Bulk Polymerization Process For Producing Polydienes
    6.
    发明申请
    Bulk Polymerization Process For Producing Polydienes 有权
    用于生产聚二烯的大量聚合方法

    公开(公告)号:US20140378630A1

    公开(公告)日:2014-12-25

    申请号:US14368946

    申请日:2012-12-27

    IPC分类号: C08F136/06

    摘要: A process for preparing a polydiene, the process comprising the steps of: polymerizing conjugated diene monomer with a metallocene complex catalyst system within a polymerization mixture that includes less than 20% by weight of solvent based on the total weight of the polymerization mixture, where the metallocene complex catalyst system includes the combination or reaction product of: (a) metallocene complex, (b) an alkylating agent, and optionally (c) a non-coordinating anion.

    摘要翻译: 一种制备聚二烯的方法,该方法包括以下步骤:在聚合混合物内聚合共轭二烯单体与茂金属络合物催化剂体系,其包含基于聚合混合物的总重量小于20重量%的溶剂,其中 茂金属络合物催化剂体系包括以下组合或反应产物:(a)茂金属络合物,(b)烷基化剂和任选的(c)非配位阴离子。

    Process for preparing blends of trans-1,4-polybutadiene and syndiotactic 1,2-polybutadiene

    公开(公告)号:US10035908B1

    公开(公告)日:2018-07-31

    申请号:US15149816

    申请日:2016-05-09

    IPC分类号: C08L47/00

    摘要: A process for preparing a blend of trans-1,4-polybutadiene and syndiotactic 1,2-polybutadiene, the process comprising the steps of (i) polymerizing 1,3-butadiene in the presence of a lanthanide-based catalyst to form a polymerization mixture including trans-1,4-polybutadiene, where the lanthanide-based catalyst includes (a) a lanthanide-containing compound, and (b) an organomagnesium compound; and (ii) polymerizing 1,3-butadiene in the presence of an iron-based catalyst within the polymerization mixture including trans-1,4-polybutadiene to form syndiotactic 1,2-polybutadiene within the polymerization mixture including trans-1,4-polybutadiene and thereby produce a blend of trans-1,4-polybutadiene and syndiotactic 1,2-polybutadiene; where the iron-based catalyst includes (a) an iron-containing compound, (b) an organomagnesium compound, and (c) a silyl phosphonate.