Apparatus for the internal coating of contact tubes
    73.
    发明授权
    Apparatus for the internal coating of contact tubes 失效
    接触管内涂装置

    公开(公告)号:US4471712A

    公开(公告)日:1984-09-18

    申请号:US508133

    申请日:1983-06-27

    CPC分类号: B05C7/04 B05D7/222

    摘要: The previously carried out internal coating of contact tubes not only required very much manual labor and was very time consuming, but it was also unsatisfactory in regard to adhesion of the contact liquid to the surface and homogenity of the catalyst. By the simultaneous action of heat on the liquid interface in the tubes during the lowering of the liquid level as well as by a specially suited apparatus for this purpose which operates according to the principle of communicating tubes there is provided the possibility of a good adhesion to the surface as well as the formation of a homogeneous layer at very little operating expense.

    摘要翻译: 先前进行的接触管的内部涂层不仅需要非常多的手工劳动,并且非常耗时,而且对于接触液体对表面的粘附和催化剂的均匀性也是不令人满意的。 通过在液面降低期间在管中的液体界面上的热同时作用以及根据连通管的原理的特别适合的用于该目的的设备,提供了对 表面以及以非常小的操作费用形成均匀的层。

    Bis-(silylethyl)-oligosulphides and process for their production
    74.
    发明授权
    Bis-(silylethyl)-oligosulphides and process for their production 失效
    双(甲硅烷基乙基) - 二硫化物及其生产方法

    公开(公告)号:US4444936A

    公开(公告)日:1984-04-24

    申请号:US461432

    申请日:1983-01-27

    摘要: Novel bis-(silylethyl)-oligosulphides are obtained by reacting a vinyl silane of the formula (CH.sub.2 .dbd.CH).sub.m --SiR.sub.n.sup.1 R.sub.4--(m+n) in which R represents chlorine, bromine, iodine, C.sub.1 --C.sub.3 -alkoxy, 2-methoxyethoxy, 2-ethoxyethoxy or hydroxy, R.sup.1 represents C.sub.1 --C.sub.3 -alkyl, phenyl or C.sub.5 --C.sub.7 -cycloalkyl, n is 0, 1 or 2, m is 1 or 2 and m+n is 1, 2 or 3 with sulphur as well as in a given case hydrogen sulphide in molar ratios of vinyl silane to sulphur of from 1:2.5 to 1:10 and vinyl silane to hydrogen sulphide of from 1:0 to 1:5 at temperatures between about 100.degree. and 200.degree. C. under pressure of from 1 to 25 bars (total pressure at the reaction) temperature) and in the presence of sulphidation catalysts known per se, in a given case followed by hydrolysis or partial hydrolysis of the reaction products. The bis-(silylethyl)-oligosulphides are used as reinforcing additives (adhesive agents) in crosslinkable rubber mixtures containing silicate fillers and in a given case carbon black as well as in a given case sulphur and other customary constituents.

    摘要翻译: 通过使式(CH2 = CH)m-SiRn1R4-(m + n)的乙烯基硅烷(其中R表示氯,溴,碘,C1-C3-烷氧基,2-甲基苯基) 甲氧基乙氧基,2-乙氧基乙氧基或羟基,R1代表C1-C3-烷基,苯基或C5-C7-环烷基,n是0,1或2,m是1或2,m + n是1,2或3, 以及在给定情况下,在约100至200℃的温度下,乙烯基硅烷与硫的摩尔比为1:2.5至1:10的硫化氢和乙烯基硅烷至硫化氢的摩尔比为1:0至1:5 在1至25巴(反应总压力)温度的压力下,在本身已知的硫化催化剂的存在下,在给定的情况下,随后水解或部分水解反应产物。 双(甲硅烷基乙基) - 二硫化物用作含有硅酸盐填料的交联性橡胶混合物中的增强添加剂(粘合剂),在给定情况下用于炭黑以及在给定情况下硫和其它常规组分。

    Aqueous solution of cationic organosilicon compounds and process for the
production of the solutions
    76.
    发明授权
    Aqueous solution of cationic organosilicon compounds and process for the production of the solutions 失效
    阳离子有机硅化合物的水溶液及其制备方法

    公开(公告)号:US4390712A

    公开(公告)日:1983-06-28

    申请号:US298251

    申请日:1981-08-31

    IPC分类号: B03D1/01 C07F7/18 C07F7/10

    摘要: There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.

