公开(公告)号：US20120208691A1

公开(公告)日：2012-08-16

申请号：US13501811

申请日：2010-10-11

Applicant: Ivor Bull ,  Ulrich Müller ,  Bilge Yilmaz

Inventor： Ivor Bull ,  Ulrich Müller ,  Bilge Yilmaz

IPC: B01J29/76 ,  B01D53/56 ,  B01D53/94 ,  C01B39/02 ,  B01D53/58

CPC classification number: B01J29/76 ,  B01D53/9409 ,  B01D53/9418 ,  B01D53/9459 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/904 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2258/012 ,  B01J29/064 ,  B01J29/072 ,  B01J29/70 ,  B01J29/72 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J35/002 ,  B01J37/0009 ,  B01J37/10 ,  B01J2229/186 ,  B01J2229/36 ,  Y02C20/10

Abstract: Aspects of the present invention relates to a copper containing Levyne molecular sieve having a silica to alumina mole ratio less than 30 and a Cu:Al atomic ratio less than 0.45, wherein the Levyne molecular sieve retains at least 60% of its surface area after exposure to a temperature of from about 750° C. to about 950° C. in the present of up to 10 volume percent water vapor for a time ranging from about 1 to about 48 hours.

Abstract translation: 本发明的方面涉及二氧化硅与氧化铝的摩尔比小于30且Cu:Al原子比小于0.45的含铜Levyne分子筛，其中Levyne分子筛在曝光后保持其表面积的至少60％ 在约10体积％的水蒸气中存在约750℃至约950℃的温度，时间范围为约1至约48小时。

公开(公告)号：US20120141685A1

公开(公告)日：2012-06-07

申请号：US13313122

申请日：2011-12-07

Applicant: Manuela Gaab ,  Andrea Weber ,  Milan Kostur ,  Ulrich Müller

Inventor： Manuela Gaab ,  Andrea Weber ,  Milan Kostur ,  Ulrich Müller

IPC: B05D3/02 ,  B05D1/36

CPC classification number: D21H19/10 ,  D21H19/02

Abstract: Described is a process for coating at least part of a surface of a support with a porous metal-organic framework comprising at least one at least bidentate organic compound coordinated to at least one metal ion, which process comprises the steps (a) spraying of the at least one part of the support surface with a first solution comprising the at least one metal ion; (b) spraying of the at least one part of the support surface with a second solution comprising the at least one at least bidentate organic compound, wherein step (b) is carried out before, after or simultaneously with step (a), to form a layer of the porous metal-organic framework.

Abstract translation: 描述了一种用多孔金属 - 有机骨架涂覆载体表面的至少一部分的方法，所述多孔金属 - 有机骨架包含至少一种与至少一种金属离子配位的至少二齿有机化合物，该方法包括步骤（a） 所述支撑表面的至少一部分具有包含所述至少一种金属离子的第一溶液; （b）用包含至少一种至少二齿有机化合物的第二溶液喷洒至少一部分载体表面，其中步骤（b）在步骤（a）之前或之后进行，以形成 一层多孔金属 - 有机骨架。

公开(公告)号：US20110313226A1

公开(公告)日：2011-12-22

申请号：US13163430

申请日：2011-06-17

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Bibiana Andrea Betancur Moreno ,  Hermann Gies ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Meike Pfaff ,  Bin Xie ,  Haiyan Zhang

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Bibiana Andrea Betancur Moreno ,  Hermann Gies ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Meike Pfaff ,  Bin Xie ,  Haiyan Zhang

IPC: C07C1/20 ,  C07C2/00 ,  B01D53/94 ,  C01B39/00 ,  B01D53/56

CPC classification number: C01B39/48 ,  B01D2253/108 ,  B01D2255/50 ,  B01J20/186 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J20/3007 ,  B01J20/3042 ,  B01J29/70 ,  C01B37/02 ,  C01B39/46 ,  C10G3/49 ,  C10G11/18 ,  C10G25/03 ,  C10G2300/405 ,  C10G2300/70 ,  Y02P30/20

Abstract: Described is a process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises: (1) preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and (2) crystallizing the mixture obtained in step (1);wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises one or more alkali metals M, wherein the molar ratio of the total amount of the one or more solvents to the total amount of the one or more sources for YO2 based on YO2 is 9.5 or less, and wherein for crystallization temperatures of 175° C. or higher in step (2), the duration of crystallization at those temperatures is less than 14 d, as well as to a zeolitic material, preferably being obtainable or obtained according to the inventive process, said zeolitic material having an LEV-type framework structure comprising YO2 and X2O3, wherein the zeolitic material optionally comprises one or more alkali metals M, and wherein the zeolitic material displays an Y:X atomic ratio of from 1 to 9.4.

