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    METHOD FOR PRODUCING BLOCK COPOLYMERS
    83.
    发明申请
    METHOD FOR PRODUCING BLOCK COPOLYMERS 有权
    生产嵌段共聚物的方法

    公开(公告)号：US20120101218A1

    公开(公告)日：2012-04-26

    申请号：US13279481

    申请日：2011-10-24

    申请人： Longlan CUI ,  Shaoguang FENG ,  Yanfei LIU ,  Tao WANG ,  Qingwei ZHANG

    发明人： Longlan CUI ,  Shaoguang FENG ,  Yanfei LIU ,  Tao WANG ,  Qingwei ZHANG

    IPC分类号： C09D153/00 ,  C08F265/02

    CPC分类号： C08F2/001 ,  C08F212/12 ,  C08F293/005 ,  C09D153/00

    摘要： A method for producing an AB block copolymer with PDI is provided. The method comprises steps of: 1) reaction, in the presence of at least one free radical initiator, of a reaction mixture comprising a compound of formula (I), and 2) reaction, at a temperature of 45° C. or above, of a reaction mixture comprising an ethylenically unsaturated monomer B and, independent from that of step 1), a compound of formula (I) and the macroinitiator of step 1) in solvent(s) to obtain the AB block copolymer; wherein the weight ratio of the compound of formula (I) to the macroinitiator in step 2) is at least 1:1000.

    摘要翻译： 提供了一种用PDI制备AB嵌段共聚物的方法。 该方法包括以下步骤：1）在至少一种自由基引发剂存在下，将包含式（I）化合物的反应混合物和2）在45℃或更高的温度下反应， 包含烯键式不饱和单体B和独立于步骤1）的反应混合物，式（I）化合物和步骤1）的大分子引发剂在溶剂中以获得AB嵌段共聚物; 其中式（I）化合物与步骤2）中的大分子引发剂的重量比为至少1:1000。

    AB DIBLOCK COPOLYMERS AND APPLICATIONS FOR THEIR USE
    86.
    发明申请
    AB DIBLOCK COPOLYMERS AND APPLICATIONS FOR THEIR USE 审中-公开
    AB二嵌段共聚物及其应用

    公开(公告)号：US20110257289A1

    公开(公告)日：2011-10-20

    申请号：US13078576

    申请日：2011-04-01

    申请人： Simon Biggs ,  Gaelle Baquey ,  Maggy Manguian ,  Sasha Heriot

    发明人： Simon Biggs ,  Gaelle Baquey ,  Maggy Manguian ,  Sasha Heriot

    IPC分类号： C09D143/02 ,  B05D1/02 ,  B05D1/28 ,  B05D1/30 ,  C09D133/10 ,  B05D1/36 ,  C09D133/16 ,  B05D1/18 ,  B05D3/12 ,  B82Y5/00

    CPC分类号： C09D153/00 ,  C08F293/005 ,  C08L53/00 ,  C09D5/1668 ,  C08L2666/02

    摘要： The present invention relates to the use of AB block copolymer composition as a surface coating wherein the composition comprises (a) an AB block copolymer; and (b) a liquid medium and wherein the AB block copolymer comprises: (a) a substantially hydrophobic block A, and (b) a substantially hydrophilic block B wherein the hydrophobic block A comprises one or more monomer of formula (A) wherein R is H or C1 to C4 alkyl; Z is O, P or N; and R′ is selected from the group comprising: C1 to C18 linear or non linear alkyl; C1 to C18 alkylamino alkyl; C1 to C18 dihydroxyalkyl; C1 to C18 silylalkyl; epoxy alkyl, phosphoryl or phosphoryl alkyl; a styrene based monomer; a vinyl phosphonate or phosphoric acid monomer; and wherein the liquid medium comprises either: (i) water; (ii) an organic solvent; (iii) an organic solvent substantially free from water; or (iv) an organic solvent and water; and wherein: the liquid medium further optionally comprises one or more additive, surfactant or wetting agent.

