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    Thin multi-stage catalytic reactor with internal heat exchanger, and use thereof
    63.
    发明申请
    Thin multi-stage catalytic reactor with internal heat exchanger, and use thereof 有权
    具有内部热交换器的薄型多级催化反应器及其应用

    公开(公告)号：US20020159933A1

    公开(公告)日：2002-10-31

    申请号：US10084493

    申请日：2002-02-28

    Applicant: Institut Francais du Petrole

    Inventor： Frederic Hoffmann ,  Eric Lenglet ,  Philippe Mege

    IPC: B01J008/12 ,  B01J008/02

    CPC classification number: B01J8/085 ,  B01J8/003 ,  B01J8/004 ,  B01J8/0426 ,  B01J8/0496 ,  B01J8/125 ,  B01J2208/00168 ,  B01J2219/185 ,  B01J2219/1943

    Abstract: An elongate reaction vessel includes at least two stages in the vertical direction in which an endothermic or exothermic catalytic reaction is carried out and comprises: A catalytic reaction zone (12a, 12b) per stage (6, 7); Introducing (2) a reaction fluid to a stage adapted for transverse motion of the fluid across the whole vertical extent of the reaction zone; introducing and extracting the catalyst; a heat exchanger (5a) for reaction fluids located inside the vessel between two successive reaction zones; means (6) for transporting reaction fluids from one stage to another preferably connected to the exchanger of the stage under consideration and to the inlet for reaction fluids of the subsequent stage; means for recovering reaction fluids downstream of the last stage. The temperature variation in each zone and the temperature level are respectively adjusted by the thickness of each zone and by heat exchange.

    Abstract translation: 细长反应容器包括在垂直方向上至少两个阶段，其中进行吸热或放热催化反应，并包括：每级催化反应区（12a，12b）（6,7）; 将反应流体引入（2）反应流体，以适应流体在整个反应区域的整个垂直范围内的横向运动; 引入和提取催化剂; 用于位于两个连续反应区之间的反应流体的热交换器（5a）; 用于将反应流体从一个阶段转移到另一个阶段的装置（6），优选地连接到所考虑的阶段的交换器和后续阶段的反应流体的入口; 用于在最后阶段下游回收反应液的装置。 每个区域的温度变化和温度水平分别通过每个区域的厚度和通过热交换来调整。

    Pulsed flow preferential oxidation reactor
    64.
    发明申请
    Pulsed flow preferential oxidation reactor 审中-公开
    脉冲流优先氧化反应器

    公开(公告)号：US20020018738A1

    公开(公告)日：2002-02-14

    申请号：US09827258

    申请日：2001-04-05

    Inventor： Richard Woods ,  Shawn Barge

    IPC: B01J008/00

    CPC classification number: C01B3/583 ,  B01J8/0207 ,  B01J8/0278 ,  B01J8/0403 ,  B01J8/0492 ,  B01J19/245 ,  B01J19/2485 ,  B01J23/56 ,  B01J2208/00168 ,  B01J2208/00176 ,  B01J2208/00548 ,  B01J2208/00628 ,  B01J2219/0002 ,  B01J2219/00087 ,  B01J2219/00164 ,  B01J2219/00186 ,  B01J2219/00231 ,  C01B2203/044 ,  C01B2203/047 ,  C01B2203/066 ,  C01B2203/12 ,  C01B2203/1276 ,  C01B2203/145 ,  C01B2203/169 ,  H01M8/0631

    Abstract: A multi-stage preferential oxidation reactor for removing carbon-monoxide from a product-gas comprises at least one preferential oxidation reactor stage having a product-gas stream inlet end and a product-gas stream outlet end. A first inlet is provided to introduce the product-gas stream into the preferential oxidation reactor stage, and is located at the product-gas stream inlet end of the preferential oxidation reactor stage. The first inlet is configured with a pulsator for pulsing the flow of the product-gas stream into the preferential oxidation reactor stage. A second inlet is also provided to introduce an oxidant into the preferential oxidation reactor stage. The second inlet is located at the product-gas stream inlet end of the oxidizer preferential oxidation reactor stage. An outlet is provided for removal of the treated product-gas stream from the preferential oxidation reactor stage.

