公开(公告)号：US5686523A

公开(公告)日：1997-11-11

申请号：US540142

申请日：1995-10-06

Applicant: Ming J. Chen ,  Frederick D. Osterholtz ,  Eric R. Pohl ,  Antonio Chaves ,  Phil E. Ramadatt

Inventor： Ming J. Chen ,  Frederick D. Osterholtz ,  Eric R. Pohl ,  Antonio Chaves ,  Phil E. Ramadatt

IPC: C08L83/06 ,  C08J3/215 ,  C08J3/24 ,  C08K5/5415 ,  C08L43/04 ,  C08L101/10 ,  C09D143/04 ,  C09D167/00 ,  C09D201/10

CPC classification number: C09D143/04 ,  C08K5/5415 ,  C09D167/00 ,  C09D201/10

Abstract: Stable alkoxy silane containing compositions and methods for the preparation of a stable silane containing compositions comprising: (I) a water insoluble or slightly soluble alkoxy silane; (II) emulsifier; (III) water; and (IV) water dispersible or emulsified polymer containing an alkoxy silane functional group. Also provided are two part systems such that an alkoxy silane emulsion comprising components (I)-(III) are combined and the component (IV) may be added upon use of components (I) to (III). Moreover, additional components, (V), such as catalysts and pH buffers may be added.

Abstract translation: 含有稳定的烷氧基硅烷的组合物和制备含硅烷的组合物的方法，包括：（I）水不溶性或微溶性烷氧基硅烷; （II）乳化剂; （三）水; 和（IV）含有烷氧基硅烷官能团的水分散性或乳化性聚合物。 还提供了两部分系统，使得包含组分（I） - （III）的烷氧基​​硅烷乳液合并，并且组分（IV）可以在使用组分（I）至（III）时加入。 此外，可以加入另外的组分（V），例如催化剂和pH缓冲剂。

公开(公告)号：US5663215A

公开(公告)日：1997-09-02

申请号：US634221

申请日：1996-04-18

Applicant: Brian D. Milligan

Inventor： Brian D. Milligan

IPC: C09D5/16 ,  C09D183/04 ,  C09D201/10 ,  C09D143/04

CPC classification number: C09D183/04 ,  C09D201/10 ,  C09D5/1675 ,  Y10T428/31511 ,  Y10T428/31551 ,  Y10T428/31663

Abstract: A composition suitable for the production of an antifouling coating which comprises: (A) a polymer carrying pendent and/or terminal curable functional groups, at least a major proportion of the repeating units in the polymer (A) being other than siloxane units and (B) a curable organohydrogen polysiloxane or polydiorganosiloxane, the curable functional groups in component (A) being capable of undergoing a condensation curing reaction with component (B). The composition provides antifouling coating having good adhesion and mechanical durability and are used in aquatic or marine environments.

Abstract translation: 一种适于生产防污涂料的组合物，其包括：（A）携带侧链和/或末端可固化官能团的聚合物，聚合物（A）中至少大部分重复单元不是硅氧烷单元和（ B）可固化的有机氢聚硅氧烷或聚二有机硅氧烷，组分（A）中的可固化官能团能够与组分（B）进行缩合固化反应。 该组合物提供具有良好粘附性和机械耐久性的防污涂料，并用于水生或海洋环境中。

公开(公告)号：US5654360A

公开(公告)日：1997-08-05

申请号：US572614

申请日：1995-12-14

Applicant: Peter David Palasz

Inventor： Peter David Palasz

IPC: C09D133/04 ,  C09D133/06 ,  C09D143/04 ,  C09D163/00 ,  C09D167/00 ,  C09D175/00 ,  C09D201/10 ,  C08K5/04 ,  C08K5/05 ,  C08L43/04 ,  C08L63/02

CPC classification number: C09D143/04 ,  C09D133/06 ,  C09D133/068 ,  C09D201/10

Abstract: The invention provides a water-based coating composition in two pack form comprising:i) in a first pack a substantially non-aqueous solution of a silicon-containing polymer which is soluble in water miscible organic solvents and essentially soluble in aqueous media, the silicon groups on the polymer being of formula (1):--SiR.sup.1.sub.a R.sub.3-a (1) in which a is 0 to 2, R.sup.1 is Cl-6 alkyl and R is OH or a hydrolysable group, andii) in a second pack a polymer in dispersion in an aqueous liquid carrier for the composition,where the non-volatile binder solids content of the composition is at least 5% by weight and the molar concentration of silicon in the composition is greater than 0 and less than 0.5.

