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    Antistatic composition
    3.
    发明授权
    Antistatic composition 失效
    防静电组成

    公开(公告)号：US5965206A

    公开(公告)日：1999-10-12

    申请号：US925015

    申请日：1997-09-08

    申请人： Bruno Hilti ,  Ernst Minder ,  Jurgen Pfeiffer ,  Markus Grob

    发明人： Bruno Hilti ,  Ernst Minder ,  Jurgen Pfeiffer ,  Markus Grob

    IPC分类号： C09K3/16 ,  C08G69/44 ,  C08K3/00 ,  C08K3/24 ,  C08K5/00 ,  C08K7/02 ,  C08K13/04 ,  C08L23/06 ,  C08L77/02 ,  C08L101/00 ,  C08L101/12 ,  B05D1/00

    CPC分类号： C08L101/00 ,  C08L2201/04 ,  C08L23/06 ,  C08L77/02 ,  Y10S524/911 ,  Y10T428/29

    摘要： The invention relates to a composition that comprises a thermoplastic or elastomeric polymeric substrate (A) and an antistatic mixture (B) in the form of contiguous fibers, which mixture comprises (b1) an organic polymeric material that is fibrous or forms fibers on mixing and is not soluble in the thermoplastic or elastomeric polymeric substrate (A); (b2) a polymer or copolymer capable of ion conduction that has blocks for complexing or solvating a salt of an inorganic or low-molecular-weight organic protonic acid (b3) and has a better compatibility with the organic polymer (b1) that is fibrous or forms fibers on mixing than with the polymeric organic substrate (A); and (b3) a salt of an inorganic or low-molecular-weight organic protonic acid such as NaClO.sub.4 or K P F.sub.6 that has been complexed or solvated in the polymer or copolymer (b2). The invention relates also to the antistatic mixture (B) as such, to its use in rendering polymers antistatic and to a process for the preparation of antistatic thermoplastic or elastomeric polymeric substrates.

    摘要翻译： 本发明涉及包含热塑性或弹性体聚合物基材（A）和邻接纤维形式的抗静电混合物（B）的组合物，该混合物包含（b1）在混合时纤维状或形成纤维的有机聚合材料， 不溶于热塑性或弹性聚合物基材（A）; （b2）能够离子传导的聚合物或共聚物，其具有用于络合或溶解无机或低分子量有机质子酸（b3）的盐的嵌段，并且与纤维状的有机聚合物（b1）具有更好的相容性 或在混合时形成纤维，而不是聚合物有机基材（A）; 和（b3）已经在聚合物或共聚物（b2）中络合或溶剂化的无机或低分子量有机质子酸如NaClO 4或K P F 6的盐。 本发明还涉及抗静电混合物（B），其用于使聚合物抗静电，以及制备抗静电热塑性或弹性聚合物基材的方法。

    Electroconductive composition
    4.
    发明授权
    Electroconductive composition 失效
    导电组合物

    公开(公告)号：US5871670A

    公开(公告)日：1999-02-16

    申请号：US793716

    申请日：1997-03-03

    申请人： Bruno Hilti ,  Ernst Minder ,  Jurgen Pfeiffer

    发明人： Bruno Hilti ,  Ernst Minder ,  Jurgen Pfeiffer

    IPC分类号： C07D335/02 ,  C07D339/04 ,  C07D339/06 ,  C07D339/08 ,  C07D345/00 ,  C07D495/06 ,  C07D495/22 ,  C07D517/06 ,  C07D517/22 ,  C08K5/45 ,  C08L101/00 ,  H01B1/12 ,  H01B1/20 ,  C08K5/00

    CPC分类号： H01B1/121 ,  Y10S524/91 ,  Y10S524/911

    摘要： A composition comprising a matrix of a thermoplastic, thermosetting or a structurally crosslinked polymer, in which is incorporated an electroconductive network of crystal needles of a charge transfer complex (abbreviated to CT complex) from an electron donor and an electron acceptor, characterized in that:(1) the matrix contains uniformly distributed an excess, with respect to the CT complex formation, either of at least one electron donor or at least one electron acceptor as weakly polymer-soluble finely divided particles,(2) the CT complex is formed either by at least one weakly polymer-soluble electron donor and at least one polymer-soluble electron acceptor or by at least one weakly polymer-soluble electron acceptor and at least one polymer-soluble electron donor, and(3) microcrystalline needles grow from the weakly polymer-soluble particles in the polymer mass, which microcrystalline needles are in contact with and connect the weakly polymer-soluble particles to form a network which penetrates the polymer mass.

    摘要翻译： PCT No.PCT / EP95 / 03537。 371日期1997年3月3日 102（e）1997年3月3日PCT PCT 1995年9月8日PCT公布。 公开号WO96 / 09629 日期：1996年3月28日一种包含热塑性，热固性或结构交联聚合物基体的组合物，其中掺入电子转移络合物（缩写为CT络合物）的晶体针的电导网络和电子受体 其特征在于：（1）相对于CT络合物形成，基质含有均匀分布的过量的至少一种电子给体或至少一种电子受体作为弱聚合物可溶的细碎颗粒，（2） CT复合物由至少一种弱聚合物可溶电子给体和至少一种聚合物可溶电子受体或至少一种弱聚合物可溶电子受体和至少一种聚合物可溶电子给体形成，和（3）微晶 针从聚合物物质中的弱聚合物可溶性颗粒生长，微晶针与弱聚合物可溶性颗粒接触并连接 以形成穿透聚合物质量的网络。

    Process for the production of conductive layers
    6.
    发明授权
    Process for the production of conductive layers 失效
    生产导电层的工艺