    Abstract translation: 用于从产物气体中除去一氧化碳的多级优先氧化反应器包括至少一个具有产物 - 气流入口端和产物气流出口端的优先氧化反应器级。 提供第一入口以将产物气流引入优先氧化反应器阶段，并且位于优先氧化反应器阶段的产物 - 气流入口端。 第一入口配置有用于使产物气流的流动脉动到优先氧化反应器阶段的脉动器。 还提供第二入口以将氧化剂引入优先氧化反应器阶段。 第二个入口位于氧化剂优先氧化反应器阶段的产物 - 气流入口端。 提供出口用于从优先氧化反应器阶段除去经处理的产物 - 气流。

    Liquid phase reaction process
    65.
    发明授权
    Liquid phase reaction process 失效
    液相反应过程

    公开(公告)号：US5387349A

    公开(公告)日：1995-02-07

    申请号：US966900

    申请日：1992-10-26

    Applicant: Stuart G. Trotter ,  Ralph J. Doy

    Inventor： Stuart G. Trotter ,  Ralph J. Doy

    IPC: B01J7/02 ,  B01J8/04 ,  B01J8/20 ,  C01B3/02 ,  C01B13/02 ,  C02F1/72 ,  C02F1/20

    CPC classification number: B01J8/04 ,  C01B13/0203 ,  B01J2208/00061 ,  B01J2208/00168 ,  B01J2219/187 ,  Y10S423/13

    Abstract: A process wherein a liquid influent stream containing such an amount of a reactant that decomposition thereof to a desired concentration evolves, at the prevailing pressure and temperature, at least 0.5 volumes of gas per volume of the influent stream, is continuously passed through a volume of a particulate catalyst that is sufficient to decompose said reactant to said desired concentration and the evolved gas rises to the surface of said liquid and disengages therefrom into a gas space above said liquid, thereby providing an effluent stream having said desired concentration of said reactant. In order that back mixing of the effluent stream with said influent stream is avoided, the catalyst is disposed in a plurality of serially connected reaction volumes, each of which has a liquid surface from which evolved gas can disengage into the gas space, and the extent of reaction in each of said reaction volumes is limited by providing that the depth of catalyst in each reaction volume is such that the rate at which gas disengages from the liquid surface of each reaction volume is less than 0.05 m.sup.3.s.sup.-1 per m.sup.2 of the liquid surface of that reaction volume.

    Abstract translation: 一种方法，其中含有这种量的反应物的液体流入物流，其分解为所需浓度，在主要压力和温度下，每体积流入物流至少0.5体积的气体，连续通过一定量的 足以将所述反应物分解成所需浓度的颗粒催化剂，并且放出的气体上升到所述液体的表面并与其分离成在所述液体上方的气体空间，由此提供具有所需浓度的所述反应物的流出物流。 为了避免流出物流与所述流入物流的反向混合，催化剂设置在多个串联连接的反应体积中，每个反应体积具有液体表面，放出气体可以从该表面脱离到气体空间中， 在每个反应体积中的反应的限制是通过使每个反应体积中的催化剂深度使得气体与每个反应体积的液体表面脱离的速率小于0.05m 3·s -1 / m 2 该反应体积的液体表面。

    Processes for carrying out catalytic endothermic high-pressure gas reactions
    66.
    发明授权
    Processes for carrying out catalytic endothermic high-pressure gas reactions 失效
    进行催化吸热高压气体反应的方法

    公开(公告)号：US4461751A

    公开(公告)日：1984-07-24

    申请号：US486929

    申请日：1983-04-20

    Applicant: John V. Albano ,  George Friedman

    Inventor： John V. Albano ,  George Friedman

    IPC: B01J8/00 ,  B01J8/04 ,  C01C1/04 ,  C01C3/02 ,  C07C29/151 ,  C07C29/152

    CPC classification number: C07C29/1516 ,  B01J8/0005 ,  B01J8/0415 ,  B01J8/0496 ,  C01C1/0417 ,  C01C3/0225 ,  C07C29/152 ,  B01J2208/0007 ,  B01J2208/00088 ,  B01J2208/00132 ,  B01J2208/00168 ,  B01J2208/00194 ,  B01J2208/00256 ,  Y02P20/52

    Abstract: Processes for carrying out catalytic exothermic and endothermic high-pressure gas reactions with a single-walled pressure vessel or shell containing cross-flow (e.g., radial flow) heat transfer exchangers, a continuous catalytic bed having at least two stages, and means for effecting "cross-over" material flows from "outside" to "inside" (for exothermic reactions) and vice versa (for endothermic reactions), whereby conditions of: maximum gas temperature always being in the core of said vessel or shell, minimal pressure drop, and minimal compression of catalyst particles are achieved, along with significant economic savings in cost of the pressure vessel or shell and catalyst (through extension of catalyst life).

