摘要:
A method for preparing a functionalized polymer, the method comprising the steps of polymerizing monomer to form a reactive polymer, and reacting the reactive polymer with a polycyano compound.
摘要:
A method for producing a polydiene, the method comprising the steps of (i) forming an active catalyst by combining a lanthanide-containing compound, an alkylating agent, and a halogen source in the substantial absence of an organosulfide; and (ii) polymerizing conjugated diene monomer in the presence of the active catalyst and an organosulfide.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer and reacting the reactive polymer with a heterocyclic nitrile compound.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of preparing a reactive polymer and reacting the reactive polymer with a heterocyclic nitrile compound.
摘要:
A method for preparing a coupled polymer, the method comprising the steps of: (i) polymerizing monomers to form a reactive polymer, and (ii) reacting the reactive polymer with a boronic ester containing a cyano group.
摘要:
A process for preparing a polydiene, the process comprising the steps of: polymerizing conjugated diene monomer with a metallocene complex catalyst system within a polymerization mixture that includes less than 20% by weight of solvent based on the total weight of the polymerization mixture, where the metallocene complex catalyst system includes the combination or reaction product of: (a) metallocene complex, (b) an alkylating agent, and optionally (c) a non-coordinating anion.
摘要:
A vulcanizable composition comprising rubber component, a filler, and a curing agent, where the rubber component includes a block copolymer of polybutadiene and polyisoprene, and where the block copolymer has a cis content of at least 90%.
摘要:
A method for preparing a functionalized polymer, the method comprising the steps of (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with an imine compound containing a cyano group.
摘要:
A process for preparing a blend of trans-1,4-polybutadiene and syndiotactic 1,2-polybutadiene, the process comprising the steps of (i) polymerizing 1,3-butadiene in the presence of a lanthanide-based catalyst to form a polymerization mixture including trans-1,4-polybutadiene, where the lanthanide-based catalyst includes (a) a lanthanide-containing compound, and (b) an organomagnesium compound; and (ii) polymerizing 1,3-butadiene in the presence of an iron-based catalyst within the polymerization mixture including trans-1,4-polybutadiene to form syndiotactic 1,2-polybutadiene within the polymerization mixture including trans-1,4-polybutadiene and thereby produce a blend of trans-1,4-polybutadiene and syndiotactic 1,2-polybutadiene; where the iron-based catalyst includes (a) an iron-containing compound, (b) an organomagnesium compound, and (c) a silyl phosphonate.
摘要:
A method for providing a polymer having terminal functionality involves reacting a terminally active polymer with an α,β-ethylenically unsaturated compound that includes a group 2-13 element so as to provide a functionalized polymer. The resulting polymer exhibits enhanced interactivity with particulate fillers and can be used in the manufacture of vulcanizates.