    摘要翻译： 本发明涉及AB嵌段共聚物组合物作为表面涂层的用途，其中组合物包含（a）AB嵌段共聚物; 和（b）液体介质，其中所述AB嵌段共聚物包含：（a）基本上疏水的嵌段A和（b）基本上亲水的嵌段B，其中所述疏水性嵌段A包含一种或多种式（A）的单体，其中R 是H或C 1至C 4烷基; Z是O，P或N; 并且R'选自包括以下的基团：C1至C18直链或非直链烷基; C1至C18烷基氨基烷基; C1至C18二羟基烷基; C1至C18甲硅烷基烷基; 环氧烷基，磷酰基或磷酰基烷基; 苯乙烯基单体; 乙烯基膦酸酯或磷酸单体; 并且其中所述液体介质包括：（i）水; （ii）有机溶剂; （iii）基本上不含水的有机溶剂; 或（iv）有机溶剂和水; 并且其中：所述液体介质还任选地包含一种或多种添加剂，表面活性剂或润湿剂。

    AQUEOUS PIGMENT DISPERSION AND APPLICATIONS THEREOF
    87.
    发明申请
    AQUEOUS PIGMENT DISPERSION AND APPLICATIONS THEREOF 审中-公开
    水性颜料分散体及其应用

    公开(公告)号：US20110223529A1

    公开(公告)日：2011-09-15

    申请号：US12737568

    申请日：2009-07-24

    申请人： Hiroyuki Shimanaka ,  Taiyo Aoyagi ,  Yoshikazu Murakami ,  Sachio Yoshikawa ,  Naoyuki Sakai ,  Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

    发明人： Hiroyuki Shimanaka ,  Taiyo Aoyagi ,  Yoshikazu Murakami ,  Sachio Yoshikawa ,  Naoyuki Sakai ,  Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

    IPC分类号： G03G9/00 ,  C09D153/00 ,  C09D133/10

    CPC分类号： C09D153/00 ,  C08F293/005 ,  C08F2438/00 ,  C08K9/08 ,  C08L53/00 ,  C09B67/0066 ,  C09B67/009 ,  C09D7/62 ,  C09D11/326 ,  C09D17/001 ,  C08L2666/02

    摘要： Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it.

    摘要翻译： 公开了至少含有颜料，水，高分子分散剂和碱的水性颜料分散体。 高分子分散剂是具有式（1）的A-B的二嵌段聚合物或具有式（2）的A-B-C的三嵌段聚合物。 二嵌段或三嵌段聚合物是通过使用有机碘化物作为聚合引发化合物和有机磷化合物，有机氮化合物或有机氧化合物作为催化剂，通过使自由基发生剂聚合加成聚合的单体获得的二嵌段或三嵌段聚合物。 还公开了水性颜料分散体的制造方法和用途。 利用通过简单的活性自由基聚合方法获得的高分子分散体，其不存在常规活性自由基聚合和精确控制分子结构的问题，可以通过分散在其中的颜料来获得水性颜料分散体。

    AQUEOUS COATING COMPOSITION AND PROCESS FOR ITS PRODUCTION, AND PROCESS FOR FORMING COATING FILM
    88.
    发明申请
    AQUEOUS COATING COMPOSITION AND PROCESS FOR ITS PRODUCTION, AND PROCESS FOR FORMING COATING FILM 有权
    水性涂​​料组合物及其制备方法，以及形成涂膜的方法

    公开(公告)号：US20110184116A1

    公开(公告)日：2011-07-28

    申请号：US13081608

    申请日：2011-04-07

    申请人： Isao KIMURA ,  Naoko Sumi

    发明人： Isao KIMURA ,  Naoko Sumi

    IPC分类号： C09D127/12 ,  C09D153/00

    CPC分类号： C09D5/028 ,  C08L53/00 ,  C09D127/12 ,  C09D153/00 ,  C08L2666/24 ,  C08L2666/04

    摘要： To provide an aqueous coating composition which has a high storage stability and which is capable of forming a coating film excellent in gloss, adhesion and water resistance; a process for its production; and a process for forming a coating film by using the aqueous coating composition.An aqueous coating composition comprising a fluoro-olefin copolymer, a pigment, a copolymer (1) (an A-B type block copolymer which is a copolymer having no fluorine atoms or ionic groups and which comprises hydrophilic blocks (A) having repeating units (a) having a polyoxyethylene chain in the side chain, and hydrophobic blocks (B) having repeating units (b) having a hydrocarbon chain in the side chain) and an aqueous medium.