Abstract translation: 描述了一种生产具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括：（1）制备包含一种或多种YO 2，一种或多种溶剂的来源的混合物，以及 任选地包含晶种; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，其中沸石材料任选地包含一种或多种碱金属M，其中一种或多种溶剂的总量与一种或多种溶剂的总量的摩尔比 基于YO 2的YO 2的来源为9.5或更低，并且其中对于步骤（2）中的结晶温度为175℃或更高的温度，在这些温度下的结晶持续时间小于14天，以及沸石材料， 所述沸石材料具有包含YO 2和X 2 O 3的LEV型骨架结构，其中所述沸石材料任选地包含一种或多种碱金属M，并且其中所述沸石材料显示Y：X原子 比例为1〜9.4。

公开(公告)号：US20110312486A1

公开(公告)日：2011-12-22

申请号：US13163377

申请日：2011-06-17

Applicant: Bilge Yilmaz ,  Ulrich Müller ,  Meike Pfaff ,  Hermann Gies ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Hiroyuki Imai ,  Bin Xie ,  Haiyan Zhang

Inventor： Bilge Yilmaz ,  Ulrich Müller ,  Meike Pfaff ,  Hermann Gies ,  Feng-Shou Xiao ,  Takashi Tatsumi ,  Xinhe Bao ,  Weiping Zhang ,  Dirk de Vos ,  Hiroyuki Imai ,  Bin Xie ,  Haiyan Zhang

IPC: B01J29/04 ,  C07C1/20 ,  B01D53/56 ,  C07C2/00 ,  C01B39/00 ,  B01D53/94

CPC classification number: C01B39/46 ,  B01D53/9418 ,  B01D2251/2067 ,  B01D2253/108 ,  B01D2253/3425 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/50 ,  B01D2255/9207 ,  B01D2257/402 ,  B01D2257/404 ,  B01D2257/406 ,  B01D2258/012 ,  B01J20/186 ,  B01J20/28011 ,  B01J20/2803 ,  B01J20/28042 ,  B01J20/28057 ,  B01J29/70 ,  B01J2229/186 ,  C01B37/02 ,  C01B39/48 ,  C01P2006/12 ,  C07C1/20 ,  C07C2529/70 ,  C07C2529/80 ,  C10G3/49 ,  C10G11/18 ,  C10G25/03 ,  C10G2300/405 ,  C10G2300/70 ,  Y02C20/10 ,  Y02P20/153 ,  Y02P20/52 ,  Y02P30/20

Abstract: Described is a process for the production of a zeolitic material having an LEV-type framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises (1) preparing a mixture comprising one or more sources for YO2, one or more solvents, and optionally comprising seed crystals; and (2) crystallizing the mixture obtained in step (1); wherein Y is a tetravalent element, and X is a trivalent element, and wherein the mixture crystallized in step (2) contains 3 wt.-% or less of one or more metals M based on 100 wt-% of YO2, preferably 1 wt.-% or less, more preferably 0.5 wt.-% or less, more preferably 0.1 wt.-% or less, more preferably 0.05 wt.-% or less, more preferably 0.01 wt.-% or less, more preferably 0.005 wt.-% or less, more preferably 0.001 wt.-% or less, more preferably 0.0005 wt.-% or less, more preferably 0.0001 wt.-% or less of one or more metals M based on 100 wt.-% of YO2, wherein even more preferably the mixture crystallized in step (2) contains no metal M, wherein M stands for sodium or potassium, preferably for sodium and potassium, more preferably for the group of alkali metals, wherein even more preferably M stands for the group of alkali and alkaline earth metals.

Abstract translation: 描述了一种制备具有包含YO 2和任选地包含X 2 O 3的LEV型骨架结构的沸石材料的方法，其中所述方法包括（1）制备包含一种或多种YO 2，一种或多种溶剂来源的混合物， 包括晶种; 和（2）使步骤（1）中获得的混合物结晶; 其中Y是四价元素，X是三价元素，并且其中步骤（2）中结晶的混合物含有基于100重量％的YO 2，优选1重量％的3重量％或更少的一种或多种金属M 更优选为0.5重量％以下，更优选为0.1重量％以下，更优选为0.05重量％以下，更优选为0.01重量％以下，更优选为0.005重量％ 更优选0.001重量％以下，更优选0.0005重量％以下，更优选0.0001重量％以下的一种或多种金属M，基于100重量％的YO 2 其中甚至更优选在步骤（2）中结晶的混合物不含金属M，其中M代表钠或钾，优选钠和钾，更优选碱金属组，其中甚至更优选M代表基团 的碱金属和碱土金属。

