摘要:
Disclosed are improved curable powder coating compositions comprised of a particulate, film-forming mixture of a polymer having reactive functional groups, and a curing agent therefor having functional groups reactive with the functional groups of the polymer and present in an amount sufficient to cure the coating composition, wherein the inclusion of a particular polyester which has carboxylic acid functional groups improves adhesion to metal, particularly aluminum, and filiform corrosion resistance.
摘要:
A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.
摘要:
A polyester prepared by free radical polymerization of an unsaturated polyester prepolymer, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.
摘要:
The present invention is directed to a coating composition comprising polyurea formed from a reaction mixture comprising: (a) a first component comprising isocyanate, wherein said isocyanate comprises an isocyanate functional prepolymer formed from a reaction mixture comprising isocyanate and a material comprising a phosphorus-containing polyol; and (b) a second component comprising an amine.
摘要:
An aminoplast-curable film-forming composition is disclosed. The film-forming composition is a crosslinkable composition comprising (1) a material containing a plurality of carbamate and/or urea functional groups and (2) an aminoplast crosslinking agent. The composition provides a coating with improved acid etch resistance, making the coating particularly useful as an automotive clear coat.
摘要:
Disclosed is an adduct of a mercapto-functional monohydric alcohol and a vinyl-type silane having at least one hydrolyzable group directly attached to a silicon atom, the adduct prepared by reacting the mercapto-functional monohydric alcohol and the vinyl-type silane in the presence of a free radical initiator.Also disclosed is an NCO-functional compound comprising the reaction product of: (A) the aforesaid adduct of a mercapto-functional monohydric alcohol and a vinyl-type silane having at least one hydrolyzable group directly attached to a silicon atom, and (B) an organic polyisocyanate.
摘要:
A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin; and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formulas: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom;W is C.sub.1 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkenylene;V is C.sub.1 -C.sub.18 alkylene, C.sub.1 -C.sub.18 hydroxyl substituted alkylene, C.sub.2 -C.sub.18 alkenylene, C.sub.2 -C.sub.18 hydroxyl substituted alkenylene; andR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical.
摘要:
Curable compositions based on polyuretidiones, polythiols and photoactivable bases are disclosed. Also a process for generating isocyanate groups by exposing uretidiones to radiation in the range of 100-315 nm is disclosed. The process can be used in a dual curing system for curing compositions that comprise groups that under go photoinduced polymerizations and active hydrogen groups that react with the generated isocyanates.
摘要:
A method of preparing an organic sol of particles is provided. Steps include: a) providing a suspension of particles in an aqueous medium; b) adding an organic liquid to form an admixture where the concentration of particles in the admixture is less than or equal to 40 percent by weight; c) maintaining the admixture at a temperature and pressure and for a time sufficient to reduce the water content to less than 30 percent by weight while simultaneously adding a water-compatible organic liquid at a rate sufficient to maintain a concentration of particles in the admixture at less than or equal to 50 percent by weight; and d) adding at least one polymer while maintaining the admixture at a temperature and pressure and for a time sufficient to provide an organic sol of particles comprising 1 percent by weight or less of water.
摘要:
The present invention relates to solid, particulate free film-forming compositions, multi-layer composite coatings comprising such film-forming compositions and methods of applying such multi-component composite coatings to a substrate. The solvent free film-forming compositions include UV-curable powder coating compositions comprising an amorphous (meth)acrylate terminated poly(ester-urethane) and optionally a second (meth)acrylate terminated polyurethane.