摘要:
The present invention relates to the use of films, formed from an adhesive layer and a layer (A), for coating articles made of a thermoset, the adhesive layer comprising, by weiqht: 0 to 60 parts of PVDE, 10 to 100 parts of functionalized PMMA, 0 to 50 parts of an acrylic elastomer and 0 to 4 parts of a UV absorber, the total making up 100 parts, the layer (A) comprising, as main constituents, 0 to 100 parts of PVDF per 100 to 0 parts of PMMA, respectively. This film may be manufactured by coextrusion and is then fixed to the thermoset, for example by hot pressing.The invention also relates to an SMC (Sheet Moulding Compound) multilayer structure comprising, in this order: a backing film, a crosslinkable composition (the precursor of the thermoset), the above adhesive layer and the above layer (A).
摘要:
The present invention relates to a thermoformable multilayer film comprising in succession: a protective layer (A); a transparent layer (B) comprising (by weight the total amount being 100%) 0 to 100% of a fluoropolymer (B1) and 100 to 0% of a polymer (B2) essentially consisting of alkyl (meth)acrylate units; a layer (C) based on a polyamide with amine terminal groups; a layer (D) consisting of a polyolefin functionalized by an unsaturated carboxylic acid anhydride; a bonding layer (E) made of a polyolefin, said film being obtained by coextruding the various layers, said film being used to cover various substrates, for example by injection-moulding the substrate in the melt onto the multilayer film placed in the bottom of an injection mould, the layer (A) of the film being placed against the wall of the mould.
摘要:
The invention relates to a method of producing a film comprising at least one layer of a thermoplastic fluoro-polymer and at least one layer of another polymer (A). The inventive method consists in using extrusion blow molding to coextrude a fluoro-polymer and polymer (A) which adhere to one another; with a layer of another thermoplastic polymer (B) such that it forms a layer which is adjacent to the fluoropolymer/polymer (A) layer According to the invention, the thermoplastic polymer (B) is incompatible with the fluoro-polymer and polymer (A) and has adequate extrudate behavior to support the layers of fluoro-polymer and/or polymer (A). Once the coextrudate has been cooled, by separating the layer(s) of (B), at least the film is recovered, said film comprising at least one layer of a polymer selected from among thermoplastic fluoro-polymers and polymers (A).
摘要:
A structure made of a fluoropolymer layer and directly attached to one of its sides a tie layer based on a polyamide which results from the condensation of at least one diacid and at least one diamine of the following formula (1): in which R1 represents H or -Z1-NH2 and Z1 represents an alkyl, a cycloalkyl or an aryl having up to 15 carbon atoms and R2 represents H or -Z2-NH2 and Z2 represents an alkyl, a cycloalkyl or an aryl having up to 15 carbon atoms, it being possible for R1 and R2 to be identical or different. The tie resin may also be a copolymer having polyamide blocks and polyether blocks, the polyamide blocks resulting from condensation of at least one diacid and at least one diamine of formula (1). The invention also relates to a structure comprising a fluoropolymer layer, the tie layer and a substrate layer, respectively, as well as to a structure comprising a tie layer, respectively. This structure may be placed between two substrate layers and may be in the form of a sheet, film, profile or tube. It is particularly useful in the form of a tube for transporting gasoline between the tank and the injection device in motor-vehicle engines.
摘要:
The present invention relates to a microcomposite powder comprising particles from 1 um to 300 um of an electrically conductive product, which are coated with particles from 0.1 &mgr;m to 0.5 &mgr;m of a fluoropolymer. According to one advantageous form of the invention the microcomposite powder comprises a product (A) which is a polymer or an oligomer which can be dissolved with a solvent which is not a solvent for the fluoropolymer or for the electrically conductive product. The present invention also relates to objects consisting of this powder. These objects may be bipolar plates for fuel cells, or supercapacitor components.
摘要:
The present invention relates to a structure made of at least one layer containing a polyamide MXD.10/Z in which: MXD. 10 is the product of condensation of a blend of xylylenediamines containing 70 to 100% of meta-xylylenediamine and of sebacic acid, Z is a repeating unit chosen at least among the repeating units resulting from the polycondensation of a lactam monomer, from an alpha-omega carboxylic aminoacid, the repeating unit X1. Y1 where X1 designates the repeating unit resulting from the polycondensation an aliphatic, arylaliphatic, cycloapiphatic, or aromatic diamine and Yl designates the repeating unit resulting from the polycondensation of a aliphatic carboxylic, cycloaliphatic or aromatic diacid, and the weight ratio Z/(MXD+10+Z) is between 0 and 15%. The structure of the invention can either be made of one layer of this polyamide or either can contain a layer containing the polyamide MXD.10 and at least one layer of another material. The invention also relates to bottles, tanks, containers, pipes, tubes and many types of containment devices made using the previous structure. This structure can also be used into films to produce goods packaging. All these objects have good barrier properties. The invention also relates to these objects as well as the use of these structures and objects.
摘要:
The invention relates to a bonding agent for PVDF, containing alkyl (alkyl)acrylate units and units bearing a carboxylic acid functional group. This bonding agent, containing PVDF, forms a barrier to hydrocarbons. The invention also relates to the material including the present bonding agent, especially petrol pipes including polyamide and the present bonding agent, in conjunction with PVDF.
摘要:
The invention relates to a polyamide-based thermoplastic composition comprising, by weight: 50 to 98 parts of a polyamide (A1) nondiamine; 0.2 to 40 parts, preferably 0.2 to 9 parts, of a polyamide (A2) diamine, said polyamide (A2) being different from the polyamide (A1) and the ratio by mass (A2)/(A1) being less than 1; 1 to 60 parts, preferably 1 to 30 parts, of a reactive impact modifier (B) or of a blend of modifiers comprising at least one reactive impact modifier (B) or of a blend (B′) comprising at least one impact modifier and at least one reactive modifier. It also relates to an impact modifier composition and to the process for the preparation of a thermoplastic composition according to the invention using such an impact modifier composition.
摘要:
An immiscible polymer system is disclosed, said system itself ecomprising a stable mixture of polymers that are individually miscible with the polymers to be compatibilized. The compositions consisting of this polymer mixture may be obtained by extrusion.
摘要:
The present invention relates to antistatic and adherent compositions based on polyamide, which can be employed especially for the manufacture of composite materials and articles, such as multilayer pipes and/or conduits for conveying and/or storing hydrocarbons. The compositions contain carbon black and are employed for the production of pipes, containers and drums including:an inner layer in contact with the hydrocarbons, based on the said antistatic and adherent composition,a middle layer made of fluoropolymer, preferably of polyvinylidene fluoride, andan outer layer of polyamide,these layers being bonded to each other respectively by layers of adhesive binder. The invention also relates to a process for preparing these items.