公开(公告)号：US4145276A

公开(公告)日：1979-03-20

申请号：US862324

申请日：1977-12-20

Applicant: Jean Cosyns ,  Jean-Pierre Franck

Inventor： Jean Cosyns ,  Jean-Pierre Franck

IPC: C10G65/08 ,  B01J23/00 ,  B01J27/00 ,  C07B61/00 ,  C07C1/00 ,  C07C5/02 ,  C07C7/163 ,  C07C9/00 ,  C07C15/02 ,  C07C67/00 ,  C10G45/52 ,  C10G65/04 ,  C10G23/04

CPC classification number: C10G45/52 ,  C10G65/04

Abstract: An unstable heavy hydrocarbon fraction obtained by pyrosis is reacted with hydrogen in contact with three successive catalysts: (a) a group VIII metal catalyst (b) a catalyst comprising nickel and tungsten compounds, and (c) a catalyst comprising alumina, a group VIII noble metal and fluorine or chlorine.

公开(公告)号：US4140621A

公开(公告)日：1979-02-20

申请号：US835076

申请日：1977-09-20

Applicant: Jean-Pierre Franck ,  Jean-Francois Le Page ,  Germain Martino ,  Jean Miquel

Inventor： Jean-Pierre Franck ,  Jean-Francois Le Page ,  Germain Martino ,  Jean Miquel

IPC: B01J23/00 ,  C07C1/00 ,  C07C4/06 ,  C07C11/09 ,  C07C67/00 ,  C10G47/14 ,  C07C9/08 ,  B01J27/04

CPC classification number: C07C4/06 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2523/46 ,  C10G2400/26

Abstract: A saturated hydrocarbon charge containing both butane and isobutane is subjected to selective hydrogenolysis in the presence of a catalyst comprising a specific carrier and 0.1 - 10 % b.w. of rhodium. Butane is thus selectively converted to ethane and propane, while isobutane is preserved or formed and can be recovered from the reaction product.

Abstract translation: 在含有特定载体和0.1-10％b.w的催化剂存在下，将含有丁烷和异丁烷的饱和烃电荷进行选择性氢解。 的铑。 因此，丁烷选择性地转化为乙烷和丙烷，而异丁烷被保存或形成，并且可以从反应产物中回收。

公开(公告)号：US4737262A

公开(公告)日：1988-04-12

申请号：US10596

申请日：1987-02-03

Applicant: Jean-Pierre Franck ,  Jean-Paul Bournonville

Inventor： Jean-Pierre Franck ,  Jean-Paul Bournonville

IPC: B01J27/00 ,  B01J27/13 ,  B01J31/00 ,  B01J31/12 ,  B01J31/22 ,  C10G35/04 ,  C10G35/085 ,  C10G35/09 ,  C10G50/00 ,  C10G59/02

CPC classification number: C10G35/09 ,  C10G59/02

Abstract: A process for the catalytic reforming of a hydrocarbon charge wherein the charge passes successively through at least two catalyst beds, the first one being a bed of a first catalyst whose carrier contains platinum, rhenium and at least one halogen, at least the last bed being a moving bed of a second catalyst whose carrier contains platinum, at least one additional metal M selected from the group consisting of tin, gallium, germanium, indium, lead and thallium and at least one halogen, said metal M being introduced onto this carrier by means of an organometallic compound and the proportion by weight of said second catalyst being from 25 to 55% of the total catalyst mass used in all the catalyst beds. The charge preferably passes through at least two fixed beds of the first catalyst and at least one moving bed of the second catalyst, the carrier of the two catalysts being preferably alumina.By this process high grade gasolines (of Research Octane Number higher than 95) are produced over long periods.

Abstract translation: 一种用于烃电荷的催化重整的方法，其中电荷依次通过至少两个催化剂床，第一个是载体包含铂，铼和至少一个卤素的第一催化剂的床，至少最后一个床是 载体包含铂的第二催化剂的移动床，选自锡，镓，锗，铟，铅和铊的至少一种另外的金属M和至少一种卤素，所述金属M通过 有机金属化合物的手段和所述第二催化剂的重量比例在所有催化剂床中使用的总催化剂质量的25-55％。 电荷优选通过第一催化剂的至少两个固定床和第二催化剂的至少一个移动床，两种催化剂的载体优选为氧化铝。 通过这种方法，高品质汽油（研究辛烷值高于95）长期生产。

