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公开(公告)号：US20050027058A1
公开(公告)日：2005-02-03
申请号：US10478606
申请日：2002-05-29
申请人： Anthony Dias , Andy Tsou , David Chung , Weiqing Weng
发明人： Anthony Dias , Andy Tsou , David Chung , Weiqing Weng
IPC分类号： B60C5/14 , C08K3/00 , C08K3/34 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/28 , C08L101/00 , C08K9/00
CPC分类号： B60C1/0008 , C08K3/04 , C08K3/346 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/283 , C08L23/28 , C08L2666/04
摘要： The present invention includes blends of a halogenated elastomer such as a butyl rubber or an interpolymer of, on one embodiment, a C4 to C7 isomonoolefin, a para-methylstyrene and a para-(halomethylstyrene), the interpolymer having been pre-mixed with an exfoliating compound and clay, the entire blend forming a nanocomposite in one embodiment. The clay may or may not have undergone an additional exfoliating treatment prior to blending with the halogenated elastomer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an air barrier.
摘要翻译： 本发明包括卤化弹性体如丁基橡胶或在一个实施方案中为C4至C7异单烯烃，对甲基苯乙烯和对 - （卤代甲基苯乙烯）的互聚物的共混体，该互聚物已经与 去角质化合物和粘土，在一个实施方案中，整个共混物形成纳米复合材料。 在与卤化弹性体共混之前，粘土可以或可以不经历额外的去角质处理。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为空气屏障。
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公开(公告)号：US20050027057A1
公开(公告)日：2005-02-03
申请号：US10478281
申请日：2002-05-29
申请人： Anthony Dias , Andy Tsou , David Chung , Weiqing Weng , Caiguo Gong
发明人： Anthony Dias , Andy Tsou , David Chung , Weiqing Weng , Caiguo Gong
IPC分类号： B60C5/14 , B60C1/00 , C08K3/00 , C08K3/34 , C08L21/00 , C08L23/22 , C08L23/28 , C08L23/36 , C08L77/00 , C08K9/00
CPC分类号： B60C1/0008 , C08K3/346 , C08K5/17 , C08L21/00 , C08L23/22 , C08L23/283 , C08L77/00 , C08L23/28 , C08L2666/20 , C08L2666/04
摘要： The present invention is a blend of an halogenated elastomer and a clay, desirably an exfoliated clay, to form a nanocomposite suitable for an air barrier. In one embodiment, the halogenated elastomer, is a polymer comprising C4 to C7 isoolefin derived units, a para-methylstyrene derived units, and para-(halomethylstyrene) derived units. In another embodiment, the halogenated elastomer is a butyl-type rubber. The clay may or may not have an additional exfoliating treatment present prior to blending with the interpolymer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an innerliner or innertube.
摘要翻译： 本发明是卤化弹性体和粘土的混合物，理想地是剥离粘土，以形成适合于空气屏障的纳米复合材料。 在一个实施方案中，卤化弹性体是包含C4至C7异烯烃衍生单元，对甲基苯乙烯衍生单元和对 - （卤代甲基苯乙烯）衍生单元的聚合物。 在另一个实施方案中，卤化弹性体是丁基型橡胶。 在与共聚体共混之前，粘土可以或可以不具有额外的去角质处理。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为内衬或内管。
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公开(公告)号：US20060100339A1
公开(公告)日：2006-05-11
申请号：US10518193
申请日：2003-05-30
申请人： Caiguo Gong , Anthony Dias , Andy Tsou , Beverly Poole , Kriss Karp
发明人： Caiguo Gong , Anthony Dias , Andy Tsou , Beverly Poole , Kriss Karp
IPC分类号： C08K3/34
CPC分类号： B82Y30/00 , C08F8/00 , C08K3/346 , C08K9/04 , C08K2201/011 , C08F10/00 , C08L15/00 , C08L19/006 , C08L19/00
摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C2 to C10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene-co-p-alkylstyrene) elastomers and poly(isobutylene-co-isoprene) elastomers, which are functionalized by reacting free radical generating agents and unsaturated carboxylic acids, unsaturated esters, unsaturated imides, and the like, with the elastomer. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.
摘要翻译： 本发明的一个实施方案是包含粘土和弹性体的纳米复合材料，所述弹性体包含至少C 2至C 10 O 12烯烃衍生单元; 其中弹性体还包括垂直于弹性体的官能化单体单元。 弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过使自由基产生剂和不饱和羧酸，不饱和酯，不饱和酰亚胺和 像弹性体一样。 粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。 组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。 本发明的纳米复合材料具有改善的空气阻隔性能，例如可用于轮胎内衬和内管。
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公开(公告)号：US20050277723A1
公开(公告)日：2005-12-15
申请号：US10518127
申请日：2003-05-30
申请人： Caiguo Gong , Anthony Dias , Andy Tsou , Beverly Poole , Kriss Karp
发明人： Caiguo Gong , Anthony Dias , Andy Tsou , Beverly Poole , Kriss Karp
摘要： An embodiment of the present invention is a nanocomposite comprising a clay and an elastomer comprising at least C2 to C10 olefin derived units; wherein the elastomer also comprises functionalized monomer units pendant to the elastomer. Desirable embodiments of the elastomer include poly(isobutylene-co-p-alkylstyrene) elastomers and poly(isobutylene-co-isoprene) elastomers, which are functionalized via Friedel-Crafts reaction with a Lewis acid and a functionalizing agent such as acid anhydrides and/or acylhalides. The clay is exfoliated in one embodiment by the addition of exfoliating agents such as alkyl amines and silanes to the clay. The composition can include secondary rubbers such as general purpose rubbers, and curatives, fillers, and the like. The nanocomposites of the invention have improved air barrier properties such as are useful for tire innerliners and innertubes.