    公开(公告)号：US5348762A

    公开(公告)日：1994-09-20

    申请号：US62038

    申请日：1993-05-14

    申请人： Walther Hofherr ,  Ernst Minder ,  Bruno Hilti ,  Jean-Philippe Ansermet

    发明人： Walther Hofherr ,  Ernst Minder ,  Bruno Hilti ,  Jean-Philippe Ansermet

    IPC分类号： C07D345/00 ,  C07D495/06 ,  C08K5/45 ,  C08K5/56 ,  C09D5/24 ,  C09K3/00 ,  H01B1/12 ,  H01B1/20 ,  H01B5/16 ,  B05D5/12

    CPC分类号： C09D5/24 ,  H01B1/121

    摘要： A process for the production of a conductive layer on a substrate, said conductive layer comprising a network of crystal needles of conductive radical cation salts based on tetrathiotetracenes, tetraselenotetracenes or tetratellurotetracenes and chlorine, bromine, iodine or copper dichloride, and said network is embedded in a polymer matrix, by coating at least one side of said substrate with a) a suspension of crystal needles of the radical cation salts of formula I in an inch solvent which may additionally contain a thermoplastic polymer or at least one starting compound for a thermosetting polymer, or b) a solution (b1) of a tetrathiotetracene, tetraselenotetracene or tetratellurotetracene, (b2) of a monomeric, oligomeric or polymeric organic compound which contains chlorine, bromine or iodone and, when heated with these tetracenes, forms a radical cation salt, or of anhydrous CuCl.sub.2, a CuCl.sub.2 aquo complex or a CuCl.sub.2 solvent complex, and (C3) of a thermoplastic polymer or at least one starting compound for a thermosetting polymer, in an inert solvent, and subsequently evaporating the solvent, which process comprises applying said layer by spraying the suspension a) or solution b) from nozzles on to the substrate. Very fine meshed, dense and isotropic crystal needle networks are obtained. The coatings exhibit rapid surface discharges and are suitable for use as electostatic coatings or, on account of their good electrical conductivities, as electrode material for display elements.

    摘要翻译： 一种用于在基底上制备导电层的方法，所述导电层包括基于四硫代四烯，四硒代四烯或四氯四烯的导电自由基阳离子盐和氯，溴，碘或二氯化铜的晶体针网络，并且所述网络嵌入 聚合物基质，通过用a）式I的自由基阳离子盐的晶体针的溶液在英寸溶剂中悬浮，所述悬浮液可以另外含有热塑性聚合物或至少一种用于热固性聚合物的起始化合物 或b）含有氯，溴或碘的单体，低聚或聚合有机化合物的四联四烯，四硒基四烯或四亚甲基四苯（b2）的溶液（b1），并且当与这些四环加热形成自由基阳离子盐时， 或无水CuCl 2，CuCl 2水溶液络合物或CuCl 2溶剂络合物，和（C3）热塑性聚合物或至少一种 在惰性溶剂中的起始化合物，然后蒸发溶剂，该方法包括通过将悬浮液a）或溶液b）从喷嘴喷射到基底上来施加所述层。 获得非常细的网状，致密和各向同性的晶体针网络。 涂层表现出快速的表面放电，并且适合用作静电涂层，或由于其良好的导电性，可用作显示元件的电极材料。

    Antistatic and electrically conducting composition
    10.
    发明授权
    Antistatic and electrically conducting composition 失效
    抗静电和导电组合物

    公开(公告)号：US5324791A

    公开(公告)日：1994-06-28

    申请号：US991678

    申请日：1992-12-16

    申请人： Jurgen Finter ,  Bruno Hilti ,  Carl W. Mayer ,  Ernst Minder

    发明人： Jurgen Finter ,  Bruno Hilti ,  Carl W. Mayer ,  Ernst Minder

    IPC分类号： C08L101/00 ,  C08F20/22 ,  C08F20/26 ,  C08K5/36 ,  C08K5/46 ,  C08K5/48 ,  C08L101/04 ,  C09D5/24 ,  C09K3/16 ,  H01B1/12 ,  H01B1/20 ,  H05F1/00 ,  C08F8/20

    CPC分类号： C08K5/46 ,  C08F20/22 ,  C08F20/26 ,  C08K5/48 ,  C09D5/24 ,  C09K3/16 ,  H01B1/121

    摘要： The action of thermoplastic polymers to whose polymer backbone aliphatic or cycloaliphatic groups are bonded via a group --O--, --O--CO--, --CO--OR.sup.22 --OCO-- or --CO--O--, said aliphatic or cycloaliphatic groups being substituted by Cl, Br and/or iodine in the .alpha.-, .beta.-, .gamma.- or .omega.-position, on an unsubstituted or substituted tetrathio-, tetraseleno- or tetratelluronaphthalene or -tetracene contained in this polymer gives electrically conducting compositions by the formation of charge transfer complexes. These compositions are suitable for the production of antistatic or electrically conducting mouldings, sheets, filaments, fibres, coatings and composites.

    摘要翻译： 其聚合物主链脂族或脂环族基团通过基团-O - ， - CO-，-CO-OR 22 -OCO-或-CO-O-键合的热塑性聚合物的作用，所述脂族或脂环族基团被 在该聚合物中包含的未取代或取代的四硫代 - ，四硒 - 或四碲化萘或 - 四烯上的α-，β-，γ-或ω-位中的Cl，Br和/或碘通过形成电荷产生导电组合物 转移复合物。 这些组合物适用于生产抗静电或导电模制品，片材，长丝，纤维，涂料和复合材料。