Abstract translation: 本发明提供了两种包装形式的水性涂料组合物，其包括：i）在第一包装中，基本上是含水聚合物的非水溶液，其可溶于水可混溶的有机溶剂并且基本上可溶于含水介质中，所述硅 聚合物上具有式（1）的基团：-SiR1aR3-a（1）其中a是0-2，R1是C1-6烷基，R是OH或可水解基团，和ii）在第二个包装中，聚合物 在组合物的水性液体载体中分散，其中组合物的非挥发性粘合剂固体含量为至少5重量％，组合物中硅的摩尔浓度大于0且小于0.5。

公开(公告)号：US5238993A

公开(公告)日：1993-08-24

申请号：US955763

申请日：1992-10-02

Applicant: Harry W. S. Hsieh

Inventor： Harry W. S. Hsieh

IPC: C09D175/06 ,  C08G18/08 ,  C08G18/42 ,  C08G18/80 ,  C09D201/02 ,  C09D201/10 ,  C09J5/02 ,  C09J175/06 ,  C09J201/10

CPC classification number: C08G18/809 ,  C08G18/0852 ,  C08G18/4211

Abstract: In one aspect, this invention is a primer comprising a solution of: (a) a polyester resin of a carboxylic acid and a glycol; (b) a polymethylene poly(phenyl isocyanate), diphenylmethane diisocyanate, or mixture thereof; and (c) a silane-containing moiety; in a solvent mixture comprising: (i) a high boiling polar solvent; (ii) an oxygenated solvent; and (iii) an aromatic solvent; wherein the weight ratio of (a):(b) is in the range of from about 0.25:1.0 to 2.0:1.0. In a second aspect, this invention is a primer comprising a solution of: (a) 5-50% of a polyester resin of a carboxylic acid and a glycol; (b) 5-50% of a polymethylene poly(phenyl isocyanate), diphenylmethane diisocyanate, or mixture thereof; (c) 0.1-50% of a silane-containing moiety; (d) 0.1-50% of a high boiling polar solvent; (e) 10-70% of an oxygenated solvent; and (f) 1-50% of an aromatic solvent. It has been discovered that the primer of the invention advantageously provides improved adhesion characteristics of metal-to-glass bonding when used to prime acid resistant paint-coated metal substrates before applying a urethane adhesive, particularly when used with a "fast cure" adhesive comprising an isocyanate-functional prepolymer and dimorpholinediethyl ether.

Abstract translation: 一方面，本发明是一种底漆，其包含以下溶液：（a）羧酸和二醇的聚酯树脂; （b）聚亚甲基聚（苯基异氰酸酯），二苯基甲烷二异氰酸酯或其混合物; 和（c）含硅烷的部分; 在溶剂混合物中，包括：（i）高沸点极性溶剂; （ii）氧化溶剂; 和（iii）芳族溶剂; 其中（a）：（b）的重量比在约0.25:1.0-2.0:1.0的范围内。 在第二方面，本发明是一种底漆，其包含以下溶液：（a）5-50％的羧酸和二醇的聚酯树脂; （b）5-50％的聚亚甲基聚（苯基异氰酸酯），二苯基甲烷二异氰酸酯或其混合物; （c）0.1-50％的含硅烷部分; （d）0.1-50％的高沸点极性溶剂; （e）10-70％的氧化溶剂; 和（f）1-50％的芳族溶剂。 已经发现，本发明的底漆在施加氨基甲酸乙酯粘合剂之前，特别是当与“快速固化”粘合剂一起使用时，有利地提供金属对玻璃粘合剂的改善的粘合特性，所述粘合特性用于在耐酸漆涂覆的金属基材上浇注， 异氰酸酯官能预聚物和二吗啉二乙醚。