    摘要翻译： 提供具有高储存稳定性并且能够形成光泽，粘附性和耐水性优异的涂膜的水性涂料组合物; 一个生产过程; 以及通过使用该水性涂料组合物形成涂膜的方法。 一种水性涂料组合物，其包含氟代烯烃共聚物，颜料，共聚物（1）（AB型嵌段共聚物，其是不含氟原子或离子基团的共聚物，并且包含具有重复单元（a）的亲水性嵌段（A） 在侧链中具有聚氧乙烯链，以及具有在侧链中具有烃链的重复单元（b））和水性介质的疏水性嵌段（B）。

    RIGID-MATRIX COMPOSITION-GRADIENT COPOLYMERS WHICH ARE SOLUBLE AND/OR DISPERSIBLE IN WATER AND IN ORGANIC SOLVENTS
    90.
    发明申请
    RIGID-MATRIX COMPOSITION-GRADIENT COPOLYMERS WHICH ARE SOLUBLE AND/OR DISPERSIBLE IN WATER AND IN ORGANIC SOLVENTS 有权
    在水和有机溶剂中易溶于和/或不均匀的刚性 - 基质组合物 - 梯度共聚物

    公开(公告)号：US20110172352A1

    公开(公告)日：2011-07-14

    申请号：US13119056

    申请日：2009-09-18

    申请人： Stephanie Magnet ,  Helene Hediger ,  Oliver Guerret

    发明人： Stephanie Magnet ,  Helene Hediger ,  Oliver Guerret

    IPC分类号： C08F220/18 ,  C08F2/38 ,  C08L33/08

    CPC分类号： C09J153/00 ,  A61K8/8152 ,  A61Q19/00 ,  C08F2/38 ,  C08F212/08 ,  C08F220/06 ,  C08F293/005 ,  C08F2220/1808 ,  C08F2438/02 ,  C08L33/02 ,  C08L33/10 ,  C08L53/00 ,  C08L2666/02 ,  C09D125/14 ,  C09D153/00 ,  C09J125/14

    摘要： The invention relates to composition-gradient copolymers, comprising: repeat units resulting from the polymerization of at least one first monomer M1, the corresponding homopolymer of which exhibits a glass transition temperature Tg1 of less than 20° C., said repeat units representing from 15 to 40% by weight, with respect to the total weight of the copolymer; repeat units resulting from the polymerization of at least one second monomer M2, the corresponding homopolymer of which exhibits a glass transition temperature Tg2 of greater than 20° C., said repeat units representing from 45% to 65% by weight, with respect to the total weight of the copolymer; hydrophilic repeat units resulting from the polymerization of a least one third monomer M3, said repeat units representing from 10 to 25% by weight, with respect to the total weight of the copolymer.

    摘要翻译： 本发明涉及组合物梯度共聚物，其包含：由至少一种第一单体M1的聚合产生的重复单元，其相应​​的均聚物的玻璃化转变温度Tg1小于20℃，所述重复单元表示15 至40重量％，相对于共聚物的总重量; 由至少一种第二单体M2的聚合产生的重复单元，其相应​​的均聚物表现出大于20℃的玻璃化转变温度Tg2，所述重复单元相对于所述重复单元为45重量％至65重量％ 共聚物的总重量; 由至少一个第三单体M3的聚合产生的亲水重复单元，所述重复单元相对于共聚物的总重量为10-25重量％。