利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

144 条记录 (耗时 0.089 秒)

    Silane compound for use in the synthesis of semiconducting polymers with perpendicular arranged cores
    51.
    发明授权
    Silane compound for use in the synthesis of semiconducting polymers with perpendicular arranged cores 失效
    用于合成具有垂直排列芯的半导体聚合物的硅烷化合物

    公开(公告)号：US5059695A

    公开(公告)日：1991-10-22

    申请号：US492543

    申请日：1990-03-12

    申请人： James M. Tour ,  Ruilian Wu ,  Jeffry S. Schumm

    发明人： James M. Tour ,  Ruilian Wu ,  Jeffry S. Schumm

    IPC分类号： C07F7/12 ,  C07F7/08

    CPC分类号： C07F7/0816

    摘要： The stereochemical structure necessary for preparation of perpendicularly arranged cores is provided by a compound of the formula ##STR1## wherein X is a reactive group through which polymeric subunits can be bonded to the compound. In particular, X is advantageously Br. This compound can be synthesized by the reaction of tetrakis(3'-trimethylsilyl-2'-propynyl)silane with zirconocene dichloride and n-butyllithium and adding sulfur monochloride to the reaction product. This produces an adduct in which X is SiMe.sub.3. This adduct may be converted to the bromo compound by reaction with bromine. The tetrakis(3'-trimethylsilyl-2-propynyl)silane may be prepared by forming a magnesium Grignard reagent from 3-bromo-1-trimethylsilylpropyne and reacting the Grignard reagent with silicon tetrachloride.

    摘要翻译： 用于制备垂直排列的核心所需的立体化学结构由下式化合物提供：其中X是可与聚合物亚单元键合的反应性基团。 特别地，X优选为Br。 该化合物可以通过四（3'-三甲基甲硅烷基-2'-丙炔基）硅烷与二氯化二茂锆和正丁基锂的反应合成，并向反应产物中加入一氯化硫。 这产生其中X是SiMe 3的加合物。 该加成物可以通过与溴反应转化成溴化合物。 四（3'-三甲基甲硅烷基-2-丙炔基）硅烷可以通过从3-溴-1-三甲基甲硅烷基丙炔形成镁格氏试剂并使格利雅试剂与四氯化硅反应来制备。

    LASER INDUCED GRAPHENE HYBRID MATERIALS FOR ELECTRONIC DEVICES
    53.
    发明申请
    LASER INDUCED GRAPHENE HYBRID MATERIALS FOR ELECTRONIC DEVICES 审中-公开

    公开(公告)号：US20190088420A1

    公开(公告)日：2019-03-21

    申请号：US15528320

    申请日：2015-11-27

    申请人： James M. Tour ,  Lei Li ,  Zhiwei Peng ,  Jibo Zhang

    发明人： James M. Tour ,  Lei Li ,  Zhiwei Peng ,  Jibo Zhang

    IPC分类号： H01G11/36 ,  C01B32/184 ,  C01B32/194 ,  H01M4/587 ,  H01M4/62

    摘要： In some embodiments, the present disclosure pertains to methods of producing a graphene hybrid material by exposing a graphene precursor material to a laser source to form a laser-induced graphene, where the laser-induced graphene is derived from the graphene precursor material. The methods of the present disclosure also include a step of associating a pseudocapacitive material (e.g., a conducting polymer or a metal oxide) with the laser-induced graphene to form the graphene hybrid material. The formed graphene hybrid material can become embedded with or separated from the graphene precursor material. The graphene hybrid materials can also be utilized as components of an electronic device, such as electrodes in a microsupercapacitor. Additional embodiments of the present disclosure pertain to the aforementioned graphene hybrid materials and electronic devices.

    Hydrated porous materials for selective CO2 capture
    54.
    发明授权
    Hydrated porous materials for selective CO2 capture 有权

    公开(公告)号：US10232343B2

    公开(公告)日：2019-03-19

    申请号：US15640765

    申请日：2017-07-03

    申请人： James M. Tour ,  Almaz S. Jalilov

    发明人： James M. Tour ,  Almaz S. Jalilov

    IPC分类号： B01D53/02 ,  B01J20/20 ,  B01D53/62 ,  B01J20/28 ,  B01J20/30 ,  C10L3/10

    摘要： In some embodiments, the present disclosure pertains to methods of capturing CO2 from an environment by hydrating a porous material with water molecules to the extent thereby to define a preselected region of a plurality of hydrated pores and yet to the extent to allow the preselected region of a plurality of pores of the porous material to uptake gas molecules; positioning the porous material within a CO2 associated environment; and capturing CO2 by the hydrated porous material. In some embodiments, the pore volume of the hydrated porous material includes between 90% and 20% of the pre-hydrated pore volume to provide unhydrated pore volume within the porous material for enhanced selective uptake of CO2 in the CO2 associated environment. In some embodiments, the step of capturing includes forming CO2-hydrates within the pores of the porous material, where the CO2.nH2O ratio is n

