公开(公告)号：US20180148572A1

公开(公告)日：2018-05-31

申请号：US15830100

申请日：2017-12-04

Applicant: ARKEMA FRANCE

Inventor： Nadine Decraemer ,  Denis Huze ,  Hervé Ster ,  Jerome Pascal ,  Benoît Brule

IPC: C08L61/16

CPC classification number: C08L61/16 ,  B29B13/021 ,  B29C67/04 ,  B29K2071/00 ,  C08G65/40 ,  C08G2650/40 ,  C08J3/124 ,  C08J2371/10

Abstract: The invention relates to a process for the heat treatment of poly(arylene ether ketone ketone) powder suitable for laser sintering, and also to the powders resulting from this process.

公开(公告)号：US11945135B2

公开(公告)日：2024-04-02

申请号：US16470390

申请日：2017-12-20

Applicant: Arkema France

Inventor： Gilles Hochstetter ,  Arthur Pierre Babeau ,  Thibaut Savart ,  François Tanguy ,  Denis Huze ,  Mathieu Capelot ,  Patrice Gaillard

IPC: B29B15/12 ,  B29C70/20 ,  B29C70/54 ,  B29K101/12 ,  B29K307/04

CPC classification number: B29B15/12 ,  B29C70/20 ,  B29K2101/12 ,  B29K2307/04

Abstract: The invention relates to a process for manufacturing a pre-impregnated fibrous material comprising a continuous fibre fibrous material and at least one thermoplastic polymer matrix, characterized in that said pre-impregnated fibrous material is made of a single unidirectional ribbon or a plurality of parallel ribbons unidirectional and in that said method comprises an impregnation step, in particular at the core, of said fibrous material being in the form of a roving or of several parallel rovings by said thermoplastic polymer being in powder form, said step of impregnation being carried out with said at least one thermoplastic polymer and said fibrous material the D90/D10 ratio of which by volume of the thermoplastic polymer particles ranges from 1.5 to 50, in particular from 2 to 10 and the ratio of the average diameter by volume (D50) thermoplastic polymer particles on the average diameter of the unit fibres of said fibrous material ranges from 3 to 40, except for an impregnation process in aqueous suspension of a fibrous material made of carbon fibres by a thermoplastic polymer, said D50/mean unit fibre diameter ratio being comprised from 3 to 8, and excluding any electrostatic process in voluntary charge.

公开(公告)号：US11938656B2

公开(公告)日：2024-03-26

申请号：US16623946

申请日：2018-06-21

Applicant: Arkema France

Inventor： Gilles Hochstetter ,  Mathieu Capelot ,  Thibaut Savart ,  Arthur Pierre Babeau ,  Denis Huze ,  François Tanguy ,  Patrice Gaillard

IPC: B29B15/12 ,  B29C35/08 ,  B29C70/50 ,  B29K77/00 ,  B29K307/04 ,  B29K507/04

CPC classification number: B29B15/125 ,  B29C35/0805 ,  B29C70/506 ,  B29C2035/0822 ,  B29K2077/00 ,  B29K2307/04 ,  B29K2507/04

Abstract: A method of manufacturing an impregnated fibrous material including a fibrous material made of continuous fibers and at least one thermoplastic polymer matrix, the method including pre-impregnating the fibrous material while it is in the form of a roving or several parallel rovings with the thermoplastic material and heating the thermoplastic matrix for melting, or maintaining in the molten state, the thermoplastic polymer after pre-impregnation, the at least one heating step being carried out by means of at least one heat-conducting spreading part (E) and at least one heating system, with the exception of a heated calendar, the roving or the rovings being in contact with part or all of the surface of the at least one spreading part (E) and partially or wholly passing over the surface of the at least one spreading part (E) at the level of the heating system.

