公开(公告)号：US20190103630A1

公开(公告)日：2019-04-04

申请号：US16102606

申请日：2018-08-13

Applicant: QuantumScape Corporation

Inventor： Dong Hee Anna CHOI ,  Niall DONNELLY ,  Tim HOLME ,  Will HUDSON ,  Sriram IYER ,  Oleh KARPENKO ,  Mohit SINGH ,  Adrian WINOTO

IPC: H01M10/0562 ,  C04B35/486 ,  C04B35/495 ,  C04B35/622 ,  H01M10/0585 ,  C04B35/65 ,  C01G25/00 ,  C04B35/626 ,  C04B35/488 ,  C04B41/00 ,  C04B35/64 ,  C04B41/50 ,  H01M10/0525 ,  C04B35/117 ,  C04B35/645 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0561

Abstract: Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (

公开(公告)号：US09806372B2

公开(公告)日：2017-10-31

申请号：US14531929

申请日：2014-11-03

Applicant: QuantumScape Corporation

Inventor： Tim Holme ,  Niall Donnelly ,  Sriram Iyer ,  Adrian Winoto ,  Mohit Singh ,  Will Hudson ,  Dong Hee Anna Choi ,  Oleh Karpenko ,  Kian Kerman

IPC: H01M10/0562 ,  H01M10/0525 ,  C04B35/626 ,  C04B35/65 ,  H01M10/0585 ,  C01G25/00 ,  C04B35/488 ,  C04B35/622 ,  C04B35/64 ,  H01M10/052 ,  H01M10/056 ,  H01M10/0561

CPC classification number: H01M10/0562 ,  C01G25/006 ,  C01P2006/40 ,  C04B35/117 ,  C04B35/486 ,  C04B35/4885 ,  C04B35/495 ,  C04B35/62218 ,  C04B35/6261 ,  C04B35/6262 ,  C04B35/64 ,  C04B35/645 ,  C04B35/65 ,  C04B41/009 ,  C04B41/5027 ,  C04B2235/3203 ,  C04B2235/3205 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3217 ,  C04B2235/3222 ,  C04B2235/3227 ,  C04B2235/3229 ,  C04B2235/3244 ,  C04B2235/3248 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3256 ,  C04B2235/3258 ,  C04B2235/3294 ,  C04B2235/6025 ,  C04B2235/656 ,  C04B2235/6567 ,  C04B2235/661 ,  C04B2235/666 ,  C04B2235/764 ,  C04B2235/786 ,  C04B2235/96 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/056 ,  H01M10/0561 ,  H01M10/0585 ,  H01M2300/0071 ,  H01M2300/0091

Abstract: Disclosed herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also disclosed herein are lithium-stuffed garnet thin films having fine grains therein. Also disclosed herein are methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also disclosed herein are methods for preparing dense thin (

公开(公告)号：US20170155113A1

公开(公告)日：2017-06-01

申请号：US15362892

申请日：2016-11-29

Applicant: Sumitomo Chemical Company, Limited

Inventor： Hiroki HASHIWAKI ,  Chikara MURAKAMI

IPC: H01M2/16 ,  H01M10/0561 ,  H01M10/0564 ,  H01M10/0525

CPC classification number: H01M2/1653 ,  C08J5/18 ,  C08J2323/06 ,  C08J2491/06 ,  H01M2/145 ,  H01M2/1673 ,  H01M2/1686 ,  H01M10/05 ,  H01M10/0525 ,  H01M10/0561 ,  H01M10/0564 ,  H01M2300/002 ,  H01M2300/0025 ,  H01M2300/0034 ,  H01M2300/0037

Abstract: Provided is a nonaqueous electrolyte secondary battery including a porous film containing polyolefin as a main component, the nonaqueous electrolyte secondary battery separator having a parameter X of not more than 20, the parameter X being calculated based on the following equation: X=100×|MD tan δ−TD tan δ|/{(MD tan δ+TD tan δ)/2}, where MD tan δ is tan δ in a machine direction of the porous film and TD tan δ is tan δ in a transverse direction of the porous film, MD tan δ and TD tan δ each being obtained by viscoelasticity measurement carried out with respect to the porous film at a frequency of 10 Hz and a temperature of 90° C., the nonaqueous electrolyte secondary battery separator making it possible to reduce an increase in internal resistance which increase is caused by repeated charge and discharge.

