摘要:
Novel catalyst compositions comprising complexes of tin(IV) salts and amine compounds are used to prepare polyurethanes, polyureas, polycarbodiimides and polyisocyanurates. The complexes, which preferably employ primary amines, allow delay of gelation until they dissociate under certain reaction conditions. The complexes can be prepared neat or in situ in an active hydrogen containing formulation component. The complexes serve to delay gelation of the formulation because they can be prepared to be relatively stable to moisture and will predictably dissociate upon heating, either as a result of the exothermic nature of the reaction being catalyzed or with application of an external heat source. The catalyst compositions are particularly useful for preparation of carpet underlay and in other applications requiring significant delay prior to gelation.
摘要:
Flexible polyurethane foams are prepared by reacting a polyisocyanate with certain amine-terminated compounds. The amine terminated compounds are characterized in having at least 30 percent of their active hydrogen-containing groups in the form of primary aromatic, Lewis acid-blocked primary aliphatic and/or secondary aromatic or aliphatic amine groups. The resulting foams exhibit excellent physical properties, even in the absence of a cross-linker compound.
摘要:
This invention comprises a process whereby an amine functional compound having an equivalent weight of at least about 400 is reacted with an excess of a polyisocyanate to form an isocyanate-terminated prepolymer or quasi prepolymer, which polymer or quasi prepolymer is reacted with an isocyanate-reactive material which is preferably a relatively low equivalent weight polyol or mixture thereof with an additional amount of said amine functional compound or a relatively high equivalent weight polyol to form a polyurea containing polymer which is preferably non-cellular or microcellular.
摘要:
A polyurethane-polymer composition suitable for preparing a lightweight tire support includes at least one isocyanate, at least one polyol, and at least one chain extender. A polyurethane-polymer composition can also include an additive such as a catalyst, a filler, a surfactant, a colorant, and a mold-release agent. A lightweight tire support can be prepared from a polyurethane-polymer composition by, for example, reaction injection molding. Such a tire support desirably has temperature stability and load-bearing capability.
摘要:
The present invention provides a unitary run flat tire (RFT) reinforcement that is formed into a relatively rigid shape. The reinforcement is insertable into a mold for an RFT support and can maintain the needed structural rigidity for such insertion. Further, the invention provides an RFT support that is molded and includes the RFT reinforcement. The invention also provides a wheel assembly including a tire, a rim, and an RFT support between the rim and the tire, where the support includes the RFT reinforcement. The RFT support can have a colored indicator formed or subsequently applied thereto to indicate one or more attributes of the support.
摘要:
A blended composition containing polycarbonate, polyester, an olefinic epoxide-containing copolymer and a polyamine compound, which composition possesses a desirable balance of impact resistance, solvent resistance, and resistance to thermal deformation.
摘要:
The present invention provides a process for preparing a stable dispersion of a preformed polymer in a polyol in a single mixer. A preformed polymer is mixed under sufficient heat and shear to reduce its particle size to a desired size in the presence of a polyol. The present invention also provides stable dispersions of polymers in polyols and polyurethane formulations containing stable dispersions made by the process of the present invention.
摘要:
The invention includes a process for preparing a flexible, water-blown polyurea foam by reacting a reaction mixture containing at least one polyisocyanate component and an active hydrogen component, wherein active hydrogen compounds of relatively high equivalent weight have an average of about 1.5 to about 4 active hydrogen-containing groups per molecule, of which active hydrogen-containing groups: an average of (a) from about 5 to about 60 percent are primary aliphatic amine groups or (b) at least about 25 percent are primary aromatic, secondary aliphatic, Lewis acid-blocked primary or secondary aliphatic or aromatic amine groups or mixtures of such groups. An amount of at least one alkali metal halide salt effective to increase load bearing strength of the foam is incorporated into the reaction mixture. Differing amounts of alkali metal halide salts are suitably incorporated into different areas of the foam to produce areas having differing load bearing strengths. The invention includes the foams formed by the processes of the invention as well as active hydrogen compositions containing the alkali metal halide salts and useful in the processes.
摘要:
Polyurethanes are produced from compositions comprising at least one relatively high equivalent weight component and at least one chain extender selected from the group consisting of heterocyclic diamines, diaromatic disulfides, alkyl ethers of halogen-substituted aromatic diamines, polysubstituted alkyl diamines and alkyl acid esters of halogen-substituted diamino phenols of designated structures. Polyurethanes having high thermal stability, high tear strength and high modulus are produced.
摘要:
The present invention provides a unitary run flat tire (RFT) reinforcement using filament material that is formed into a relatively rigid shape. The reinforcement is insertable into a mold for an RFT support and can maintain the needed structural rigidity for such insertion. Further, the invention provides an RFT support that is molded and includes the RFT reinforcement. The invention also provides a wheel assembly including a tire, a rim, and an RFT support between the rim and the tire, where the support includes the RFT reinforcement. The RFT support can have a colored indicator formed or subsequently applied thereto to indicate one or more attributes of the support.