TETRAFLUOROETHYLENE COPOLYMERS
    84.
    发明申请
    TETRAFLUOROETHYLENE COPOLYMERS 审中-公开
    四氢氟乙烯共聚物

    公开(公告)号:US20150232593A1

    公开(公告)日:2015-08-20

    申请号:US14409082

    申请日:2013-06-13

    CPC classification number: C08F214/262 C08F2/10 C08F14/26 C08F2/24

    Abstract: The invention pertains to a tetrafluoroethylene (TFE) copolymer comprising recurring units derived from at least one perfluoroalkyl(oxy)vinylether of formula CF2═CF—O—Rf, wherein Rf is a C1-C6 perfluoroalkyl radical possibly comprising one or more ethereal oxygen atoms [monomer (F)], in an amount of 0.005 to 0.025% moles, with respect to the total moles of the copolymer, wherein a particular relation between monomer content and amorphous index is satisfied, and to a process for its manufacture by emulsion polymerization in the presence of certain cyclic surfactants.

    Abstract translation: 本发明涉及包含衍生自式CF2≡CF-O-Rf的至少一种全氟烷基(氧)乙烯基醚的重复单元的四氟乙烯(TFE)共聚物,其中Rf是可能包含一个或多个醚性氧原子的C 1 -C 6全氟烷基 相对于共聚物的总摩尔数为0.005〜0.025摩尔%的[单体(F)],其中满足单体含量与无定形指数之间的特定关系,以及其通过乳液聚合制造方法 在某些环状表面活性剂的存在下。

    ALLYL-BEARING FLUORINATED IONOMERS
    85.
    发明申请
    ALLYL-BEARING FLUORINATED IONOMERS 有权
    ALLYL轴承氟化离子

    公开(公告)号:US20150218084A1

    公开(公告)日:2015-08-06

    申请号:US14420708

    申请日:2013-07-30

    Abstract: The present invention provides a fluorinated ionomer [polymer (I)] comprising recurring units derived from at least the following monomers: (i) 5 to 50% by weight of a fluorinated monomer [monomer (A)] containing at least one —SO2X functionality, preferably having the formula of CF2═CF—O—(CF2CF(CF3)O)m—(CF2)mSO2X (I) wherein m is 0 or 1, n is an integer between 0-10, and X is selected from F, OH, and O−Me+, wherein Me+ indicates an alkali metal ion or an ammonium cation of formula NR4− where each R independently represents a hydrogen atom or a monovalent organic radical selected from aliphatic radicals having from 1 to 8 carbon atoms and arylic or alicyclic radicals having from 3 to 8 carbon atoms; (ii) a non-functional fluorinated monomer [monomer (B)] having at least one ethylene unsaturation; and (iii) a fluorinated polyfunctional compound having the general formula: (CR1R2═CFCF2—O)a—Rf—((O)c—CF═CR3R4)b (II) wherein: a is an integer equal to or larger than 1, preferably a is 1, 2, or 3; b is 0 or 1 and the sum of a and b is an integer equal to or larger than 2; c is 0 or 1; R1, R2, R3 and R4 are independently selected from F, H, alkyl, alkoxy, polyoxy alkyl, perfluoroalkyl, perfluoroalkoxy or perfluoropolyoxy alkyl, preferably F; and Rf represents a hydrocarbon or fluorocarbon group having at least two carbon atoms. The low-EW perfluorinated ionomers made of polymer (I) are adapted to be processed into thin films, which are found to have superior physical stability than the existing products and are thus well suited for low humidity or high temperature electrochemical applications. Moreover, these low-EW ionomers are melt processable and have limited loss of volatile substances at their melt processing temperatures.

