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    Alkyl phenol-sulfur condensates as fuel and lubricating oil additives
    1.
    发明授权
    Alkyl phenol-sulfur condensates as fuel and lubricating oil additives 失效
    烷基酚 - 硫缩合物作为燃料和润滑油添加剂

    公开(公告)号：US5236608A

    公开(公告)日：1993-08-17

    申请号：US561895

    申请日：1990-08-02

    申请人： David J. Martella ,  John J. Jaruzelski

    发明人： David J. Martella ,  John J. Jaruzelski

    IPC分类号： C08G75/14 ,  C10L1/24 ,  C10M151/04

    CPC分类号： C10L1/2475 ,  C08G75/14 ,  C10M151/04 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2221/04 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/06 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/102 ,  C10N2240/103 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/40

    摘要： Additives for improving the low temperature flow properties and oxidative stability of hydrocarbon oils are disclosed, which comprise the condensation reaction product of alkylated phenol and sulfurizing agent, wherein:(a) the polymer composition has a number average molecular weight of at least about 3,000 and a molecular weight distribution of at least about 1.5;(b) in the alkylated phenol reactant the alkyl groups (i) are essentially linear; (ii) have between 6 and 50 carbon atoms; and (iii) have an average number of carbon atoms between about 12 and 26; and(c) not more than about 10 mole percent of the alkyl groups on the alkylated phenol have less than 12 carbon atoms and not more than about 10 mole percent of the alkyl groups on the alkylated phenol have more than 26 carbon atoms. The additives may also be produced in a branched backbone form in which monomer reactants are compolymerized with certain tri- or tetrafunctional comonomers. Blends of these additives with various hydrocarbon oils, and particularly various middle distillates and lubricating oil compositions, whose low temperature flow properties and oxidative stability are significantly improved thereby, are also disclosed.

    摘要翻译： 公开了用于改进烃油的低温流动性能和氧化稳定性的添加剂，其包括烷基化苯酚和硫化剂的缩合反应产物，其中：（a）聚合物组合物的数均分子量为至少约3,000， 分子量分布至少约1.5; （b）在烷基化酚反应物中，烷基（i）基本上是线性的; （ii）具有6至50个碳原子; 和（iii）平均碳原子数在约12和26之间; 和（c）不超过约10摩尔％的烷基化苯酚上的烷基具有小于12个碳原子，不超过约10摩尔％的烷基化苯酚上的烷基具有多于26个碳原子。 添加剂也可以以支链骨架形式制备，其中单体反应物与某些三官能或四官能团共聚单体共聚。 还公开了这些添加剂与各种烃油的混合物，特别是各种中间馏分和润滑油组合物，其低温流动性能和氧化稳定性由此显着提高。

    Preparation of linear alkyl aromatics
    3.
    发明授权
    Preparation of linear alkyl aromatics 失效
    线性烷基芳烃的制备

    公开(公告)号：US5268524A

    公开(公告)日：1993-12-07

    申请号：US950866

    申请日：1992-09-24

    申请人： David J. Martella ,  John J. Jaruzelski ,  Frank J. Chen

    发明人： David J. Martella ,  John J. Jaruzelski ,  Frank J. Chen

    IPC分类号： C07B37/02 ,  C07B37/04 ,  C07C2/66 ,  C07C37/14

    CPC分类号： C07C37/14 ,  C07B37/02 ,  C07B37/04 ,  C07C2/66 ,  C07C2529/06

    摘要： Essentially linear alkyl aromatics wherein the alkyl is attached to the aromatic ring at the .beta.-position are produced by the process wherein a linear hydrocarbon selected from the group consisting of linear .alpha.-olefins, linear .alpha.-substituted alkyl halides or linear .alpha.-substituted alkyl alcohol or mixtures of such olefins, halides or alcohols are reacted with an aromatic compound in the presence of an aprotic-polar cosolvent.

    摘要翻译： 其中烷基连接到β-位上的芳香环的基本上直链的烷基芳族化合物是通过以下方法生产的，其中选自直链α-烯烃，直链α-取代的烷基卤化物或直链α-取代的烷基 在非质子极性助溶剂的存在下，醇或这些烯烃，卤化物或醇的混合物与芳族化合物反应。

    Process for preparing alkyl phenol-sulfur condensate lubricating oil additives
    4.
    发明授权
    Process for preparing alkyl phenol-sulfur condensate lubricating oil additives 失效
    烷基酚 - 硫磺缩合物润滑油添加剂的制备方法

    公开(公告)号：US5262508A

    公开(公告)日：1993-11-16

    申请号：US930134

    申请日：1992-08-13

    申请人： David J. Martella ,  John J. Jaruzelski ,  Frank J. Chen

    发明人： David J. Martella ,  John J. Jaruzelski ,  Frank J. Chen

    IPC分类号： C07C37/14 ,  C07G99/00 ,  C08G75/14 ,  C10L1/24 ,  C10M151/04 ,  F02B75/02 ,  C08G59/00 ,  C08G63/78 ,  C08G65/38 ,  C10M105/08

    CPC分类号： C07C37/14 ,  C07G17/004 ,  C08G75/14 ,  C10L1/2481 ,  C10M151/04 ,  C10M2221/02 ,  C10N2240/00 ,  C10N2240/02 ,  C10N2240/06 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/102 ,  C10N2240/103 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  C10N2270/02 ,  F02B2075/025