公开(公告)号：US20100003173A1

公开(公告)日：2010-01-07

申请号：US12556961

申请日：2009-09-10

Applicant: Ulrich Müller ,  Georg Krug ,  Peter Rudolf ,  Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Bassler

Inventor： Ulrich Müller ,  Georg Krug ,  Peter Rudolf ,  Joaquim Henrique Teles ,  Hans-Georg Göbbel ,  Peter Bassler

IPC: B01J8/02 ,  B01J29/06

CPC classification number: C07D301/12 ,  Y02P20/52

Abstract: Process for preparing propylene oxide, which comprises at least the steps (i) and (ii): (i) providing a catalyst comprising at least one porous oxidic material; (ii) reacting propene with a hydroperoxide in at least one nitrile as solvent or in a solvent mixture comprising at least one nitrile in the presence of the catalyst of (i), wherein the at least one porous oxidic material is a zeolite which is assigned X-ray-crystallographically to the MWW type.

Abstract translation: 制备环氧丙烷的方法，其至少包括步骤（i）和（ii）：（i）提供包含至少一种多孔氧化物质的催化剂; （ii）使丙烯与至少一种腈作为溶剂中的氢过氧化物反应或在包含至少一种腈的溶剂混合物中，在（i）的催化剂存在下反应，其中所述至少一种多孔氧化物质是被分配的沸石 X射线晶体学到MWW型。

公开(公告)号：US07265487B2

公开(公告)日：2007-09-04

申请号：US10852126

申请日：2004-05-25

Applicant: Günter Huber ,  Frank Jermann ,  Ulrich Müller ,  Martin Zachau

Inventor： Günter Huber ,  Frank Jermann ,  Ulrich Müller ,  Martin Zachau

IPC: H01J1/62 ,  H01J63/04

CPC classification number: H01J61/48 ,  C09K11/0883 ,  C09K11/666 ,  C09K11/7721 ,  C09K11/7734 ,  C09K11/7739 ,  C09K11/7774 ,  C09K11/7777 ,  C09K11/778 ,  C09K11/7787 ,  C09K11/7792 ,  H01J61/44 ,  H01J65/046

Abstract: A discharge lamp (1) having a discharge vessel (2) which surrounds a discharge medium which emits electromagnetic radiation in the VUV region when the lamp is operating has, on the inner side of the discharge vessel wall, a first phosphor layer, which faces the discharge medium and comprises a UVA component which can be excited by the VUV radiation and is intended to emit electromagnetic radiation in the UVA region. A second phosphor layer, which can be excited by the UVA radiation and is intended to emit electromagnetic radiation in the visible region either lies beneath the first phosphor layer or is applied to the outer side of the discharge vessel wall. This results in a lower color locus shift compared to a conventional phosphor mixture, which can be excited directly by VUV radiation.

Abstract translation: 具有放电容器（2）的放电灯（1），其在灯工作时在VUV区域内发射电磁辐射的放电介质的放电容器（2）在放电容器壁的内侧具有第一荧光体层 该放电介质包括可被VUV辐射激发并且旨在在UVA区域中发射电磁辐射的UVA分量。 可以被UVA辐射激发并且旨在在可见光区域发射电磁辐射的第二磷光体层位于第一荧光体层的下面或者被施加到放电容器壁的外侧。 与常规的荧光体混合物相比，这会导致较低的颜色轨迹位移，这可以通过VUV辐射直接激发。

公开(公告)号：US07211239B2

公开(公告)日：2007-05-01

申请号：US11111871

申请日：2005-04-22

Applicant: Ulrich Müller ,  Lian Ma ,  Xiao Feng-Shou ,  Xiaoyu Yang

Inventor： Ulrich Müller ,  Lian Ma ,  Xiao Feng-Shou ,  Xiaoyu Yang

IPC: C01B39/02

CPC classification number: C01B37/005 ,  C01B39/04 ,  C01B39/40 ,  C01B39/48 ,  Y10S423/22 ,  Y10S423/27

Abstract: A process for preparing a zeolitic material, comprising (i) preparing a mixture comprising the at least one silicon containing precursor compound from which the zeolitic framework is formed, at least one pore forming agent, and at least one polymer which has an essentially spheroidal geometry in the mixture; (ii) crystallizing the zeolitic material from the mixture obtained in (i) to obtain the crystallized zeolitic material in its mother liquor.