公开(公告)号：US4588495A

公开(公告)日：1986-05-13

申请号：US704456

申请日：1985-02-22

Applicant: Jean-Pierre Franck ,  Jean-Paul Bournonville

Inventor： Jean-Pierre Franck ,  Jean-Paul Bournonville

IPC: C10G35/09 ,  B01J21/04 ,  B01J27/00 ,  B01J27/13 ,  B01J27/135 ,  C10G59/02 ,  C10G35/06

CPC classification number: C10G59/02

Abstract: In a catalytic reforming process wherein a charge is circulated successively through a first catalyst bed and then at least one further catalyst bed, the improvement wherein the catalyst of the first bed comprises a carrier of alumina base and, by weight in proportion to the carrier, 0.05-0.6% of platinum, 0.005-3% of rhenium and 0.1-15% of at least one halogen and wherein each catalyst of the other beds contains a carrier of alumina base and, by weight with respect to the carrier, 0.05-0.6% of platinum, 0.05-3% of at least one metal promoter selected from the group consisting of tin, thallium and indium and 0.1-15% of at least one halogen, the proportion by weight of the catalyst containing platinum and rhenium ranging from 8 to 40% with respect to the total catalyst mass used in all the catalyst beds.

Abstract translation: 在催化重整过程中，其中电荷依次通过第一催化剂床和至少一个另外的催化剂床循环，其中第一床的催化剂包含氧化铝碱的载体，并且按载体的重量比例， 0.05-0.6％的铂，0.005-3％的铼和0.1-15％的至少一种卤素，其中每个催化剂的其它床层含有氧化铝基质的载体，相对于载体的重量比为0.05-0.6 铂的含量为0.05-3％，选自锡，铊和铟的至少一种金属促进剂和0.1-15％的至少一种卤素，含有铂和铼的催化剂的重量比为8 相对于在所有催化剂床中使用的总催化剂质量至40％。

公开(公告)号：US4435274A

公开(公告)日：1984-03-06

申请号：US425348

申请日：1982-09-28

Applicant: Bernard Juguin ,  Jean-Pierre Franck ,  Yves Jacquin ,  Christian Marcilly ,  Germain Martino

Inventor： Bernard Juguin ,  Jean-Pierre Franck ,  Yves Jacquin ,  Christian Marcilly ,  Germain Martino

IPC: C10G1/06 ,  C10G1/00 ,  C10G65/12 ,  C10G69/00 ,  C10L1/06 ,  C10G45/02 ,  C10G35/04 ,  C10G65/00

CPC classification number: C10L1/06 ,  C10G1/002 ,  C10G2400/02

Abstract: Residual oils from steam-cracking or catalytic cracking, oils from coal liquefaction and oils from bituminous sands and shales are converted to gasoline by a process comprising the fractionation of the feed charge to a naphtha and a middle distillate: the naphtha, admixed with a gasoline cut "E", is hydrotreated and then dehydrogenated to gasoline; the middle distillate is hydrotreated and fractionated to gasoline and a heavier fraction, the heavier fraction is hydrocracked and fractionated, thus producing a gasoline cut which constitutes the above cut "E".

Abstract translation: 来自蒸汽裂解或催化裂化的残余油，来自煤液化的油和来自沥青砂和页岩的油通过包括将进料装料分馏成石脑油和中间馏分的方法转化为汽油：石脑油与汽油混合 切“E”，加氢处理后脱氢至汽油; 将中间馏分加氢处理并分馏成汽油和较重的馏分，将较重的馏分进行加氢裂化和分馏，从而产生构成上述馏分“E”的汽油馏分。

公开(公告)号：US4180453A

公开(公告)日：1979-12-25

申请号：US876825

申请日：1978-02-10

Applicant: Jean-Pierre Franck ,  Edouard Freund ,  Jean-Francois Le Page ,  Jean Miquel

Inventor： Jean-Pierre Franck ,  Edouard Freund ,  Jean-Francois Le Page ,  Jean Miquel

IPC: B01J27/00 ,  C10G65/06 ,  C10G69/06 ,  C10G37/00

CPC classification number: C10G65/06 ,  C10G2400/20

Abstract: A fresh charge containing aromatic hydrocarbons is hydrotreated in admixture with a recycle fraction, in the presence of a bifunctional catalyst, a portion of the effluent is subjected to steam-cracking, thereby recovering a gas oil fraction which is subjected to hydrogenation and forms said recycle fraction. The mixture of recycle fraction and charge is advantageously treated with hydrogen in the presence of a monofunctional catalyst to hydrogenate olefins, at a lower temperature than the hydrotreatment, and then passed to the hydrotreatment zone.

