Fluorine-containing resin composition for optical use
    42.
    发明授权
    Fluorine-containing resin composition for optical use 失效
    用于光学用途的含氟树脂组合物

    公开(公告)号:US4617350A

    公开(公告)日:1986-10-14

    申请号:US826373

    申请日:1986-02-05

    CPC classification number: C08L27/16 C08L33/08

    Abstract: A thermoplastic resin composition useful for optical purposes is obtained by blending a polymer of an acrylic ester with a copolymer of vinylidene fluoride (VDF) and hexafluoroacetone (HFA). The blending ratio is not limited, though very good transparency is ensured when the acrylic ester polymer amounts to at least 20 wt %. It is preferable to use a polymer of an acrylic ester with an alkyl alcohol having not more than 4 carbon atoms. When using the resin composition in optical fibers or cylindrical lenses it is suitable to use a VDF/HFA copolymer containing not more than 20 mol % of HFA. The refractive index of a member formed of the resin composition is lower than that of the acrylic ester polymer and falls in the range of about 1.37-1.48. The resin composition is soluble in various organic solvents and accordingly can be used for adhesing and coating purposes too. Besides, this resin composition serves as a thermochromic material.

    Abstract translation: 通过将丙烯酸酯的聚合物与偏二氟乙烯(VDF)和六氟丙酮(HFA)的共聚物共混而获得用于光学目的的热塑性树脂组合物。 共混比没有限制,但是当丙烯酸酯聚合物达到至少20重量%时,确保了非常好的透明度。 优选使用具有不超过4个碳原子的烷基醇的丙烯酸酯的聚合物。 当将光学纤维或圆柱形透镜中的树脂组合物使用时,适合使用含有不大于20mol%HFA的VDF / HFA共聚物。 由树脂组合物形成的部件的折射率低于丙烯酸酯聚合物的折射率,并且在约1.37-1.48的范围内。 树脂组合物可溶于各种有机溶剂,因此也可用于粘合和涂布。 此外,该树脂组合物用作热变色材料。

    Fluoroelastomer film compositions and solutions containing epoxy resin
adducts
    43.
    发明授权
    Fluoroelastomer film compositions and solutions containing epoxy resin adducts 失效
    含氟弹性体膜组合物和含有环氧树脂加合物的溶液

    公开(公告)号:US4421878A

    公开(公告)日:1983-12-20

    申请号:US324840

    申请日:1981-11-25

    Applicant: Donald Close

    Inventor: Donald Close

    CPC classification number: C08L27/12 C08L63/00 C08L77/00 Y10T428/31544

    Abstract: The invention herein disclosed provides a method for preparing improved fluoroelastomer film compositions including the steps of dissolving a fluoroelastomer gum selected from the group consisting of copolymers of vinylidene fluoride and hexafluoropropylene, and terpolymers of vinylidene fluoride, hexafluoropropylene and tetrafluoroethylene in a solvent, adding an amine-derived curative to the gum solution and curing the fluoroelastomer gum with the curative in the absence of metallic oxides. A method is also provided for adhering fluoroelastomer film compositions, devoid of metallic oxides, to substrates which includes the steps of dissolving the fluoroelastomer gum in a solvent, adding an amine-derived curative to the gum solution, coating the substrate with the fluoroelastomer gum-curative solution and evaporating the solvent leaving a film firmly adhered to the substrate. When metallic oxides are present, the foregoing method can also be practiced by including the step of adding an epoxy resin to the composition. The fluoroelastomer film compositions disclosed herein are also novel and can be used to coat a variety of substrates thereby providing other novel, useful articles.

    Abstract translation: 本文公开的本发明提供了一种制备改进的含氟弹性体膜组合物的方法,包括以下步骤:将选自偏二氟乙烯和六氟丙烯的共聚物的含氟弹性体胶和偏二氟乙烯,六氟丙烯和四氟乙烯的三元共聚物溶解在溶剂中, 得到固化剂至胶溶液,并在没有金属氧化物的情况下用固化剂固化含氟弹性体胶。 还提供了一种方法,用于将没有金属氧化物的含氟弹性体膜组合物粘附到基底上,其中包括将含氟弹性体胶溶解在溶剂中的步骤,向胶溶液中加入胺衍生的固化剂,用含氟弹性体胶 - 固化溶液并蒸发溶剂,留下牢固粘附在基材上的膜。 当存在金属氧化物时,上述方法也可以通过包括向组合物中加入环氧树脂的步骤来实施。 本文公开的含氟弹性体膜组合物也是新颖的,并且可以用于涂覆各种基材,从而提供其它新颖有用的制品。

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