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    PROCESS FOR THE COUPLED PREPARATION OF POLYSILAZANES AND TRISILYLAMINE
    83.
    发明申请
    PROCESS FOR THE COUPLED PREPARATION OF POLYSILAZANES AND TRISILYLAMINE 审中-公开
    多氯联苯和三甲硅烷偶联制备工艺

    公开(公告)号：US20150147256A1

    公开(公告)日：2015-05-28

    申请号：US14344801

    申请日：2013-06-25

    申请人： Carl-Friedrich Hoppe ,  Christian Götz ,  Hartwig Rauleder ,  Goswin Uehlenbruck

    发明人： Carl-Friedrich Hoppe ,  Christian Götz ,  Hartwig Rauleder ,  Goswin Uehlenbruck

    IPC分类号： C01B21/087 ,  B01J19/24

    CPC分类号： C01B21/087 ,  B01J19/24 ,  B01J2219/24 ,  C08G77/62

    摘要： The invention relates to a process for preparing trisilylamine and polysilazanes in the liquid phase, in which ammonia dissolved in an inert solvent is initially introduced in a substoichiometric amount relative to monochlorosilane which is likewise present in an inert solvent. The reaction is carried out in a reactor in which trisilylamine formed according to the following equation 4NH3+3H3SiCl→3NH4Cl+(SiH3)3N and polysilazanes are formed. The reactor is subsequently depressurized and TSA is separated off in gaseous form from the product mixture. The TSA obtained is purified by filtration and distillation and obtained in high or very high purity. Further ammonia dissolved in an inert solvent is subsequently introduced into the reactor, using, together with the previously introduced amount of ammonia, a stoichiometric excess of ammonia relative to the amount of MCS previously present. Excess ammonia is subsequently discharged, inert gas is introduced and the bottom product mixture from the reactor is passed through a filter unit, with solid ammonium chloride being separated off and a liquid mixture of polysilazanes and solvent being obtained.

    摘要翻译： 本发明涉及在液相中制备三甲胺和聚硅氮烷的方法，其中溶解在惰性溶剂中的氨相对于同样存在于惰性溶剂中的一氯硅烷，最初以亚化学计量的量引入。 该反应在其中形成根据下列等式4NH 3 + 3H 3 SiCl→3NH 4 Cl +（SiH 3）3 N和聚硅氮烷形成的三乙胺的反应器中进行。 随后将反应器减压，并将TSA从产物混合物中分离出气态。 通过过滤和蒸馏纯化获得的TSA，得到高纯度或非常高的纯度。 随后将溶解在惰性溶剂中的氨加入到反应器中，与先前导入的氨一起使用相对于先前存在的MCS的量的化学计量过量的氨。 随后排出过多的氨，引入惰性气体，将来自反应器的底部产物混合物通过过滤器单元，分离出固体氯化铵，得到聚硅氮烷和溶剂的液体混合物。

    Process for preparing epoxysilanes
    88.
    发明授权
    Process for preparing epoxysilanes 有权
    制备环氧硅烷的方法

    公开(公告)号：US06402961B1

    公开(公告)日：2002-06-11

    申请号：US09621076

    申请日：2000-07-21

    申请人： Stefan Bade ,  Uwe Schoen ,  Hartwig Rauleder

    发明人： Stefan Bade ,  Uwe Schoen ,  Hartwig Rauleder

    IPC分类号： B01D1508

    CPC分类号： C07F7/1892

    摘要： A process for preparing epoxysilanes by reacting a hydrogensilane with an allyl glycidyl ether in the presence of a catalyst and working up the crude product obtained, where the catalyst is removed from the crude product and the crude product is subsequently distilled.

    摘要翻译： 一种通过在催化剂存在下使氢硅烷与烯丙基缩水甘油醚反应来制备环氧硅烷的方法，并处理所得到的粗产物，其中从粗产物中除去催化剂和粗产物。

    Process for the continuous preparation of 3-halopropylorganosilanes
    90.
    发明授权
    Process for the continuous preparation of 3-halopropylorganosilanes 失效
    连续制备3-卤代丙基有机硅烷的方法

    公开(公告)号：US06242630B1

    公开(公告)日：2001-06-05

    申请号：US08908095

    申请日：1997-08-11

    申请人： Stefan Bade ,  Uwe Schoen ,  John Burkhard ,  Franz-Michael Bollenrath ,  Norbert Hofmann ,  Hermann-Josef Korte ,  Hartwig Rauleder ,  Uwe Tanger

    发明人： Stefan Bade ,  Uwe Schoen ,  John Burkhard ,  Franz-Michael Bollenrath ,  Norbert Hofmann ,  Hermann-Josef Korte ,  Hartwig Rauleder ,  Uwe Tanger

    IPC分类号： C07F708

    CPC分类号： C07F7/14 ,  C07F7/0829 ,  C07F7/1876

    摘要： A process for the continuous preparation of 3-halopropylorganosilanes of the general structure RbH3-a-bXaSiCH2CH2CH2Y  (III), where: R is CH3, C2H5, C3H7, OCH3, OC2H5 or OC3H7, X is F, Cl, Br or I, Y is F, Cl, Br or I, and a and b are each one of the numbers 0, 1, 2 or 3 and the sum a+b is 1, 2 or 3, comprising reacting, as starting materials, an allyl halide with a silane carrying at least one H atom, wherein the starting materials are present in stoichiometric amounts or one of the starting materials is present in substoichiometric amounts, wherein the reaction carried out is a partial reaction of from 10% to 80%, on a molar basis, of the starting materials, based on either material, when both are present in stoichiometric amounts, or based on the substoichiometric material.

    摘要翻译： 连续制备通常结构的3-卤代丙基有机硅烷的方法，其中R为CH 3，C 2 H 5，C 3 H 7，OCH 3，OC 2 H 5或OC 3 H 7，X为F，Cl，Br或I，Y为F，Cl，Br或I， 和b分别为数字0,1,2或3中的一个，并且和a + b为1,2或3，包括使烯丙基卤化物与携带至少一个H原子的硅烷作为原料，其中， 原料以化学计量的量存在，或者一种起始原料以亚化学计量的量存在，其中进行的反应是基于摩尔的10％至80％的起始原料的部分反应，基于任一材料 ，当两者都以化学计量的量存在时，或基于亚化学计量的材料。