摘要翻译： 本发明的一个实施方案是包含粘土和弹性体的纳米复合材料，所述弹性体包含至少C 2至C 10 O 12烯烃衍生单元; 其中弹性体还包括垂直于弹性体的官能化单体单元。 弹性体的优选实施方案包括聚（异丁烯 - 共 - 对烷基苯乙烯）弹性体和聚（异丁烯 - 共异戊二烯）弹性体，其通过与路易斯酸和官能化试剂如酸酐和/ 或酰卤。 粘土在一个实施方案中通过向粘土中加入去角质剂如烷基胺和硅烷来剥离。 组合物可以包括二次橡胶，例如通用橡胶，固化剂，填料等。 本发明的纳米复合材料具有改善的空气阻隔性能，例如可用于轮胎内衬和内管。
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公开(公告)号：US20050090616A1
公开(公告)日：2005-04-28
申请号：US10925117
申请日：2004-08-23
申请人： Anthony Dias , Patrick Brant , Andy Tsou , Rui Zhao , Ilan Duvdevani
发明人： Anthony Dias , Patrick Brant , Andy Tsou , Rui Zhao , Ilan Duvdevani
CPC分类号： B32B25/08 , B29C48/08 , B29C48/21 , B29C48/30 , B29C48/307 , B32B2250/05 , B32B2305/30 , B32B2307/7242 , B32B2309/105 , B60C1/0008 , C08L23/16 , C08L77/00 , C08L2666/20
摘要： The present invention relates to microlayered composites made from blends of elastomeric compositions and high barrier thermoplastic resins for use in air barriers, such as for tire innerliners. The invention also provides for processes to manufacture the microlayered composites such as through the use of microlayer coextrusion.
摘要翻译： 本发明涉及由弹性体组合物和高阻隔性热塑性树脂的混合物制成的微层复合材料，用于空气屏障，例如轮胎内衬。 本发明还提供了通过使用微层共挤出来制造微层复合材料的方法。
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公开(公告)号：US20050032937A1
公开(公告)日：2005-02-10
申请号：US10476936
申请日：2002-05-29
申请人： Andy Tsou , Anthony Dias
发明人： Andy Tsou , Anthony Dias
IPC分类号： B60C5/14 , C08K3/34 , C08K9/04 , C08L21/00 , C08L23/20 , C08L23/22 , C08L23/28 , C08L25/16 , C08L25/18 , C08L77/00 , C08L101/00 , C08K9/00
CPC分类号： C08L23/22 , C08K3/346 , C08L21/00 , C08L23/283 , C08L77/00 , C08L23/28 , C08L2666/20 , C08L2666/04 , C08L2666/02
摘要： The present invention is a blend of a thermoplastic engineering resin and an interpolymer of, on one embodiment, a C4 to C7 isomonoolefin, a para-methylstyrene and a para-(halomethylstyrene), the interpolymer having been pre-mixed with an exfoliated-clay, the entire blend forming a nanocomposite. The resin may or may not have a clay present prior to blending with the interpolymer. The interpolymer/clay mixture forms a distinct phase in the nanocomposite blend of the invention. The blend of the invention has improved air barrier properties and is suitable as an air barrier.
摘要翻译： 本发明是一种热塑性工程树脂和互聚物的共混物，在一个实施方案中，其为C4至C7异单烯烃，对甲基苯乙烯和对 - （卤代甲基苯乙烯），该互聚物已经与剥离粘土 ，整个共混物形成纳米复合材料。 在与共聚体共混之前，树脂可以具有也可以不具有粘土。 互聚物/粘土混合物在本发明的纳米复合材料混合物中形成不同的相。 本发明的共混物具有改善的空气阻隔性能，并且适合作为空气屏障。
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公开(公告)号：US20070106024A1
公开(公告)日：2007-05-10
申请号：US11270364
申请日：2005-11-09
申请人： Andy Tsou , David Chung
发明人： Andy Tsou , David Chung
IPC分类号： C08L77/00
CPC分类号： C08F8/20 , C08L23/283 , C08L77/00 , C08L79/08 , C08F210/00 , C08L2666/06
摘要： The present invention provides a thermoplastic composition which may be unvulcanized or vulcanized. The thermoplastic composition can be a blend of a thermoplastic engineering resin, a halogenated terpolymer of a C4 to C7 isomonoolefin, a para-alkylstyrene, and a multiolefin. The engineering resin can be a polyamide, such as nylon 6/66 copolymers for example. The isomonoolefin can be an isobutylene for example. The multiolefin can be a C4 to C14 diene, such as isoprene for example.