Abstract translation: 将含有芳烃的新鲜电荷与再循环部分混合加氢处理，在双官能催化剂存在下，将一部分流出物进行蒸汽裂化，从而回收粗制油馏分进行氢化并形成所述再循环 分数。 有利的是，在单官能催化剂存在下，用氢气处理再循环部分和装料的混合物，以在比加氢处理的温度更低的温度下氢化烯烃，然后通入加氢处理区。

公开(公告)号：US4977121A

公开(公告)日：1990-12-11

申请号：US5806

申请日：1987-01-22

Applicant: Pierre Dufresne ,  Jean-Pierre Franck ,  Francis Raatz ,  Christine Travers

Inventor： Pierre Dufresne ,  Jean-Pierre Franck ,  Francis Raatz ,  Christine Travers

IPC: B01J29/00 ,  B01J29/20 ,  B01J29/22 ,  B01J29/24 ,  C07C5/27 ,  C10G35/095 ,  C10G45/60 ,  C10G45/64

CPC classification number: C10G35/095 ,  B01J29/20 ,  C07C5/2791

Abstract: The invention concerns a catalyst containing by weight:(a) from 10 to 99.99% of a mordenite being in major part shaped as needles and having a Si/Al atomic ratio of about 5 to 50, a benzene adsorption capacity of more than 5% by weight with respect to the dry mordenite weight, a volume V of a unit cell from 2.73 to 2,78 nm.sup.3, a sodium content by weight lower than 0.2% and adsorbing molecules of a kinetic diameter larger than about 6.6.times.10.sup.-10 m,(b) from 0 to 89.99% of a matrix,(c) from 0.005 to 15% of at least one metal from group VIII, and(d) from 0.005 to 10% of at least one metal from group IV A.The catalyst is used for hydroisomerizing cuts containing a high proportion of normal paraffins having 4, 5, 6 or 7 carbon atoms per molecule to obtain with a good conversion and selectivity a mixture containing a high proportion of isoparaffins.

公开(公告)号：US4943546A

公开(公告)日：1990-07-24

申请号：US266594

申请日：1988-11-03

Applicant: Christine Travers ,  Jean-Pierre Franck

Inventor： Christine Travers ,  Jean-Pierre Franck

IPC: B01J29/18 ,  B01J29/20 ,  B01J29/22 ,  B01J35/00 ,  C07B61/00 ,  C07C1/00 ,  C07C5/27 ,  C07C9/16 ,  C07C67/00 ,  C10G45/64

CPC classification number: C10G45/64 ,  B01J29/20 ,  B01J29/22 ,  C07C5/2791 ,  B01J2229/16 ,  B01J2229/37 ,  B01J2229/42 ,  B01J35/002

Abstract: A catalyst comprising by weight:(a) 10-99.98% of a mordenite, in major part as needles, having a Si/Al atomic ratio of from 5:1 to 100:1, a sodium content lower than 0.2% by weight of the dry mordenite weight, a mesh volume V of elementary mesh from 2.73 to 2.78 nm.sup.3, which adsorbs molecules of a kinetic diameter higher than about 6.6 Angstroms and has a benzene adsorption capacity higher than about 5% by weight,(b) 0-89.98% of a matrix selected from the group formed of alumina, silica, magnesia, natural clays, mixtures of said compounds and alumina-boron oxide combinations,(c) 0.01-15% of at least one group VIII metal, and(d) 0.01-1% of at least one group IV B metal (Ti, Zr, Hf).The catalyst is preferably prepared by introducing the group IV B metal into the matrix, admixing the obtained product with mordenite and then introducing the group VIII metal.The catalyst is used for hydroisomerizing n-paraffins having 4 to 7 carbon atoms with a good conversion rate and a good selectivity, thus obtaining a mixture comprising a high proportion of isoparaffins.