公开(公告)号：US20170125763A1

公开(公告)日：2017-05-04

申请号：US15128772

申请日：2015-03-18

Applicant: TOSOH CORPORATION

Inventor： Kei INATOMI ,  Yasutake WAKABAYASHI ,  Shigehiko ABE

IPC: H01M2/16 ,  B01D69/02 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0569 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0561 ,  B01D71/26 ,  H01M4/583

CPC classification number: H01M2/1653 ,  B01D53/228 ,  B01D69/02 ,  B01D71/26 ,  B01D2325/24 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M4/583 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0561 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/002 ,  H01M2300/0037 ,  C08F110/02 ,  C08F2500/01

Abstract: To provide an ultrahigh molecular weight polyethylene stretched microporous film having high strength and heat resistance.An ultrahigh molecular weight polyethylene stretched microporous film, which comprises at least an ultrahigh molecular weight polyethylene having an intrinsic viscosity ([η]) of at least 7 dl/g and at most 60 dl/g, and which has a porosity of at least 10% and at most 70% and a breaking stress of at least 1 MPa when melt-stretched at 150° C., which uses, as the ultrahigh molecular weight polyethylene, preferably ultrahigh molecular weight polyethylene particles which satisfy (1) an intrinsic viscosity ([η]) of at least 7 dl/g and at most 60 dl/g, (2) a bulk density of at least 130 kg/m3 and at most 700 kg/m3, and (3) ΔTm (ΔTm=Tm1−Tm2) of at least 9° C. and at most 30° C., which is a difference between the melting point (Tm1) at the 1st scanning and the melting point (Tm2) at the 2nd scanning measured by DSC.

公开(公告)号：US09478368B2

公开(公告)日：2016-10-25

申请号：US14450786

申请日：2014-08-04

Applicant: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

Inventor： Kyosuke Ito ,  Toru Itakura

IPC: H01G11/62 ,  H01M10/0563 ,  H01M10/0561 ,  H01G11/58 ,  H01M10/0525 ,  H01M10/0566 ,  H01M10/0569

CPC classification number: H01M10/0569 ,  H01G11/22 ,  H01G11/58 ,  H01G11/62 ,  H01M10/0525 ,  H01M10/0561 ,  H01M10/0563 ,  H01M10/0566 ,  H01M2300/0034 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

Abstract: One object is to provide a power storage device including an electrolyte using a room-temperature ionic liquid which includes a univalent anion and a cyclic quaternary ammonium cation having excellent reduction resistance. Another object is to provide a high-performance power storage device. A room-temperature ionic liquid which includes a cyclic quaternary ammonium cation represented by a general formula (G1) below is used for an electrolyte of a power storage device. In the general formula (G1), one or two of R1 to R5 are any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, and a methoxyethyl group. The other three or four of R1 to R5 are hydrogen atoms. A− is a univalent imide anion, a univalent methide anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate (BF4−), or hexafluorophosphate (PF6−).

Abstract translation: 一个目的是提供一种蓄电装置，其包括使用室温离子液体的电解质，其包含一价阴离子和具有优异的抗还原性的环状季铵阳离子。 另一个目的是提供一种高性能蓄电装置。 包含由下述通式（G1）表示的环状季铵阳离子的室温离子液体用于蓄电装置的电解质。 在通式（G1）中，R 1至R 5中的一个或两个为具有1至20个碳原子的烷基，甲氧基，甲氧基甲基和甲氧基乙基中的任一个。 R1至R5中的另外三个或四个是氢原子。 A-是一价酰亚胺阴离子，一价甲基阴离子，全氟烷基磺酸阴离子，四氟硼酸盐（BF4-）或六氟磷酸盐（PF6-）。