    Methods for production of single-crystal graphenes
    56.
    发明授权
    Methods for production of single-crystal graphenes 有权

    公开(公告)号：US09845551B2

    公开(公告)日：2017-12-19

    申请号：US13939086

    申请日：2013-07-10

    申请人： James M. Tour ,  Zheng Yan

    发明人： James M. Tour ,  Zheng Yan

    IPC分类号： C30B25/18 ,  C30B25/02 ,  C30B29/02 ,  C01B31/04 ,  B82Y30/00 ,  B82Y40/00

    CPC分类号： C30B25/186 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/186 ,  C30B25/02 ,  C30B29/02

    摘要： In some embodiments, the present disclosure pertains to methods of forming single-crystal graphenes by: (1) cleaning a surface of a catalyst; (2) annealing the surface of the catalyst; (3) applying a carbon source to the surface of the catalyst; and (4) growing single-crystal graphene on the surface of the catalyst from the carbon source. Further embodiments of the present disclosure also include a step of separating the formed single-crystal graphene from the surface of the catalyst. In some embodiments, the methods of the present disclosure also include a step of transferring the formed single-crystal graphene to a substrate. Additional embodiments of the present disclosure also include a step of growing stacks of single crystals of graphene.

    Graphene-carbon nanotube hybrid materials and use as electrodes
    58.
    发明授权
    Graphene-carbon nanotube hybrid materials and use as electrodes 有权
    石墨烯碳纳米管混合材料，用作电极

    公开(公告)号：US09455094B2

    公开(公告)日：2016-09-27

    申请号：US14358864

    申请日：2012-11-19

    申请人： James M. Tour ,  Yu Zhu ,  Lei Li ,  Zheng Yan ,  Jian Lin

    发明人： James M. Tour ,  Yu Zhu ,  Lei Li ,  Zheng Yan ,  Jian Lin

    IPC分类号： H01G11/36 ,  C01B31/04 ,  C01B31/02 ,  H01G11/72 ,  B82Y30/00 ,  B82Y40/00

    CPC分类号： H01G11/36 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/158 ,  C01B32/16 ,  C01B32/182 ,  C01B32/194 ,  H01G11/72 ,  Y02E60/13 ,  Y10T428/24893 ,  Y10T428/30

    摘要： Provided are methods of making graphene-carbon nanotube hybrid materials. Such methods generally include: (1) associating a graphene film with a substrate; (2) applying a catalyst and a carbon source to the graphene film; and (3) growing carbon nanotubes on the graphene film. The grown carbon nanotubes become covalently linked to the graphene film through carbon-carbon bonds that are located at one or more junctions between the carbon nanotubes and the graphene film. In addition, the grown carbon nanotubes are in ohmic contact with the graphene film through the carbon-carbon bonds at the one or more junctions. The one or more junctions may include seven-membered carbon rings. Also provided are the formed graphene-carbon nanotube hybrid materials.

    摘要翻译： 提供制造石墨烯 - 碳纳米管混合材料的方法。 这些方法通常包括：（1）将石墨烯膜与基底缔合; （2）向石墨烯膜施加催化剂和碳源; 和（3）在石墨烯膜上生长碳纳米管。 生长的碳纳米管通过位于碳纳米管和石墨烯膜之间的一个或多个结处的碳 - 碳键共价连接到石墨烯膜上。 此外，生长的碳纳米管通过在一个或多个结处的碳 - 碳键与石墨烯膜欧姆接触。 一个或多个连接点可以包括七元碳环。 还提供了形成的石墨烯 - 碳纳米管混合材料。

    Synthesis of magnetic carbon nanoribbons and magnetic functionalized carbon nanoribbons
    59.
    发明授权
    Synthesis of magnetic carbon nanoribbons and magnetic functionalized carbon nanoribbons 有权
    磁性碳纳米带和磁性官能化碳纳米带的合成

