Substituted cyclopentenes, their preparation and their use for chiral scaffolds
    3.
    发明授权
    Substituted cyclopentenes, their preparation and their use for chiral scaffolds 失效
    取代的环戊烯,它们的制备及其在手性支架中的用途

    公开(公告)号:US06593489B1

    公开(公告)日:2003-07-15

    申请号:US09659482

    申请日:2000-09-11

    IPC分类号: C07C6974

    摘要: 3,4-Disubstituted-1-cyclopentene compounds, in substantially enantiopure form, have the relative stereochemistry according to formula (1A) or (1B) including the opposite enantiomers thereof, wherein R1 is either COOX, wherein X is selected from the group consisting of alkyl, H, and a salt-forming cation, or CH2OH, whererin the hydroxy group is optionally protected; R2 is H or a protecting group; R3 is H or alkyl, and R4 is selected from the group consisting of H, alkoxy, alkyl, aryl, and aralkyl; or, in the case of formula (1A), R2 and R4 are linked to form an oxazolidonone ring. These compounds can be used to prepare a series of complementary stereochemcially varied cyclopentane scaffolds.

    摘要翻译: 具有基本对映体形式的3,4-二取代-1-环戊烯化合物具有根据式(1A)或(1B)的相对立体化学,包括其相对的对映异构体,其中R 1是COOX,其中X选自烷基 ,H和成盐阳离子或CH 2 OH,其中羟基任选被保护; R 2是H或保护基; R 3是H或烷基,R 4选自H,烷氧基,烷基,芳基, 和芳烷基; 或者在式(1A)的情况下,R 2和R 4连接形成恶唑烷酮环。这些化合物可用于制备一系列互补的立体化学变化的环戊烷支架。

    Rubber compositions comprising unsaturated imidoalkoxysilanes
    6.
    发明申请
    Rubber compositions comprising unsaturated imidoalkoxysilanes 有权
    包含不饱和亚氨基烷氧基硅烷的橡胶组合物

    公开(公告)号:US20070123616A1

    公开(公告)日:2007-05-31

    申请号:US11287757

    申请日:2005-11-28

    IPC分类号: C08K5/34

    摘要: A rubber comprising a silane, a filler and at least one rubber selected from the group consisting of solution polymerization-derived styrene-butadiene rubber (S-SBR) having from about 10 to about 80 percent vinyl content; (ii) emulsion polymerization-derived rubber; and (iii) butadiene rubber having from about 5 to about 99 percent cis content and from about 0 to about 60 percent vinyl content.

    摘要翻译: 一种橡胶,其包含硅烷,填料和选自乙烯基含量约10至约80%的溶液聚合衍生的苯乙烯 - 丁二烯橡胶(S-SBR)中的至少一种橡胶; (ii)乳液聚合衍生的橡胶; 和(iii)具有约5至约99%顺式含量和约0至约60%乙烯基含量的丁二烯橡胶。

    Rubber compositions comprising unsaturated imidoalkoxysilanes
    7.
    发明授权
    Rubber compositions comprising unsaturated imidoalkoxysilanes 有权
    包含不饱和亚氨基烷氧基硅烷的橡胶组合物

    公开(公告)号:US07368490B2

    公开(公告)日:2008-05-06

    申请号:US11287757

    申请日:2005-11-28

    IPC分类号: C08G73/10

    摘要: A rubber comprising a silane, a filler and at least one rubber selected from the group consisting of solution polymerization-derived styrene-butadiene rubber (S-SBR) having from about 10 to about 80 percent vinyl content; (ii) emulsion polymerization-derived rubber; and (iii) butadiene rubber having from about 5 to about 99 percent cis content and from about 0 to about 60 percent vinyl content.

    摘要翻译: 一种橡胶,其包含硅烷,填料和选自乙烯基含量约10至约80%的溶液聚合衍生的苯乙烯 - 丁二烯橡胶(S-SBR)中的至少一种橡胶; (ii)乳液聚合衍生的橡胶; 和(iii)具有约5至约99%顺式含量和约0至约60%乙烯基含量的丁二烯橡胶。