公开(公告)号：US08889091B2

公开(公告)日：2014-11-18

申请号：US13813387

申请日：2011-07-29

Applicant: Alf Schulz ,  Placido Garcia-Juan

Inventor： Alf Schulz ,  Placido Garcia-Juan

IPC: C01B25/10 ,  H01M10/0561 ,  C01B25/455 ,  H01M10/0563 ,  C01D15/00 ,  H01M10/052

CPC classification number: H01M10/0561 ,  C01B25/455 ,  C01D15/00 ,  H01M10/052 ,  H01M10/0563 ,  Y02E60/122 ,  Y02P70/54

Abstract: LiPO2F2, an electrolyte salt additive for batteries, is manufactured by the reaction of POF3, PF5 or mixtures thereof, with Li3PO4 forming a reaction mixture comprising LiPO2F2. When POF3 is applied, the reaction mixture which contains essentially only LiPO2F2 is preferably extracted from the reaction mixture with a solvent which also is applicable as solvent for lithium ion batteries. If PF5 is applied, then, depending on the molar ratio of PF5 and Li3PO4, the reaction mixture also contains LiF and/or LiPF6. To isolate pure LiPO2F2 from LiF, the reaction mixture containing essentially only LiPO2F2 and LiF may for example, be extracted with dimethoxyethane, acetone, dimethyl carbonate or propylene carbonate. To isolate pure LiPO2F2 from LiPF6, the reaction mixture containing essentially only these constituents is preferably extracted with a solvent which also is applicable as solvent for the LiPF6 in lithium ion batteries to dissolve and remove LiPF6.

Abstract translation: 用于电池的电解质盐添加剂LiPO2F2是通过POF 3，PF 5或其混合物与形成包含LiPO2F2的反应混合物的Li 3 PO 4的反应制备的。 当使用POF3时，优选仅用LiPO2F2的反应混合物用也可用作锂离子电池的溶剂的溶剂从反应混合物中提取。 如果使用PF5，则根据PF5和Li3PO4的摩尔比，反应混合物还含有LiF和/或LiPF6。 为了从LiF中分离纯LiPO2F2，基本上仅含有LiPO2F2和LiF的反应混合物可以例如用二甲氧基乙烷，丙酮，碳酸二甲酯或碳酸亚丙酯萃取。 为了从LiPF 6中分离纯LiPO2F2，基本上仅含有这些成分的反应混合物优选用溶剂萃取，该溶剂也可用作锂离子电池中的LiPF 6的溶剂以溶解和除去LiPF 6。

公开(公告)号：US08795544B2

公开(公告)日：2014-08-05

申请号：US13167030

申请日：2011-06-23

Applicant: Kyosuke Ito ,  Toru Itakura

Inventor： Kyosuke Ito ,  Toru Itakura

IPC: H01M10/0561 ,  H01M10/0563

CPC classification number: H01M10/0569 ,  H01G11/22 ,  H01G11/58 ,  H01G11/62 ,  H01M10/0525 ,  H01M10/0561 ,  H01M10/0563 ,  H01M10/0566 ,  H01M2300/0034 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

Abstract: One object is to provide a power storage device including an electrolyte using a room-temperature ionic liquid which includes a univalent anion and a cyclic quaternary ammonium cation having excellent reduction resistance. Another object is to provide a high-performance power storage device. A room-temperature ionic liquid which includes a cyclic quaternary ammonium cation represented by a general formula (G1) below is used for an electrolyte of a power storage device. In the general formula (G1), one or two of R1 to R5 are any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, and a methoxyethyl group. The other three or four of R1 to R5 are hydrogen atoms. A− is a univalent imide anion, a univalent methide anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate (BF4−), or hexafluorophosphate (PF6−).