公开(公告)号：US11413832B2

公开(公告)日：2022-08-16

申请号：US16078399

申请日：2017-12-20

Applicant: Arkema France

Inventor： Gilles Hochstetter ,  Arthur Pierre Babeau ,  Thibaut Savart ,  François Tanguy ,  Denis Huze ,  Mathieu Capelot ,  Patrice Gaillard

IPC: B29C70/52 ,  B29C70/20 ,  B29C70/08 ,  B29B15/12 ,  B01J8/38 ,  B29K101/12 ,  B33Y10/00 ,  B33Y30/00 ,  B33Y70/00 ,  B29K77/00 ,  B29K105/10

Abstract: The invention relates to a process for manufacturing a preimpregnated fibrous material containing a fibrous material made of continuous fibers and at least one thermoplastic polymer matrix, wherein the preimpregnated fibrous material is produced as a single unidirectional tape or of a plurality of parallel unidirectional tapes and wherein the process includes a step of impregnating, in particular fully and homogeneously, the fibrous material that is in the form of a roving or of several parallel rovings with the at least one thermoplastic polymer matrix that is in powder form, the impregnating step being carried out by a dry route in a tank and the control of the amount of the at least one thermoplastic polymer matrix in said fibrous material being achieved by control of the residence time of said fibrous material in the powder, with the exclusion of any electrostatic process with intentional charging.

公开(公告)号：US10675785B2

公开(公告)日：2020-06-09

申请号：US16623991

申请日：2018-06-21

Applicant: Arkema France

Inventor： Gilles Hochstetter ,  Mathieu Capelot ,  Denis Huze ,  François Tanguy ,  Thibaut Savart ,  Arthur Pierre Babeau ,  Patrice Gaillard

IPC: C08L77/06 ,  B29B15/12 ,  C08J5/04 ,  B29K101/12

Abstract: An impregnated fibrous material comprising a fibrous material made of continuous fiber and at least one thermoplastic polymer matrix, wherein the at least one thermoplastic polymer is an non-reactive amorphous polymer, the glass transition temperature of which is such that Tg≥80° C., or a non-reactive semi-crystalline polymer, the melting temperature of which is Tf≥150° C., the fiber volume ratio is constant in at least 70% of the volume of the tape or ribbon, the fiber ratio in the pre-impregnated fibrous material ranging from 45 to 65% by volume, the porosity rate in the pre-impregnated fibrous material being less than 10%.

公开(公告)号：US20180304578A1

公开(公告)日：2018-10-25

申请号：US15768045

申请日：2016-10-13

Applicant: Arkema France

Inventor： Marc Audenaert ,  Denis Huze

IPC: B32B5/26 ,  H01B1/22 ,  B32B27/34 ,  C08J5/04

CPC classification number: B32B5/26 ,  B32B5/022 ,  B32B5/024 ,  B32B5/026 ,  B32B27/34 ,  B32B2262/02 ,  B32B2262/101 ,  B32B2262/106 ,  B32B2262/14 ,  B32B2264/0264 ,  B32B2307/202 ,  B32B2307/212 ,  B32B2419/00 ,  B32B2605/08 ,  B32B2605/18 ,  C08J5/042 ,  C08J5/24 ,  C08J2377/00 ,  C08K2003/0806 ,  C23C16/06 ,  H01B1/22 ,  C08K3/08 ,  C08L77/02

Abstract: The present invention relates to a method for producing a conductive composite material, as well as the composite material capable of being obtained by said method. The conductive material is obtained from a composite polymer matrix, which is formed by aggregation of composite conductive particles consisting of particles of a polymer matrix, having a diamter d50 of between 1 and 4000 μm, coated with a layer of electrically conductive material consisting of at least one metal. The ratio of the thickness of the conductive layer to the diameter d50 of the polymer matrix particles is between 0.0025:100 and 1.5:100, said thickness being less than 300 nm.

公开(公告)号：US20180134891A1

公开(公告)日：2018-05-17

申请号：US15822444

申请日：2017-11-27

Applicant: ARKEMA FRANCE

Inventor： Nadine Decraemer ,  Denis Huze ,  Cyrille Mathieu ,  Herve Ster ,  Jerome Pascal ,  Benoit Brule

IPC: C08L61/16 ,  C08J3/14 ,  C08J3/12 ,  C08L71/00 ,  C08G61/12

CPC classification number: C08L61/16 ,  B29C64/153 ,  C08G61/127 ,  C08G2261/3442 ,  C08G2650/40 ,  C08J3/124 ,  C08J3/14 ,  C08J2371/00 ,  C08L71/00

Abstract: The present invention relates to a composition comprising at least one poly(arylene ether ketone) powder suitable for laser sintering and also to the process which makes it possible to obtain it, minimizing the amount by weight of remaining non-sintered powder after production of the part by sintering.

