Biological reactor
    61.
    发明授权
    Biological reactor 失效
    生物反应器

    公开(公告)号:US5217900A

    公开(公告)日:1993-06-08

    申请号:US380730

    申请日:1989-07-13

    IPC分类号: C12M1/00 C12M1/40

    摘要: A biological reactor which is operated using microorganisms and/or enzymes and used for the oxidative conversion of organic compounds, and in which the organic compounds to be converted are employed in the presence of a biocatalyst in the reactor space (4) (anode space) and the enzymes are regenerated at a polarized electrode (1), the polarization of the electrode (1) being effected by means of a catalyst electrode (2) which is separated from the reactor space (4) by a polyelectrolyte (3) and is located in an electrolyte space (5), wherein the electrode (1) is prepared from an electrically conductive carbon material which has been partially oxidized on the surface at a potential .epsilon..sub.h of from +1.3 to +10 V in an aqueous oxygen-containing mineral acid.

    摘要翻译: 使用微生物和/或酶操作并用于有机化合物的氧化转化的生物反应器,其中待转化的有机化合物在反应器空间(4)(阳极空间)中的生物催化剂存在下使用, 并且酶在极化电极(1)再生,电极(1)的极化通过由聚电解质(3)与反应器空间(4)分离的催化剂电极(2)进行,并且是 位于电解质空间(5)中,其中所述电极(1)由导电碳材料制备,所述导电碳材料在表面上在含氧含氧量的水溶液中以+1.3至+10V的电位εh部分氧化 无机酸。

    Azolylnitriles, and fungicides containing these compounds
    70.
    发明授权
    Azolylnitriles, and fungicides containing these compounds 失效
    腈基腈和含有这些化合物的杀真菌剂

    公开(公告)号:US4639447A

    公开(公告)日:1987-01-27

    申请号:US741112

    申请日:1985-06-04

    摘要: Compounds of the formula ##STR1## where R.sup.2 is a 5-membered or 6-membered heterocyclic structure possessing one or two hetero atoms or is phenyl which is unsubstituted or substituted by R.sub.n, R is hydrogen, alkyl, alkoxy, alkylthio, alkylsulfonyl, halogen, haloalkyl, nitro, cyano, unsubstituted or substituted phenyl, unsubstituted or substituted phenoxy or unsubstituted or substituted amino, R.sup.1 is alkyl, cycloalkyl, cycloalkylalkyl, unsubstituted or substituted aryl, unsubstituted or substituted aralkyl, unsubstituted or substituted aryloxyalkyl, unsubstituted or substituted benzyloxyalkyl, unsubstituted or substituted alkenyl, unsubstituted or substituted alkynyl or (CH.sub.2 --CH.sub.2 O).sub.m --R.sup.4, where R.sup.4 is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted aryl or unsubstituted or substituted benzyl and m is 1, 2, 3 or 4, Het is 1,2,4-triazol-1-yl, imidazol-1-yl or pyrid-3-yl, n is 1, 2, 3, 4 or 5, Z is CH.sub.2, oxygen, SO.sub.t or (R.sup.3 N), where t is 0, 1 or 2 and R.sup.3 has the same meanings as R.sup.1 and is identical to or different from R.sup.1 or together with R.sup.1 forms a diradical of the formula --(CH.sub.2).sub.k -- X--(CH.sub.2).sub.1 --, where k and 1 independently of one another are each 1, 2, 3, 4 or 5, and X is O, S or NH, or Z--R.sup.1 is unsubstituted or substituted phenyl, and their plant-tolerated acid addition salts, and fungicides containing them.

    摘要翻译: 式(I)的化合物,其中R 2是具有一个或两个杂原子的5元或6元杂环结构,或者是未被取代或被R n取代的苯基,R是氢,烷基,烷氧基,烷硫基, 烷基磺酰基,卤素,卤代烷基,硝基,氰基,未取代或取代的苯基,未取代或取代的苯氧基或未取代或取代的氨基,R1是烷基,环烷基,环烷基烷基,未取代或取代的芳基,未取代或取代的芳烷基,未取代或取代的芳氧基烷基, 取代的苄氧基烷基,未取代或取代的烯基,未取代或取代的炔基或(CH 2 -CH 2 O)m -R 4,其中R 4是C 1 -C 4烷基,未取代或取代的芳基或未取代或取代的苄基,m是1,2,3或4 ,Het为1,2,4-三唑-1-基,咪唑-1-基或吡啶-3-基,n为1,2,3,4或5,Z为CH 2,氧,SOt或(R 3 N) 其中t是0,1或2,R3与R1具有相同的含义,与o相同 r不同于R 1或与R 1一起形成式 - (CH 2)k -X-(CH 2)1的双基,其中k和1彼此独立地各自为1,2,3,4或5,并且X 是O,S或NH,或Z-R 1是未取代或取代的苯基,以及它们的植物耐受酸加成盐和含有它们的杀真菌剂。