    Abstract translation: 用单壁压力容器或含有交叉流动的壳体（例如，径流）传热交换器，具有至少两个阶段的连续催化床进行催化放热和吸热高压气体反应的方法以及用于实现 “交叉”材料从“外部”流向“内部”（用于放热反应），反之亦然（对于吸热反应），其条件是：最大气体温度始终位于所述容器或壳体的核心中，最小压降 ，并且实现了催化剂颗粒的最小压缩，同时显着节省了压力容器或壳和催化剂的成本（通过延长催化剂寿命）。

    Exothermic catalytic gas reactor
    67.
    发明授权
    Exothermic catalytic gas reactor 失效
    超热催化气体反应器

    公开(公告)号：US3556738A

    公开(公告)日：1971-01-19

    申请号：US3556738D

    申请日：1967-07-24

    Applicant: ROBERT SCHOBER

    Inventor： SCHOBER ROBERT

    IPC: B01J8/04 ,  C01C1/04 ,  B01J9/00

    CPC classification number: C01C1/0423 ,  B01J8/0415 ,  B01J8/0496 ,  B01J2208/00168 ,  Y02P20/52

    Abstract: IN A CYLINDRICAL HIGH PRESSURE REACTOR, FOR INSTANCE FOR AMMONIA SYNTHESIS, A SYSTEM OF CONCENTRIC FRESH GAS COOLING TUBES ARRANGED WITH A SURFACE DECREASING TOWARDS THE BOTTOM, WHICH EXTENDS THROUGH THE ENTIRE CATALYZER SPACE IN AN AXIAL PLANE ACCORDING TO HEIGHT AND BREADTH. BAFFLE PLATES ARE ARRANGED HORIZONTALLY IN THE CATALYZER COLUMN WITH ALTERNATING PERIPHERAL RECESSES TO GUIDE THE STREAM

    OF REACTION GAS IN A VARIABLE HORIZONTAL DIRECTION TRANSVERSELY THROUGH THE COOLING TUBE SYSTEM.

    SYSTEM AND METHOD FOR PRODUCING ULTRA-HIGH MOLECULAR WEIGHT POLYALPHAOLEFINS FOR USE AS PIPELINE DRAG REDUCING AGENTS
    68.
    发明公开
    SYSTEM AND METHOD FOR PRODUCING ULTRA-HIGH MOLECULAR WEIGHT POLYALPHAOLEFINS FOR USE AS PIPELINE DRAG REDUCING AGENTS 审中-公开

    公开(公告)号：US20240261753A1

    公开(公告)日：2024-08-08

    申请号：US18565010

    申请日：2022-05-31

    Applicant: Gerald B. Eaton

    Inventor： Gerald B. Eaton

    IPC: B01J8/00 ,  B01J8/18

    CPC classification number: B01J19/249 ,  B01J8/001 ,  B01J8/18 ,  B01J19/2445 ,  B01J19/245 ,  B01J2208/00168 ,  B01J2219/2453 ,  B01J2219/2456 ,  B01J2219/2462

    Abstract: A system is disclosed for producing ultra-high-molecular-weight (UHMW) poly-alpha-olefins (PAO) for use as pipeline drag reducing agents, having improved thermal efficiency and reduced branching of the PAO. The system comprises hinged pairs of shells, each pair of shells comprising a grid of larger hemispherical voids connected by smaller hemicylindrical passages, arranged in a serpentine pattern along the surface area of the shell. When the hinged pairs of shells are shut, they form a pattern of spherical voids which can be connected to an inlet port, which receives a combination of alpha-olefin monomer feedstock and a titanium trichloride catalyst. A reactor chamber houses a plurality of these hinged pairs of shells, which may slide into slots inside the reactor chamber spaced such that each adjacent hinged pair of shells abuts the outer surface of the next when shut and inserted. The reactor chamber is cooled by an inert gas.

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