009/0014 ,  D07B2205/3089 ,  Y10T428/12438 ,  Y10T428/12562 ,  Y10T428/12924 ,  Y10T428/2958 ,  D07B2801/18

摘要： This invention relates to steel wires and steel cords used as a reinforcement for rubber articles such as pneumatic tire, industrial belt and the like, particularly steel wires and steel cords having an excellent adhesion property to rubber, in which an amount of phosphorus included as an oxide in a surface layer region from a brass plated surface applied to a circumferential face of a wire up to a depth of 5 nm in a radial direction of the wire is controlled to not more than 1.5 atomic %, whereby an excellent adhesion property between steel cord and coating rubber can be provided even when an adhesion promoter conventionally added in a coating rubber composition for the steel cord is reduced or is not added.

摘要翻译： 本发明涉及用作橡胶制品例如充气轮胎，工业皮带等的钢丝绳和钢丝帘线，特别是具有优异的橡胶密合性的钢丝和钢丝帘线，其中包含的磷的量为 在施加到线的圆周面的黄铜镀层的表面层区域中，氧化物在线材的径向上达到5nm的深度被控制为不大于1.5原子％，由此钢的粘合性优异 即使通常添加在钢帘线用涂料橡胶组合物中的粘合促进剂减少或不添加，也可以提供帘线和涂布橡胶。

公开(公告)号：US2870526A

公开(公告)日：1959-01-27

申请号：US53607555

申请日：1955-09-23

申请人： NAT STANDARD CO

发明人： ADLER ORVILLE E

IPC分类号： B29C70/68 ,  B60C9/00 ,  C23C2/06 ,  C25D3/58

CPC分类号： D07B1/0666 ,  B60C9/0007 ,  B60C2009/0014 ,  C23C2/06 ,  C25D3/58 ,  D07B2201/2011 ,  D07B2201/2013 ,  D07B2205/3071 ,  D07B2205/3089 ,  Y10S428/926 ,  Y10S428/935 ,  Y10T428/12562 ,  Y10T428/12792 ,  Y10T428/12799 ,  Y10T428/12903 ,  D07B2801/18

公开(公告)号：US11701922B2

公开(公告)日：2023-07-18

申请号：US16621570

申请日：2018-06-12

申请人： COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN

发明人： Milan Fedurco ,  Marco Ribezzo

IPC分类号： B60C9/00 ,  C08G73/02 ,  C08J5/06 ,  C09D179/04 ,  D07B1/06 ,  C08G65/40

CPC分类号： B60C9/0007 ,  C08G65/4031 ,  C08G65/4056 ,  C08G73/0233 ,  C08J5/06 ,  C09D179/04 ,  D07B1/0606 ,  B60C2009/0014 ,  C08G2380/00 ,  Y10T428/2933 ,  Y10T428/2938

摘要： A metallic or metallized reinforcer has at least a surface of which is at least partially metallic, the at least partially metallic surface being coated with a polybenzoxazine sulfide whose repeating units include at least one unit corresponding to formula (I) or (II):




in which the two oxazine rings are connected together via a central aromatic group, the benzene ring of which bears one, two, three or four groups of formula —Sx—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon-based group including 1 to 10 carbon atoms and optionally a heteroatom chosen from O, S, N and P. Such a reinforcement can be used for the reinforcement of a rubber article, in particular a motor vehicle tire.