    公开(公告)号：US09449743B2

    公开(公告)日：2016-09-20

    申请号：US14374591

    申请日：2013-01-28

    申请人： James M. Tour ,  Bostjan Genorio ,  Wei Lu ,  Brandi Katherine Price-Hoelscher

    发明人： James M. Tour ,  Bostjan Genorio ,  Wei Lu ,  Brandi Katherine Price-Hoelscher

    IPC分类号： H01F1/34 ,  C01B31/02 ,  H01F1/01 ,  C09K8/03 ,  C09K8/32 ,  C09K8/36 ,  E21B21/00 ,  C01B31/04 ,  B82Y30/00 ,  B82Y40/00 ,  E21B47/12

    CPC分类号： H01F1/01 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/168 ,  C01B32/194 ,  C09K8/032 ,  C09K8/32 ,  C09K8/36 ,  C09K2208/10 ,  E21B21/00 ,  E21B47/12

    摘要： Various embodiments of the present disclosure pertain to methods of making magnetic carbon nanoribbons. Such methods generally include: (1) forming carbon nanoribbons by splitting carbon nanomaterials; and (2) associating graphene nanoribbons with magnetic materials, precursors of magnetic materials, or combinations thereof. Further embodiments of the present disclosure also include a step of reducing the precursors of magnetic materials to magnetic materials. In various embodiments, the associating occurs before, during or after the splitting of the carbon nanomaterials. In some embodiments, the methods of the present disclosure further comprise a step of (3) functionalizing the carbon nanoribbons with functionalizing agents. In more specific embodiments, the functionalizing occurs in situ during the splitting of carbon nanomaterials. In further embodiments, the carbon nanoribbons are edge-functionalized. Additional embodiments of the present disclosure pertain to magnetic carbon nanoribbon compositions that were formed in accordance with the methods of the present disclosure.

    摘要翻译： 本公开的各种实施方案涉及制备磁性碳纳米带的方法。 这些方法通常包括：（1）通过分解碳纳米材料形成碳纳米带; 和（2）将石墨烯纳米带与磁性材料，磁性材料的前体或其组合相关联。 本公开的另外的实施方案还包括将磁性材料的前体还原成磁性材料的步骤。 在各种实施方案中，缔合发生在碳纳米材料分裂之前，期间或之后。 在一些实施方案中，本公开的方法还包括（3）用官能化试剂官能化碳纳米带的步骤。 在更具体的实施方案中，官能化在碳纳米材料分裂过程中就地发生。 在另外的实施方案中，碳纳米带是边缘官能化的。 本公开的另外的实施方案涉及根据本公开的方法形成的磁性碳纳米纤维组合物。

    GROWTH OF GRAPHENE FILMS FROM NON-GASEOUS CARBON SOURCES
    60.
    发明申请
    GROWTH OF GRAPHENE FILMS FROM NON-GASEOUS CARBON SOURCES 审中-公开
    来自非碳源碳源的石墨膜的生长

    公开(公告)号：US20160031711A1

    公开(公告)日：2016-02-04

    申请号：US14754983

    申请日：2015-06-30

    申请人： James M. Tour ,  Zhengzong Sun ,  Zheng Yan ,  Gedeng Ruan ,  Zhiwei Peng

    发明人： James M. Tour ,  Zhengzong Sun ,  Zheng Yan ,  Gedeng Ruan ,  Zhiwei Peng

    IPC分类号： C01B31/04

    CPC分类号： C01B32/194 ,  C01B32/184 ,  C01B2204/02 ,  C01B2204/04

    摘要： In various embodiments, the present disclosure provides methods of forming graphene films by: (1) depositing a non-gaseous carbon source onto a catalyst surface; (2) exposing the non-gaseous carbon source to at least one gas with a flow rate; and (3) initiating the conversion of the non-gaseous carbon source to the graphene film, where the thickness of the graphene film is controllable by the gas flow rate. Additional embodiments of the present disclosure pertain to graphene films made in accordance with the methods of the present disclosure.

    摘要翻译： 在各种实施方案中，本公开提供了通过以下步骤形成石墨烯膜的方法：（1）将非气态碳源沉积在催化剂表面上; （2）将非气态碳源以流量暴露于至少一种气体; 和（3）开始将非气态碳源转化为石墨烯膜，其中石墨烯膜的厚度可由气体流速控制。 本公开的另外的实施方案涉及根据本公开的方法制备的石墨烯膜。