Abstract translation: 一个目的是提供一种蓄电装置，其包括使用室温离子液体的电解质，其包含一价阴离子和具有优异的抗还原性的环状季铵阳离子。 另一个目的是提供一种高性能蓄电装置。 包含由下述通式（G1）表示的环状季铵阳离子的室温离子液体用于蓄电装置的电解质。 在通式（G1）中，R 1至R 5中的一个或两个为具有1至20个碳原子的烷基，甲氧基，甲氧基甲基和甲氧基乙基中的任一个。 R1至R5中的另外三个或四个是氢原子。 A-是一价酰亚胺阴离子，一价甲基阴离子，全氟烷基磺酸阴离子，四氟硼酸盐（BF4-）或六氟磷酸盐（PF6-）。

公开(公告)号：US20140057162A1

公开(公告)日：2014-02-27

申请号：US14003175

申请日：2012-02-02

Applicant: Meike Schneider ,  Wolfgang Schmidbauer ,  Oliver Hochrein ,  Thomas Pfeiffer ,  Sonja Lauer

Inventor： Meike Schneider ,  Wolfgang Schmidbauer ,  Oliver Hochrein ,  Thomas Pfeiffer ,  Sonja Lauer

IPC: H01M4/36 ,  H01M10/0525 ,  H01M10/0561

CPC classification number: H01M4/364 ,  C03C4/18 ,  C03C10/00 ,  C03C10/0027 ,  H01M4/13 ,  H01M4/5825 ,  H01M10/0525 ,  H01M10/0561 ,  H01M10/0562 ,  H01M10/0567 ,  H01M2300/0068

Abstract: A glass ceramic is provided that has at least one crystal phase that conducts lithium ions and a total content of Ta2O5 of at least 0.5 wt. %. The glass ceramic finds utility as a component selected from the group consisting of a lithium ion battery, an electrolyte in a lithium ion battery, an electrode component in a lithium ion battery, an additive to a liquid electrolyte in a lithium ion battery, a coating on an electrode in a lithium ion battery, and combinations thereof.

Abstract translation: 提供玻璃陶瓷，其具有至少一个导电锂离子的结晶相，并且Ta 2 O 5的总含量为至少0.5重量％。 ％。 玻璃陶瓷作为选自锂离子电池，锂离子电池中的电解质，锂离子电池中的电极成分，锂离子电池中的液体电解质的添加剂，涂层 在锂离子电池中的电极上，以及它们的组合。

公开(公告)号：US20140045012A1

公开(公告)日：2014-02-13

申请号：US13943093

申请日：2013-07-16

Applicant: Sanyo Electric Co., Ltd.

Inventor： Taiki Nonaka ,  Keisuke Minami ,  Shingo Tode ,  Toyoki Fujihara ,  Toshiyuki Nohma

IPC: H01M10/0561

CPC classification number: H01M10/0561 ,  H01M2/1686 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0587 ,  Y02T10/7011

Abstract: To provide a non-aqueous electrolyte secondary battery having high capacity and superior safety and cycle characteristics.The present invention is a non-aqueous electrolyte secondary battery including an electrode assembly and a non-aqueous electrolyte, the electrode assembly having a positive electrode, a negative electrode and a separator separating the positive electrode and the negative electrode, the non-aqueous electrolyte secondary battery characterized in that the separator has a three-layer laminated structure, the melting point of the middle layer being lower than either of the two outer layers, and the non-aqueous electrolyte including lithium bis(oxalato)borate.

Abstract translation: 提供具有高容量和优异的安全性和循环特性的非水电解质二次电池。 本发明是一种非水电解质二次电池，其包括电极组件和非水电解质，所述电极组件具有正极，负极和分离正极和负极的隔膜，非水电解质 二次电池，其特征在于，所述隔板具有三层层叠结构，所述中间层的熔点低于两个外层中的任一个，所述非水电解质包含双（草酸）硼酸锂。

公开(公告)号：US20140023936A1

公开(公告)日：2014-01-23

申请号：US13550884

申请日：2012-07-17

Applicant: Ilias Belharouak ,  Rui Xu

Inventor： Ilias Belharouak ,  Rui Xu

IPC: H01M10/056 ,  H01M10/0561

CPC classification number: H01M4/38 ,  H01M4/382 ,  H01M4/5815 ,  H01M10/052 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

Abstract: An electrolyte includes a lithium polysulfide of formula Li2Sx, where x>2; a shuttle inhibitor; and a non-aqueous solvent. Lithium-sulfur batteries may incorporate such electrolytes.

Abstract translation: 电解质包括式Li 2 S x的多硫化锂，其中x> 2; 穿梭抑制剂; 和非水溶剂。 锂硫电池可以并入这种电解质。