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公开(公告)号：US5124136A
公开(公告)日：1992-06-23
申请号：US543634
申请日：1990-06-26
申请人： Mark E. Davis
发明人： Mark E. Davis
CPC分类号： C01B37/06 , B01J29/84 , C01B37/04 , C01B37/08 , Y10S423/30
摘要： Crystalline metalloaluminophosphate compositions having pore windows formed by 18 tetrahedral members are prepared from a forming mixture containing sources of aluminum, phosphorus and a non-aluminum, non-phosphorus element, e.g. boron or boron and silicon. The forming mixture further contains a directing agent comprising a mixture of quaternary nitrogen compound and amine in a molar ratio of 0.01 to 0.025.
摘要翻译： 由含有铝，磷和非铝，非磷元素的形成混合物制备具有由18个四面体成分形成的孔窗的结晶金属铝磷酸盐组合物，例如， 硼或硼和硅。 形成混合物还含有包含季氮化合物和胺的混合物的导向剂，摩尔比为0.01至0.025。
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公开(公告)号：US5094828A
公开(公告)日：1992-03-10
申请号：US636055
申请日：1990-12-31
申请人： Cynthia T-W. Chu
发明人： Cynthia T-W. Chu
CPC分类号： B01J29/85 , B01J29/04 , C01B37/04 , C01B37/08 , Y10S423/30
摘要： This invention relates to a method for preparing large pore synthetic crystalline molecular sieve composition which may contain framework +3 valence element, e.g. aluminum, and one or more of a) +4 valence element, e.g. silicon, and b) +5 valence element, e.g. phosphorous. The method utilizes cyclohexylamine as directing agent in the forming mixture. The source of +3 valence element and, optionally +4 element is an alkoxide thereof, e.g., aluminum iso-propoxide. The resulting product may be used as a catalyst.
摘要翻译： 本发明涉及一种制备大孔合成结晶分子筛组合物的方法，该组合物可含有框架+3价元素，例如 铝，以及一种或多种a）+4价元素，例如 硅，和b）+5价元素，例如 磷。 该方法利用环己胺作为成型混合物中的定向剂。 +3价元素和任选的+4元素的来源是其醇盐，例如异丙醇铝。 所得产物可用作催化剂。
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公开(公告)号：US5091073A
公开(公告)日：1992-02-25
申请号：US552269
申请日：1990-07-13
申请人： Clarence D. Chang , Cynthia T. W. Chu , Ralph M. Dessau , John B. Higgins , John D. Lutner , John D. Schlenker
发明人： Clarence D. Chang , Cynthia T. W. Chu , Ralph M. Dessau , John B. Higgins , John D. Lutner , John D. Schlenker
IPC分类号： C01B25/36 , B01J29/84 , B01J29/85 , C01B25/45 , C01B33/12 , C01B37/04 , C01B37/08 , C01B39/04 , C01B39/06
CPC分类号： B01J29/85 , C01B37/04 , C01B37/08 , Y10S423/30
摘要： This invention relates to a novel synthetic crystalline molecular sieve composition, MCM-37, which may contain framework +3 valence element, e.g. aluminum, and +5 valence element, e.g. phosphorus or with an addition +4 valence element, e.g. silicon, and to use thereof as a support and in catalytic conversion of organic compounds. The crystalline composition of this invention can easily be converted to catalytically active material.
摘要翻译： 本发明涉及一种新型合成结晶分子筛组合物MCM-37，其可以含有框架+3价元素，例如 铝和+5价元素，例如 磷或加成+4价元素，例如 硅，并将其用作载体和有机化合物的催化转化。 本发明的结晶组合物可以容易地转化为催化活性材料。
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公开(公告)号：US5013535A
公开(公告)日：1991-05-07
申请号：US340829
申请日：1989-04-20
CPC分类号： C01B37/08 , C01B37/04 , Y10S423/30
摘要： Aluminophosphate-based molecular sieve compositions having the crystal structure of AlPO.sub.4 -54 are stabilized against framework collapse or conversion to other crystal structures by treatment in their hydrated state with boric acid or salts thereof. The stabiized products are characterized, in addition to their essential AlPO.sub.4 -54 structure, by the presence of at least 6 ppm of extraneous boron.
摘要翻译： 具有AlPO4-54晶体结构的磷酸铝基分子筛组合物通过用硼酸或其盐处理它们的水合状态而稳定，防止骨架塌陷或转化成其它晶体结构。 通过至少6ppm的外来硼的存在，除了其基本的AlPO4-54结构之外，稳定的产物被表征。
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公开(公告)号：US4938937A
公开(公告)日：1990-07-03
申请号：US58258
申请日：1987-06-04
申请人： David A. Lesch , Naomi Woodard , Robert L. Patton
发明人： David A. Lesch , Naomi Woodard , Robert L. Patton
IPC分类号： B01J20/02 , B01J27/18 , B01J29/83 , B01J29/84 , C01B25/36 , C01B37/04 , C07B61/00 , C07C1/00 , C07C4/06 , C07C4/08 , C07C5/02 , C07C5/27 , C07C5/32 , C07C6/08 , C07C15/08 , C07C67/00 , C08F4/06 , C08F4/12
摘要： A novel crystalline aluminophosphate of the molecular sieve type, denominated AlPO.sub.4 -34, is prepared by hydrothermal synthesis from reactive sources of aluminum and phosphorus and an organic templating agent.