    Abstract translation: 本发明提供了含至少以下单体的重复单元的氟化离聚物[聚合物(I)]:(i)5-50重量%含有至少一个-SO 2 X官能团的氟化单体[单体(A)] 优选具有CF 2 = CF-O-(CF 2 CF(CF 3)O)m - (CF 2)m SO 2 X(I)的式(其中m为0或1),n为0-10之间的整数,X选自F ,OH和O-Me +,其中Me +表示式NR4的碱金属离子或铵阳离子,其中每个R独立地表示氢原子或选自具有1至8个碳原子的脂肪族基团的一价有机基团和芳基或 具有3至8个碳原子的脂环族基团; (ii)具有至少一个乙烯不饱和度的非官能的氟化单体[单体(B)]; 和(iii)具有以下通式的氟化多官能化合物:(CR1R2 = CFCF2-O)a-Rf-((O)c-CF = CR3R4)b(Ⅱ)其中:a是等于或大于1的整数 优选a为1,2或3; b为0或1,a和b的和为等于或大于2的整数; c为0或1; R 1,R 2,R 3和R 4独立地选自F,H,烷基,烷氧基,聚氧烷基,全氟烷基,全氟烷氧基或全氟聚氧烷基,优选F; 并且Rf表示具有至少两个碳原子的烃或碳氟化合物基团。 由聚合物(I)制成的低EW全氟化离聚物适于加工成薄膜,发现它们比现有产品具有优异的物理稳定性,因此非常适合于低湿度或高温电化学应用。 此外,这些低EW离子聚合物是可熔融加工的,并且在其熔融加工温度下具有有限的挥发性物质损失。

    PROCESS FOR THE TREATMENT OF SULFONYL FLUORIDE POLYMERS
    86.
    发明申请
    PROCESS FOR THE TREATMENT OF SULFONYL FLUORIDE POLYMERS 审中-公开
    处理磺化氟化物聚合物的方法

    公开(公告)号:US20150197589A1

    公开(公告)日:2015-07-16

    申请号:US14574758

    申请日:2014-12-18

    Abstract: A process for reducing the amount of soluble polymeric fractions in a sulfonyl fluoride polymer. The process comprises contacting the sulfonyl fluoride polymer with a fluorinated fluid followed by separation of the polymer from the fluid. The fluorinated fluid is selected from hydrofluoroethers and hydrofluoropolyethers. The invention further relates to sulfonyl fluoride polymers obtainable by the process and having a heat of fusion not exceeding 4 J/g and containing less than 15% by weight of polymeric fractions having an average content of monomeric units comprising a sulfonyl functional group exceeding 24 mole %. The sulfonyl fluoride polymers so obtained are particularly suitable for the preparation of ionomeric membranes for use in electrochemical devices.

    Abstract translation: 用于减少磺酰氟聚合物中可溶性聚合物级分的量的方法。 该方法包括使磺酰氟聚合物与氟化流体接触,然后将聚合物与流体分离。 氟化流体选自氢氟醚和氢氟聚醚。 本发明还涉及通过该方法获得的磺化氟化物聚合物,其熔融热不超过4J / g,并且含有少于15%重量的具有包含超过24摩尔的磺酰基官能团的单体单元的平均含量的聚合物部分 %。 如此获得的磺酰氟聚合物特别适用于制备用于电化学装置的离聚物膜。

    HYBRID FLUOROPOLYMER COMPOSITION
    87.
    发明申请

    公开(公告)号:US20150194271A1

    公开(公告)日:2015-07-09

    申请号:US14420087

    申请日:2013-07-29

    Abstract: The present invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite, said process comprising: (i) providing a mixture comprising: (a) at least one fluoropolymer comprising recurring units derived from at least one fluorinated monomer and at least one comonomer [comonomer (MA)] comprising at least one hydroxyl group [polymer (F)]; (b) at least one metal compound [compound (M)] of formula (I): X4-mAYm, (I) wherein m is an integer from 1 to 4, and, according to certain embodiments, from 1 to 3, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group, optionally comprising one or more functional groups; (c) a liquid medium comprising at least one compound selected from the group consisting of a diester of formula (IIde) and an ester-amide of formula (IIea): R1—OOC—Zde—COO—R2 (IIde) R1—OOC—Zea—CO—NR3R4 (IIea) wherein: R1 and R2, equal to or different from each other, are independently selected from the group consisting of C1-C20 hydrocarbon groups, R3 and R4, equal to or different from each other, are independently selected from the group consisting of hydrogen, C1-C36 hydrocarbon groups, possibly substituted, being understood that R3 and R4 might be part of a cyclic moiety including the nitrogen atom to which they are bound, said cyclic moiety being possibly substituted and/or possibly comprising one or more than one additional heteroatom, and mixtures thereof, Zde and Zea, equal to or different from each other, are independently a linear or branched C3-C10 divalent alkylene group; and (d) optionally, at least one electrolytic salt (ES); (ii) reacting at least a fraction of hydroxyl groups of said comonomer (MA) of said polymer (F) with at least a fraction of the hydrolysable groups Y of said compound (M), so as to obtain a grafted fluoropolymer [polymer (Fg)] comprising one or more pendant groups of formula —Ym-1AX4-m; and (iii) hydrolysing and/or polycondensing said compound (M) and/or said pendant groups of formula —Ym-1AX4-m to yield a liquid mixture comprising the fluoropolymer hybrid organic/inorganic composite and incorporating said liquid medium.