公开(公告)号：US11059263B2

公开(公告)日：2021-07-13

申请号：US15768045

申请日：2016-10-13

Applicant: Arkema France

Inventor： Marc Audenaert ,  Denis Huze

IPC: B32B5/26 ,  H01B1/22 ,  B32B27/34 ,  C08J5/04 ,  B64D45/02 ,  C08J5/24 ,  B32B5/02 ,  C08K3/08 ,  C23C16/06

Abstract: The present invention relates to a method for producing a conductive composite material, as well as the composite material capable of being obtained by said method. The conductive material is obtained from a composite polymer matrix, which is formed by aggregation of composite conductive particles consisting of particles of a polymer matrix, having a diamter d50 of between 1 and 4000 μm, coated with a layer of electrically conductive material consisting of at least one metal. The ratio of the thickness of the conductive layer to the diameter d50 of the polymer matrix particles is between 0.0025:100 and 1.5:100, said thickness being less than 300 nm.

公开(公告)号：US10850429B2

公开(公告)日：2020-12-01

申请号：US15523781

申请日：2015-10-07

Applicant: ARKEMA FRANCE

Inventor： Benoit Brule ,  Denis Huze ,  Nadine Decraemer ,  Jerome Pascal

IPC: B33Y70/00 ,  B29C64/314 ,  B29B7/00 ,  B29B7/10 ,  B29B13/10 ,  B29B7/72 ,  B29B7/82 ,  C08G65/40 ,  C08G65/46 ,  B29C64/153 ,  B01F3/18 ,  B01F7/00 ,  B01F15/06 ,  C08J3/00 ,  B29B9/12 ,  B33Y10/00 ,  B29K71/00

Abstract: Process for densification of a poly(arylene ether ketone) (PAEK) powder or of a mixture of poly(arylene ether ketone) (PAEK) powders, the process being mixing the powder or the mixture of powders, in a mixer equipped with a rotary stirrer including at least one blade, for a period of between 30 minutes and 120 minutes, preferably of between 30 and 60 minutes, at a blade-tip speed of between 30 m/s and 70 m/s, preferably of between 40 and 50 m/s.

公开(公告)号：US20200223101A1

公开(公告)日：2020-07-16

申请号：US16470390

申请日：2017-12-20

Applicant: Arkema France

Inventor： Gilles Hochstetter ,  Arthur Pierre Babeau ,  Thibaut Savart ,  François Tanguy ,  Denis Huze ,  Mathieu Capelot ,  Patrice Gaillard

IPC: B29B15/12 ,  B29C70/20 ,  B29C70/54

Abstract: The invention relates to a process for manufacturing a pre-impregnated fibrous material comprising a continuous fibre fibrous material and at least one thermoplastic polymer matrix, characterized in that said pre-impregnated fibrous material is made of a single unidirectional ribbon or a plurality of parallel ribbons unidirectional and in that said method comprises an impregnation step, in particular at the core, of said fibrous material being in the form of a roving or of several parallel rovings by said thermoplastic polymer being in powder form, said step of impregnation being carried out with said at least one thermoplastic polymer and said fibrous material the D90/D10 ratio of which by volume of the thermoplastic polymer particles ranges from 1.5 to 50, in particular from 2 to 10 and the ratio of the average diameter by volume (D50) thermoplastic polymer particles on the average diameter of the unit fibres of said fibrous material ranges from 3 to 40, except for an impregnation process in aqueous suspension of a fibrous material made of carbon fibres by a thermoplastic polymer, said D50/mean unit fibre diameter ratio being comprised from 3 to 8, and excluding any electrostatic process in voluntary charge.