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公开(公告)号：US4744970A
公开(公告)日：1988-05-17
申请号：US600174
申请日：1984-04-13
IPC分类号： C10G11/02 , B01J20/10 , B01J29/00 , B01J29/85 , C01B37/04 , C01B37/08 , C01B39/04 , C01B39/10 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/22 , C07C5/27 , C07C5/41 , C10G11/00 , C10G49/08 , C01B25/00 , B01J29/02 , C01B33/26
CPC分类号： C07C5/41 , B01J29/85 , C01B37/08 , C07C2/12 , C07C2/54 , C07C5/02 , C07C5/224 , C07C5/2716 , C07C2529/84
摘要： Crystalline molecular sieves having three-dimensional microporous framework structures of CoO.sub.2, AlO.sub.2, SiO.sub.2, PO.sub.2 and tetrahedral units are disclosed. These molecular sieves have an empirical chemical composition on an anhydrous basis expressed by the formula:mR: (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2wherein "R" represents at least one organic templating agent present in the intracrystalline pore system; "m" represents the molar amount of "R" present per mole of (Co.sub.w Al.sub.x P.sub.y Si.sub.z)O.sub.2 ; and "w", "x", "y" and "z" represent the mole fractions of cobalt, aluminum, phosphorus and silicon, respectively, present as tetrahedral oxides. Their use as adsorbents catalysts, etc. is also disclosed.
摘要翻译： 公开了具有CoO 2，AlO 2，SiO 2，PO 2和四面体单元的三维微孔骨架结构的结晶分子筛。 这些分子筛具有以下公式表示的无水基础上的经验化学组成：mR：（CowAlxPySiz）O 2，其中“R”表示存在于晶体内孔系统中的至少一种有机模板剂; “m”表示每摩尔（CowAlxPySiz）O 2存在的“R”摩尔量; 和“w”，“x”，“y”和“z”分别表示作为四面体氧化物存在的钴，铝，磷和硅的摩尔分数。 还公开了它们作为吸附剂催化剂等的用途。
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公开(公告)号：US4473663A
公开(公告)日：1984-09-25
申请号：US480698
申请日：1983-03-31
申请人： Robert L. Patton , Richard T. Gajek
发明人： Robert L. Patton , Richard T. Gajek
IPC分类号： B01J20/02 , B01J29/00 , B01J29/04 , B01J29/83 , C01B25/36 , C01B37/04 , B01J27/14 , B01J31/02
CPC分类号： C01B37/04
摘要： A novel crystalline aluminophosphate composition having a unique crystal structure.
摘要翻译： 具有独特晶体结构的新型结晶磷酸铝组合物。
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58.发明授权Alkali metal condensed phosphate materials,processes for preparing same and resulting compositions 失效ALKALI金属凝结磷酸盐材料，其制备方法和结果组合物
公开(公告)号：US3441374A
公开(公告)日：1969-04-29
申请号：US3441374D
申请日：1966-12-21
申请人： MONSANTO CO
发明人： SHEN CHUNG YU
IPC分类号： C01B25/38 , C01B25/39 , C01B25/41 , C01B25/42 , C01B25/445 , C01B25/45 , C01B37/04 , C02F5/08 , C11D3/06 , C01B25/30
CPC分类号： C01B25/445 , C01B25/385 , C01B25/395 , C01B25/41 , C01B25/42 , C01B25/425 , C01B25/45 , C01B37/04 , C02F5/086 , C11D3/06
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公开(公告)号：US11492264B2
公开(公告)日：2022-11-08
申请号：US16298240
申请日：2019-03-11
申请人： NGK INSULATORS, LTD.
发明人： Ryotaro Yoshimura , Aya Miura , Kenichi Noda
摘要： Seed crystals are crystals of zeolite to be attached onto a support in production of a zeolite membrane complex including the support and a zeolite membrane formed on the support. The specific surface area of the seed crystals is not smaller than 10 m2/g and not larger than 150 m2/g. The strength obtained from a crystal component at a diffraction angle 2θ indicating a maximum peak in a range of diffraction angle 2θ from 12° to 25° in an X-ray diffraction pattern obtained by emitting X-ray to the seed crystals is not less than once and not more than 30 times that obtained from an amorphous component. It is thereby possible to improve adherence of the seed crystals to the support.
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公开(公告)号：US11219879B2
公开(公告)日：2022-01-11
申请号：US14867127
申请日：2015-09-28
申请人： NGK Insulators, Ltd.
发明人： Takeshi Hagio , Makoto Miyahara , Tetsuya Uchikawa , Makiko Ichikawa , Kenichi Noda , Kenji Yajima
IPC分类号： B01J20/06 , B01D69/12 , B01D71/02 , B01D67/00 , B01J20/30 , C01B37/04 , C04B35/63 , B01D63/06 , C04B38/00 , C04B35/447 , B01J20/28 , C01B39/54 , C04B111/00
摘要： An aluminophosphate-metal oxide bonded body including a metal oxide having a bonding surface on a part of the surface thereof, and aluminophosphate that is disposed on the bonding surface of the metal oxide, wherein an alkali metal, an alkaline earth metal or both of these is/are disposed on the bonding surface of the metal oxide, and the content rate of the alkali metal, alkaline earth metal or both is from 0.3 to 30.0% by mass with respect to all of the substances that are disposed on the bonding surface of the metal oxide. An aluminophosphate-metal oxide bonded body that provides a favorable bonded state even for complicated shapes is provided.
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