Abstract translation: 一种制备沸石材料的方法，包括（i）制备包含所述至少一种含硅的前体化合物的混合物，所述至少一种含有硅沸石骨架的前体化合物由其形成，至少一种成孔剂和至少一种具有基本上球形几何形状的聚合物 在混合物中 （ii）从（i）中获得的混合物中结晶沸石材料，得到其母液中的结晶沸石材料。

公开(公告)号：US20060217576A1

公开(公告)日：2006-09-28

申请号：US10555985

申请日：2004-05-10

Applicant: Ulrich Müller ,  Peter Bassler ,  Joaquim Teles ,  Norbert Rieber

Inventor： Ulrich Müller ,  Peter Bassler ,  Joaquim Teles ,  Norbert Rieber

IPC: C07C27/10 ,  B01J8/04 ,  B01J8/02 ,  B01J10/00

CPC classification number: C07D301/19 ,  B01J8/04 ,  B01J8/20 ,  B01J19/2495 ,  B01J29/40 ,  B01J29/70 ,  B01J29/89 ,  B01J35/0006 ,  B01J2208/00884 ,  B01J2208/025 ,  B01J2219/0004 ,  C07D301/12

Abstract: Process for the catalyzed reaction of an organic compound with a hydroperoxide in at least one reactor using at least two different zeolite catalysts, wherein at least two of the different zeolite catalysts are used physically separately from one another.

公开(公告)号：US07015246B2

公开(公告)日：2006-03-21

申请号：US10471444

申请日：2002-10-10

Applicant: Carsten Schmeck ,  Ulrich Müller ,  Gunter Schmidt ,  Josef Pernerstorfer ,  Hilmar Bischoff ,  Axel Kretschmer ,  Verena Vöhringer ,  Christiane Faeste ,  Helmut Haning ,  Markus Hauswald ,  Delf Schmidt ,  Martin Zoche ,  Heiner Apeler ,  Willi Jonghaus ,  Peter Reinemer

Inventor： Carsten Schmeck ,  Ulrich Müller ,  Gunter Schmidt ,  Josef Pernerstorfer ,  Hilmar Bischoff ,  Axel Kretschmer ,  Verena Vöhringer ,  Christiane Faeste ,  Helmut Haning ,  Markus Hauswald ,  Delf Schmidt ,  Martin Zoche ,  Heiner Apeler ,  Willi Jonghaus ,  Peter Reinemer

IPC: C07D307/79 ,  A61K31/343

CPC classification number: C07D307/85 ,  C07D307/80 ,  C07D307/84

Abstract: The invention relates to novel benzofuran derivatives, to processes for preparing them and to their uses in medicaments.

Abstract translation: 本发明涉及新的苯并呋喃衍生物，其制备方法及其在药物中的用途。

公开(公告)号：US06943274B2

公开(公告)日：2005-09-13

申请号：US10505705

申请日：2003-02-28

Applicant: Werner Peschel ,  Till Adrian ,  Harald Rust ,  Arnd Böttcher ,  Thomas Hill ,  Ulrich Müller ,  Rainer Papp

Inventor： Werner Peschel ,  Till Adrian ,  Harald Rust ,  Arnd Böttcher ,  Thomas Hill ,  Ulrich Müller ,  Rainer Papp

IPC: C07C5/11 ,  C07B61/00 ,  C07C29/04 ,  C07C35/08 ,  C07C29/20

CPC classification number: C07C29/04 ,  C07C2601/14 ,  C07C35/08

Abstract: A process for preparing cyclohexanol from benzene by: a) preparing cyclohexene by hydrogenating benzene in the presence of a catalyst, and b) preparing cyclohexanol by hydrating the cyclohexene in the presence of a catalyst, comprises: carrying out steps a) and b) in a reaction facility which has a bottom region at the lower end, a top region at the upper end, and a reaction zone between the top region and the bottom region which contains the catalyst according to steps a) and b), evaporating a portion of the benzene using the heat of reaction in the reaction zone, condensing it in the top region and returning it to the reaction zone, and withdrawing a reaction mixture containing cyclohexanol in the bottom region.

Abstract translation: 一种通过以下步骤由苯制备环己醇的方法：a）在催化剂存在下，通过氢化苯来制备环己烯，和b）通过在催化剂存在下使环己烯水合制备环己醇，包括：进行步骤a）和b） 具有下端的底部区域，上端的顶部区域和顶部区域和底部区域之间的反应区域的反应设备，其包含根据步骤a）和b）的催化剂，蒸发一部分 苯在反应区中使用反应热，在顶部区域冷凝并将其返回到反应区，并在底部区域中抽出含有环己醇的反应混合物。