    DOWNHOLE CABLE
    88.
    发明申请
    DOWNHOLE CABLE 审中-公开
    卧式电缆

    公开(公告)号:US20150060104A1

    公开(公告)日:2015-03-05

    申请号:US14388228

    申请日:2013-03-25

    CPC classification number: H01B7/292 H01B1/02 H01B3/445 H01B9/005

    Abstract: The present invention pertains to a cable comprising: —at least one conductor coated by an insulation coating layer, —a first protective layer surrounding said insulation coating layer, said first protective layer at least comprising, but preferably being made of a tetrafluoroethylene (TFE) copolymer comprising from 0.8% to 2.5% by weight of recurring units derived from at least one perfluorinated alkyl vinyl ether having formula (I) here below: CF2═CF—O—Rf, wherein Rf is a linear or branched C3-C5 perfluorinated alkyl group or a linear or branched C3-C12 perfluorinated alkyl group comprising one or more ether oxygen atoms, said TFE copolymer having a melt flow index comprised between 1.0 and 6.0 g/10 min, as measured according to ASTM D1238 at 372° C. under a load of 5 Kg [polymer (F)]; —optionally, a second protective layer surrounding said first protective layer, and —an armor shell surrounding said first or second protective layer. The invention also pertains to use of the cable in downhole wells.

    Abstract translation: 本发明涉及一种电缆,包括: - 由绝缘涂层涂覆的至少一个导体, - 围绕所述绝缘涂层的第一保护层,所述第一保护层至少包括但优选由四氟乙烯(TFE)制成, 共聚物,其包含0.8-2.5重量%的由至少一种具有下式(I)的全氟化烷基乙烯基醚的重复单元:CF 2 = CF-O-R f,其中R f是直链或支链C 3 -C 5全氟烷基 基团或包含一个或多个醚氧原子的直链或支链C 3 -C 12全氟化烷基,所述TFE共聚物的熔体流动指数为1.0-6.0g / 10min,根据ASTM D1238在372℃下测定, 负荷5Kg [聚合物(F)]; - 可选地,围绕所述第一保护层的第二保护层和围绕所述第一或第二保护层的护甲壳。 本发明还涉及在井下井中使用电缆。

    (PER)FLUOROPOLYETHERS WITH bi- OR ter-PHENYL END GROUPS
    89.
    发明申请
    (PER)FLUOROPOLYETHERS WITH bi- OR ter-PHENYL END GROUPS 审中-公开
    (PER)具有双 - 三苯基末端基团的氟聚醚

    公开(公告)号:US20150011446A1

    公开(公告)日:2015-01-08

    申请号:US14378115

    申请日:2013-02-12

    Abstract: The present invention relates (per)fluoropolyether compounds comprising a (per)fluoropolyether chain (Rf) having at least two chain ends, wherein at least one of said chain ends have a bi- or ter-phenyl group bearing at least one nitro group and, optionally one or more further substituents. The invention also relates to processes for the preparation of such compounds and to their use for the preparation of lubricant compositions in the form of oils or greases.

    Abstract translation: 本发明涉及包含具有至少两个链端的(全)氟聚醚链(Rf)的(全)氟聚醚化合物,其中至少一个所述链端具有带有至少一个硝基的双 - 或三苯基, ,任选的一个或多个另外的取代基。 本发明还涉及制备这些化合物的方法及其用于制备油或油脂形式的润滑剂组合物的用途。

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