公开(公告)号：US4826904A

公开(公告)日：1989-05-02

申请号：US124237

申请日：1987-11-23

Applicant: Shoichi Matsumura ,  Toshiro Nanbu ,  Hisao Furukawa

Inventor： Shoichi Matsumura ,  Toshiro Nanbu ,  Hisao Furukawa

IPC: C09D137/00 ,  C09D143/04 ,  C09D157/06 ,  C09D201/02 ,  C09D201/10 ,  C08K5/11

CPC classification number: C09D157/06 ,  C09D143/04 ,  C09D201/10

Abstract: A coating composition comprising:(A) 100 parts by weight of a vinyl polymer having on the main polymer chain end or a side chain thereof at least one silyl group containing a silicon atom to which a hydrolyzable group is linked, per one polymer molecule, the main chain of the vinyl polymer consisting essentially of a polymer of a vinyl monomer,(B) 0 to 10 parts by weight of a curing catalyst,(C) 0 to 10 parts by weight of a hydrolyzable ester compound, and(D) 0.5 to 100 parts by weight of a dialkyl ester of dibasic acid having the formula (1): ##STR1## The coating composition of the present invention has excellent adhesion to under coats, and therefore it is suitable for use as automotive refinishing paints and industrial coatings.

Abstract translation: 一种涂料组合物，其包含：（A）100重量份在每个聚合物分子上在主聚合物链末端或其侧链上含有至少一个含有可水解基团的硅原子的甲硅烷基的乙烯基聚合物， 乙烯基聚合物的主链基本上由乙烯基单体的聚合物组成，（B）0至10重量份的固化催化剂，（C）0至10重量份的可水解的酯化合物，和（D） 0.5〜100重量份具有式（1）的二元酸二烷基酯：（1）本发明的涂料组合物与涂层下的粘合性优异，因此适用于汽车修补 涂料和工业涂料。

公开(公告)号：US12129347B2

公开(公告)日：2024-10-29

申请号：US18326244

申请日：2023-05-31

Applicant: CHEM LINK, INC.

Inventor： Baljinder Kaur ,  Jonathan Ballema

IPC: C08J3/24 ,  C08G63/91 ,  C09D201/10 ,  C09J183/00 ,  C09J183/04 ,  C09J183/10 ,  C09J185/00 ,  C09J201/10 ,  C09K3/10 ,  C08G77/12 ,  C08G77/20

CPC classification number: C08J3/24 ,  C08G63/91 ,  C09D201/10 ,  C09J183/00 ,  C09J183/04 ,  C09J183/10 ,  C09J185/00 ,  C09J201/10 ,  C09K3/1018 ,  C08G77/12 ,  C08G77/20 ,  C08J2333/06 ,  C08J2333/12 ,  C08J2347/00 ,  C08J2367/00 ,  C08J2371/00 ,  C08J2381/04 ,  C08J2383/04

Abstract: The invention described herein generally pertains to a composition that includes a silyl-terminated polymer having silyl groups linked to a polymer backbone via triazole. The silyl-terminated polymer is a reaction product of a functionalized polymer backbone and a functionalized silane. The polymer backbone includes a first functional group, which may be one of an azide or an alkyne. The functionalized silane includes a second functional group may also be one of an azide or an alkyne, but is also different from the first functional group. The functionalized polymer backbone is reacted with the functionalized silane in the presence of a metal catalyst.

公开(公告)号：US12071563B2

公开(公告)日：2024-08-27

申请号：US17038304

申请日：2020-09-30

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Kiyotaka Takao ,  Kazue Toda ,  Kenji Ishizeki ,  Akira Isobe

IPC: C09D201/04 ,  B32B33/00 ,  C07F7/18 ,  C08F259/08 ,  C08G65/00 ,  C08G65/329 ,  C08G65/336 ,  C09D171/00 ,  C09D201/10

CPC classification number: C09D201/04 ,  B32B33/00 ,  C07F7/1804 ,  C08F259/08 ,  C08G65/007 ,  C08G65/329 ,  C08G65/336 ,  C09D171/00 ,  C09D201/10 ,  B32B2307/7265 ,  B32B2307/746

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.

公开(公告)号：US11932782B2

公开(公告)日：2024-03-19

申请号：US17638569

申请日：2020-08-20

Applicant: SHIN-ETSU CHEMICAL CO., LTD.

Inventor： Taiki Katayama ,  Tetsuro Yamada ,  Munenao Hirokami

IPC: C09D7/63 ,  C08K5/544 ,  C08L83/08 ,  C08L101/10 ,  C09D7/48 ,  C09D7/65 ,  C09D183/08 ,  C09D201/10

CPC classification number: C09D7/63 ,  C08K5/544 ,  C08L83/08 ,  C08L101/10 ,  C09D7/48 ,  C09D7/65 ,  C09D183/08 ,  C09D201/10 ,  C09D201/10 ,  C08K5/544 ,  C09D201/10 ,  C08L83/08

Abstract: The present invention is a room temperature curable resin composition comprising: as the main agent, an organic polymer in which both molecular chain terminals are sealed by a silanol group and/or a hydrolyzable silyl group; and an organic silicon compound of a specific structure having, in a molecule, an organosiloxane structure, a hydrolyzable silyl group, and a hindered amine skeleton. This resin composition produces a cured product in which the degradation over time associated with the effects of light such as UV rays can be suppressed.