摘要翻译： 本发明提供可以未硫化或硫化的热塑性组合物。 热塑性组合物可以是热塑性工程树脂，C 4〜C 7 O 7异构烯烃的卤代三元共聚物，对烷基苯乙烯和多烯烃的共混物。 工程树脂可以是聚酰胺，例如尼龙6/66共聚物。 异源烯烃可以是例如异丁烯。 所述多烯烃可以是C 14-14 C 12-14二烯，例如异戊二烯。
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公开(公告)号：US6096427A
公开(公告)日：2000-08-01
申请号：US123037
申请日：1998-07-27
申请人： Jiann H. Chen , Charles C. Anderson , Andy Tsou
发明人： Jiann H. Chen , Charles C. Anderson , Andy Tsou
CPC分类号： G03G15/2057 , G03G2215/2016 , G03G2215/2032 , Y10T428/31507 , Y10T428/31562 , Y10T428/31565 , Y10T428/31598 , Y10T428/31605 , Y10T428/31721
摘要： A toner fuser belt for use with electrophotographic apparatus including a thermally conductive substrate through which heat is applied; a toner release layer formed over the substrate; and an adhesion promoting layer including an aliphatic cross-linked polyurethane which is stable at fusing temperatures provided between the substrate and the toner release layer and wherein the aliphatic cross-linked polyurethane is selected to provide good adhesion between the substrate and the toner release layer.
摘要翻译： 一种用于电子照相设备的调色剂定影带，包括通过其施加热量的导热基底; 形成在所述基板上的调色剂释放层; 以及包含脂肪族交联聚氨酯的粘合促进层，其在设置在基材和调色剂剥离层之间的熔合温度下稳定，并且其中选择脂族交联聚氨酯以在基材和调色剂释放层之间提供良好的粘合性。
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9.发明申请Thermoplastic elastomer composition having viscosity-enhanced and vulcanized elastomer dispersions 有权具有粘度增强和硫化弹性体分散体的热塑性弹性体组合物公开(公告)号：US20070060684A1
公开(公告)日：2007-03-15
申请号：US10548059
申请日：2003-03-06
申请人： Andy Tsou , Yoshihiro Soeda , Hsien-chang Wang , Matthew Measmer
发明人： Andy Tsou , Yoshihiro Soeda , Hsien-chang Wang , Matthew Measmer
IPC分类号： C08K5/00
CPC分类号： C08L23/283 , C08L77/00 , C08L2666/20
摘要： A thermoplastic elastomer composition having improved mechanical properties and fatigue resistance comprising (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an amine component selected from tertiary amines and secondary diamines, wherein the elastomers are dispersed as a domain in a continuous phase of the polyamide.
摘要翻译： 一种具有改进的机械性能和抗疲劳性的热塑性弹性体组合物，其包含（A）卤代异丁烯弹性体，（B）聚酰胺和（C）选自叔胺和仲二胺的胺组分，其中弹性体作为结构域分散在连续 聚酰胺的相。
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10.发明申请Thermoplastic elastomer composition with an improved rubber pelletization process 审中-公开具有改进的橡胶造粒工艺的热塑性弹性体组合物公开(公告)号：US20060252874A1
公开(公告)日：2006-11-09
申请号：US10548063
申请日：2003-03-06
申请人： Yoshihiro Soeda , Andy Tsou , Joyce Caraway
发明人： Yoshihiro Soeda , Andy Tsou , Joyce Caraway
IPC分类号： C09B67/00
CPC分类号： C08L77/06 , C08L23/283 , C08L77/00 , C08L77/02 , C08L2312/00 , C08L2666/20 , C08L2666/08 , C08L2666/04 , C08L2666/06
摘要： A thermoplastic elastomer composition having improved durability, heat resistant and flexibility comprising a dynamically vulcanized blend of (A) a halogenated isobutylene elastomer, (B) polyamide and (C) an antioxidant having a melting temperature more than 70° C. and less than 200° C., wherein the elastomer (A) is dispersed as a domain in a continuous phase of the polyamide (B) and the dynamically vulcanized blend of the components (A) and (B) is dynamically vulcanized in the presence of the antioxidant (C) as an anti-blocking agent.
摘要翻译： 具有改进的耐久性，耐热性和柔软性的热塑性弹性体组合物，其包含（A）卤代异丁烯弹性体，（B）聚酰胺和（C）熔融温度大于70℃且小于200的抗氧化剂的动态硫化混合物 ℃，其中弹性体（A）作为结构域分散在聚酰胺（B）的连续相中，组分（A）和（B）的动态硫化共混物在抗氧化剂存在下动态硫化（ C）作为防粘连剂。
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