Abstract translation: 一种催化剂，其包含：（a）10-99.98％的丝光沸石，主要部分为针状，Si / Al原子比为5:1至100:1，钠含量低于0.2重量％ 干丝光沸石重量，2.73至2.78nm3的基本网眼的网孔体积V，其吸附动力学直径高于约6.6埃的分子，并且具有高于约5重量％的苯吸附能力，（b）0-89.98 选自氧化铝，二氧化硅，氧化镁，天然粘土，所述化合物和氧化铝 - 氧化硼组合的混合物的基体的％，（c）0.01-15％的至少一种第Ⅷ族金属，和（d）0.01 -1％的至少一种IVB族金属（Ti，Zr，Hf）。 催化剂优选通过将IVB族金属引入基体中，将所得产物与丝光沸石混合，然后引入第VIII族金属来制备。 催化剂用于将具有4至7个碳原子的正链烷烃加氢异构化，转化率高，选择性好，从而得到含有高比例异链烷烃的混合物。

公开(公告)号：US4911822A

公开(公告)日：1990-03-27

申请号：US38555

申请日：1987-04-15

Applicant: Jean-Pierre Franck ,  Adrien Orieux ,  Andre Vidal

Inventor： Jean-Pierre Franck ,  Adrien Orieux ,  Andre Vidal

IPC: C10G35/04 ,  B01J29/00 ,  B01J29/20 ,  C10G35/06 ,  C10G45/06 ,  C10G45/60 ,  C10G59/06 ,  C10G63/02 ,  C10G69/14

CPC classification number: C10G69/14 ,  C10G59/06

Abstract: The invention concerns a combined process of catalytically hydroreforming a heavy naphtha in at least one reaction zone (10) and catalytically hydroisomerizing a light naptha in at least one reaction zone (34).The invention is characterized in that the hydrogen produced in the hydroreforming unit (line 27) is used to isomerize the light naphtha, the obtained reformate and isomerate being fractionated preferably together in the same stabilization column (51 in FIG. 1).A better thermal integration, a better recovery of light hydrocarbons and a lowering of the utilities requirements and investments, as compared with units operating separately, are thus achieved.

Abstract translation: 本发明涉及在至少一个反应区（10）中催化加氢重整重质石脑油并在至少一个反应区（34）中催化加氢异构化浅孔蜡的组合方法。 本发明的特征在于，使用在水力发泡单元（管线27）中产生的氢使轻质石脑油异构化，所得到的重整产物和异构体优选在同一稳定塔（图1中的51）中一起分馏。 因此，与单独运行的单元相比，更好的热集成，轻质碳氢化合物的更好的回收和公用事业的需求和投资的降低。

公开(公告)号：US4835129A

公开(公告)日：1989-05-30

申请号：US164945

申请日：1988-03-07

Applicant: Christine Travers ,  Jean-Paul Bournonville ,  Jean-Pierre Franck

Inventor： Christine Travers ,  Jean-Paul Bournonville ,  Jean-Pierre Franck

IPC: B01J38/44 ,  B01J29/90 ,  B01J38/18 ,  B01J38/42 ,  C07C1/00 ,  C07C5/27 ,  C07C67/00 ,  C10G35/095 ,  C10G45/64

CPC classification number: C10G45/64 ,  B01J29/90 ,  B01J38/18 ,  C07C5/2791 ,  B01J38/42 ,  Y02P20/584

Abstract: Process for regenerating or activating a catalyst for isomerizing n-paraffins, containing at least one group VIII metal supported on an acid mordenite, wherein, after having lost at least a part of its initial activity, said catalyst is treated in a first step with an oxygen-containing gas at a temperature lower than about 550.degree. C., so as to remove the major part of the catalyst coke content, and in a second step the resultant product from the first step is oxychlorinated to a temperature of about 200.degree.-500.degree. C. by means of a gas mixture containing oxygen, water and chlorine or at least one chlorinated compound, said chlorine or chlorinated compound being used in a total amount of 0.5-10% by weight, calculated as chlorine, in proportion to the mordenite weight.

Abstract translation: 用于再生或活化用于使正链烷烃异构化的催化剂的方法，所述催化剂含有负载在酸性丝光沸石上的至少一种VIII族金属，其中在损失了其初始活性的至少一部分之后，所述催化剂在第一步中用 在低于约550℃的温度下进行含氧气体，以除去催化剂焦炭含量的主要部分，在第二步中将得自第一步的产物氧氯化至约200℃ - 500℃，通过含有氧，水和氯的气体混合物或至少一种氯化化合物，所述氯或氯化合物的用量按氯计算为0.5-10重量％，按氯计 丝光沸石重量。