公开(公告)号：US11739225B2

公开(公告)日：2023-08-29

申请号：US16533647

申请日：2019-08-06

Applicant: The Boeing Company

Inventor： Vijaykumar S. Ijeri ,  Om Prakash ,  Stephen P. Gaydos ,  Raghavan Subasri ,  Kalidindi Ramachandra Soma Raju ,  Dendi Sreenivas Reddy

IPC: C09D5/08 ,  C09D7/65 ,  C09D7/80 ,  C23C18/12 ,  C08K3/32 ,  C09D5/10 ,  C09D183/08 ,  C09D5/00 ,  C09D5/03 ,  C09D7/40 ,  C09D201/10 ,  C08K3/18 ,  C08K3/28

CPC classification number: C09D5/08 ,  C08K3/32 ,  C09D5/106 ,  C09D7/65 ,  C09D7/80 ,  C09D183/08 ,  C23C18/122 ,  C23C18/1216 ,  C23C18/1225 ,  C23C18/1254 ,  C08K3/18 ,  C08K3/28 ,  C08K2003/328 ,  C08K2201/011 ,  C09D5/002 ,  C09D5/038 ,  C09D7/67 ,  C09D201/10 ,  C23C2222/20

Abstract: A layered tetravalent metal phosphate composition (e.g., a layered zirconium phosphate composition) and a first corrosion inhibitor (e.g., cerium (III), a vanadate, a molybdate, a tungstate, a manganous, a manganate, a permanganate, an aluminate, a phosphonate, a thiazole, a triazole, and/or an imidazole) is dispersed in an aqueous solution and stirred to form a first solution. A precipitate of the first solution is collected and washed to form a first corrosion inhibiting material (CIM), which includes the first corrosion inhibitor intercalated in the layered tetravalent metal phosphate composition. The first CIM is added to a first sol-gel composition to form a first CIM-containing sol-gel composition. The first CIM-containing sol-gel composition is applied on a substrate to form a CIM-containing sol-gel layer, cured by UV radiation, and thermally cured to form a corrosion-resistant coating. One or more additional sol-gel composition may be applied on the substrate.

公开(公告)号：US11643572B2

公开(公告)日：2023-05-09

申请号：US17118665

申请日：2020-12-11

Applicant: AGC Inc.

Inventor： Taiki Hoshino ,  Kiyotaka Takao ,  Kazue Toda ,  Kenji Ishizeki ,  Akira Isobe

IPC: C09D201/04 ,  C08G65/336 ,  C08G65/00 ,  C08G65/329 ,  C07F7/18 ,  C09D171/00 ,  B32B33/00 ,  C08F259/08 ,  C09D201/10

CPC classification number: C09D201/04 ,  B32B33/00 ,  C07F7/1804 ,  C08F259/08 ,  C08G65/007 ,  C08G65/329 ,  C08G65/336 ,  C09D171/00 ,  C09D201/10 ,  B32B2307/7265 ,  B32B2307/746

Abstract: To provide a fluorinated ether compound, a fluorinated ether composition and a coating liquid that are able to form a surface layer which is excellent in water/oil repellency, abrasion resistance, fingerprint stain removability, lubricity and outer appearance, and an article having such a surface layer. A fluorinated ether compound represented by A1-O—(Rf1O)m1-Q1-[C(O)N(R1)]p1—R11—C[—R12—SiR13n1X13-n1]3, wherein A1 is a C1-20 perfluoroalkyl group; Rf1 is a fluoroalkylene group having no branched structure; m1 is an integer from 2 to 210; Q1 is a single bond or a fluoroalkylene group having no branched structure; R1 is a hydrogen atom, etc.; p1 is 0 or 1; R11 is a single bond, an alkylene group, etc.; R12 is an alkylene group, etc.; R13 is a monovalent hydrocarbon group, etc.; X1 is a hydrolyzable group; and n1 is an integer of from 0 to 2.