ADHESIVES COMPRISING EPOXY-ACID CROSSLINKED GROUPS AND METHODS
    68.
    发明申请
    ADHESIVES COMPRISING EPOXY-ACID CROSSLINKED GROUPS AND METHODS 审中-公开
    包含环氧交联基团的粘合剂和方法

    公开(公告)号:US20150368524A1

    公开(公告)日:2015-12-24

    申请号:US14758987

    申请日:2014-03-03

    Abstract: Adhesive compositions and methods of preparing an adhesive composition are described. The method comprises providing a syrup composition comprising a free-radically polymerizable solvent monomer and a solute (meth)acrylic copolymer, and radiation curing the syrup composition in the absence of an ionic photoacid generator. The solute (meth)acrylic copolymer comprises epoxy-functional groups, acid-functional groups, or a combination thereof. In some embodiments, an epoxy resin having on average greater than one polymerizable epoxy group per molecule or an acid comprising at least two carboxylic acid groups is utilized. The epoxy-functional groups and acid-functional groups of the (meth)acrylic copolymer or the adhesive composition can readily crosslink in the absence of an ionic photoacid generator (PAG).

    Abstract translation: 描述了粘合剂组合物和制备粘合剂组合物的方法。 该方法包括提供包含可自由基聚合的溶剂单体和溶质(甲基)丙烯酸共聚物的糖浆组合物,并且在不存在离子型光酸产生剂的情况下辐射固化糖浆组合物。 溶质(甲基)丙烯酸共聚物包含环氧官能团,酸官能团或其组合。 在一些实施方案中,使用每分子平均具有大于1个可聚合环氧基团的环氧树脂或包含至少两个羧酸基团的酸。 (甲基)丙烯酸共聚物或粘合剂组合物的环氧官能团和酸官能团可以在不存在离子光酸产生剂(PAG)的情况下容易地交联。

    MULTILAYER PRESSURE-SENSITIVE ADHESIVE FILMS WITH A (METH)ACRYLIC-BASED ELASTOMERIC MATERIAL
    69.
    发明申请
    MULTILAYER PRESSURE-SENSITIVE ADHESIVE FILMS WITH A (METH)ACRYLIC-BASED ELASTOMERIC MATERIAL 审中-公开
    具有(甲基)丙烯酸的弹性体材料的多层压敏粘合膜

    公开(公告)号:US20140367040A1

    公开(公告)日:2014-12-18

    申请号:US14344800

    申请日:2012-09-24

    Abstract: The present invention is directed to a multilayer pressure sensitive adhesive (PSA) film, having a first pressure sensitive adhesive layer and at least an opposing layer, wherein the first pressure sensitive adhesive layer comprises a pressure-sensitive adhesive composition with a (meth)acrylic-based elastomeric material comprising a reaction product of polymerizable material comprising: (a) a first monomer which is an alkyl (meth)acrylate ester of a primary alcohol R1—OH, the alkyl (meth)acrylate ester being of Formula (I) CH2═C(R2)—(CO)—OR1 (I) wherein R1 is an alkyl having 14 to 25 carbon atoms and the primary alcohol R1—OH has an iso index equal to at least 2 but no greater than 4; R2 is hydrogen or methyl; and (b) a second monomer having an ethylenically unsaturated group; wherein the at least one opposing layer comprises at least one filler material. The invention is also directed to a method for the manufacturing of such a multilayer PSA film and its use.

    Abstract translation: 本发明涉及具有第一压敏粘合剂层和至少相对层的多层压敏粘合剂(PSA)膜,其中第一压敏粘合剂层包含具有(甲基)丙烯酸类的压敏粘合剂组合物 其包含可聚合材料的反应产物,其包含:(a)第一单体,其为伯醇R 1 -OH的(甲基)丙烯酸烷基酯,(I)(甲基)丙烯酸烷基酯 ≡C(R2) - (CO)-OR1(Ⅰ)其中R1是具有14-25个碳原子的烷基,伯醇R1-OH具有等于至少2但不大于4的iso指数; R2是氢或甲基; 和(b)具有烯属不饱和基团的第二单体; 其中所述至少一个相对层包括至少一种填料。 本发明还涉及制造这种多层PSA膜的方法及其用途。

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