    摘要： Additives for improving the low temperature flow properties and oxidative stability of hydrocarbon oils are disclosed, which comprise the alkylation of a phenol in the presence of a dipolar aprotic cosolvent to produce an essentially linear alkylated phenol which is condensated with a sulphurizing agent to produce the low temperature flow improver wherein:(a) the polymer composition has a number average molecular weight of at least about 3,000 and a molecular weight distribution of at least about 1.5;(b) in the alkylated phenol reactant the alkyl groups (i) are essentially linear; (ii) have between 6 and 50 carbon atoms; and (iii) have an average number of carbon atoms between about 12 and 26; and(c) not more than about 10 mole percent of the alkyl groups on the alkylated phenol have less than 12 carbon atoms and not more than about 10 mole percent of the alkyl groups on the alkylated phenol have more than 26 carbon atoms. The additives may also be produced in a branched backbone form in which monomer reactants are copolymerized with certain tri- or tetrafunctional comonomers. Blends of these additives with various hydrocarbon oils, and particularly various middle distillates and lubricating oil compositions, whose low temperature flow properties and oxidative stability are significantly improved thereby, are also disclosed.

    摘要翻译： 公开了用于改善烃油的低温流动性能和氧化稳定性的添加剂，其包括在偶极非质子助溶剂存在下苯酚的烷基化以产生基本上线性的烷基化苯酚，其与硫化剂缩合以产生低 温度流动改进剂，其中：（a）聚合物组合物具有至少约3,000的数均分子量和至少约1.5的分子量分布; （b）在烷基化酚反应物中，烷基（i）基本上是线性的; （ii）具有6至50个碳原子; 和（iii）平均碳原子数在约12和26之间; 和（c）不超过约10摩尔％的烷基化苯酚上的烷基具有小于12个碳原子，不超过约10摩尔％的烷基化苯酚上的烷基具有多于26个碳原子。 添加剂也可以以支链骨架形式制备，其中单体反应物与某些三官能或四官能团共聚单体共聚。 还公开了这些添加剂与各种烃油的混合物，特别是各种中间馏分和润滑油组合物，其低温流动性能和氧化稳定性由此显着提高。

    Alkyl phenol-formaldehyde condensates as fuel additives
    6.
    发明授权
    Alkyl phenol-formaldehyde condensates as fuel additives 失效
    烷基苯酚 - 甲醛缩合物作为燃料添加剂

    公开(公告)号：US5082470A

    公开(公告)日：1992-01-21

    申请号：US630062

    申请日：1990-12-19

    申请人： David J. Martella ,  John J. Jaruzelski

    发明人： David J. Martella ,  John J. Jaruzelski

    IPC分类号： C08G8/08 ,  C10L1/198 ,  C10L1/24 ,  C10M145/20 ,  C10M151/04

    CPC分类号： C10L1/1981 ,  C08G8/08 ,  C10L1/2475 ,  C10M145/20 ,  C10M151/04 ,  C10M2203/10 ,  C10M2203/102 ,  C10M2209/101 ,  C10M2221/04 ,  C10N2240/04 ,  C10N2240/042 ,  C10N2240/044 ,  C10N2240/046 ,  C10N2240/06 ,  C10N2240/08 ,  C10N2240/10 ,  C10N2240/101 ,  C10N2240/102 ,  C10N2240/103 ,  C10N2240/104 ,  C10N2240/106 ,  C10N2240/40

    摘要： Additives for improving the low temperature flow properties of hydrocarbon oils are disclosed, which comprise the condensation reaction product of alkylated phenol and aldehyde, wherein:(a) the polymer composition has a number average molecular weight of at least about 3,000 and a molecular weight distribution of at least about 1.5;(b) in the alkylated phenol reactant the alkyl groups (i) are essentially linear; (ii) have between 6 and 50 carbon atoms; and (iii) have an average number of carbon atoms between about 12 and 26; and(c) not more than about 10 mole % of the alkyl groups on the alkylated phenol have less than 12 carbon atoms and not more than about 10 mole % of the alkyl groups on the alkylated phenol have more than 26 carbon atoms. The additives may also be sulfurized, or produced in a branched backbone form in which monomer reactants are copolymerized with certain tri- or tetrafunctional comonomers. Blends of these additives with various hydrocarbon oils, and particularly various middle distillates and lubricating oil compositions, whose low temperature flow properties are significantly improved thereby, are also disclosed.

    摘要翻译： 公开了用于改进烃油的低温流动性质的添加剂，其包括烷基化酚和醛的缩合反应产物，其中：（a）聚合物组合物的数均分子量为至少约3,000，分子量分布 至少约1.5; （b）在烷基化酚反应物中，烷基（i）基本上是线性的; （ii）具有6至50个碳原子; 和（iii）平均碳原子数在约12和26之间; 和（c）不超过约10摩尔％的烷基化苯酚上的烷基具有小于12个碳原子，不超过约10摩尔％的烷基化苯酚上的烷基具有多于26个碳原子。 添加剂也可以被硫化，或以支链骨架形式制备，其中单体反应物与某些三官能或四官能共聚单体共聚。 还公开了这些添加剂与各种烃油，特别是各种中间馏分和润滑油组合物的混合物，其低温流动性能由此显着改善。