    摘要翻译: 制备阳离子有机硅化合物的水溶液,其通过使式(RO)3-nRn1-Si-R2-X(I)的烷氧基​​甲硅烷基烷基卤化物反应制备,其中R是C1至C5烷基,甲氧基,乙氧基,苯基或 C5至C8环烷基; R 1是C 1至C 5烷基,苯基,甲苯基,苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基,n为0,1或2,X为氯,溴或碘,与式R3NR4R5(Ⅱ)的叔胺反应,其中R3,R4和 R5相同或不同,并且各自为烷基或苄基,其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的 在另一个选自氧,氮和硫的杂原子的情况下,杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环,或者R5是水性中的C3至C12环烷基 介质在室温(例如约20℃)至300℃的温度下以(I)至(II)的摩尔比为1:0.8至1:1.2,在给定情况下在压力下。

    Process for the production of hydrogen cyanide
    77.
    发明授权
    Process for the production of hydrogen cyanide 失效
    生产氰化氢的方法

    公开(公告)号:US4289741A

    公开(公告)日:1981-09-15

    申请号:US133358

    申请日:1980-03-24

    IPC分类号: C01C3/02

    CPC分类号: C01C3/0233

    摘要: The known hydrocyanic acid-methane-ammonia (BMA) process for the production of hydrogen cyanide can now be carried out with liquified gases namely through the presence of additional hydrogen at the beginning of the reaction. The atomic ratio of carbon to nitrogen and hydrogen is from 1:1:7.1 to 1:1.33:13. As additional hydrogen there is the portion of hydrogen present coming out of the reaction "hydrocarbon+NH.sub.3 ". Otherwise the reaction conditions are the same as in the known BMA process.

    摘要翻译: 用于生产氰化氢的已知氢氰酸 - 甲烷 - 氨(BMA)方法现在可以用液化气体进行,即在反应开始时通过存在另外的氢气来进行。 碳与氮和氢的原子比为1:1至7.1:1.33:1。 作为另外的氢,存在从反应“烃+ NH 3”出来的部分氢。 否则反应条件与已知的BMA方法相同。

    Monoclinic zirconium dioxide, method of its production and use
    80.
    发明授权
    Monoclinic zirconium dioxide, method of its production and use 失效
    单斜色二氧化锆,其生产和使用方法

    公开(公告)号:US5318765A

    公开(公告)日:1994-06-07

    申请号:US842610

    申请日:1992-02-27

    摘要: A monoclinic zirconium dioxide with an SiO.sub.2 content below 1.0% by weight is provided which is characterized by dendrite-shaped particles with an average grain size (d.sub.50 value) in a range of 0.5 .mu.m to 3.0 .mu.m and a specific surface (BET) in a range of 3 to 15 m.sup.2 /g. This zirconium dioxide is produced by thermally splitting zirconium silicate in a high-frequency- or medium-frequency induction melting furnace with sintering crust crucible, quenching the melt by blowing on a stream of melt with air and/or spraying it with water and leaching out the thermally split zirconium silicate with concentrated alkali lye at 100.degree. 200.degree. C. The zirconium dioxide of the invention provides a material with improved suitability for the production of zirconium silicate pigments of the host lattice type and inclusion type so as to provide for more color-intensive pigments.

    摘要翻译: 提供SiO 2含量低于1.0重量%的单斜二氧化锆,其特征在于平均粒径(d50值)在0.5μm至3.0μm范围内的树突状颗粒和比表面积(BET) 在3至15m 2 / g的范围内。 该二氧化锆是通过在具有烧结外壳的高频或中频感应熔化炉中热分解硅酸锆而制成的,通过用空气吹入熔融物流和/或用水喷洒熔融物并浸出 本发明的二氧化锆提供了一种改进适用于生产主晶格型和夹杂物型的硅酸锆颜料的材料,从而提供更多的颜色 密集颜料。