摘要:
The present invention relates to inner coatings of metal food containers and packaging and to a process for their production. The coatings are applied to the inside of at least a portion of the surface area of containers that are in direct contact with foods or other consumable products and subsequently cured. The coatings include a) at least one polyisocyanate containing an average of at least two NCO groups per molecule, at least 95% of the NCO groups being blocked with a blocking agent, and b) at least one polyhydroxyl compound containing an average of at least two hydroxyl groups per molecule that react with NCO groups.
摘要:
The present invention relates to inner coatings of metal food containers and packaging and to a process for their production. The coatings are appied to the inside of at least a portion of the surface area of containers that are in direct contact with foods or other consumable products and subsequently cured. The coatings include a) at least one polyisocyanate containing an average of at least two NCO groups per molecule, at least 95% of the NCO groups being blocked with a blocking agent, and b) at least one polyhydroxyl compound containing an average of at least two hydroxyl groups per molecule that react with NCO groups.
摘要:
Storage-stable Polyisocyanates based on aliphatic and/or cycloaliphatic diisocyanates including from 1 to 20% by weight of alkylamino groups of the formula R1R2N as a constituent of biuret groups, wherein R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals, and where at least 95 mol % of the isocyanate groups are blocked with at least one blocking agent, and the polyisocyanates contain from 4.0 to 21.0% by weight of blocked and free NCO groups (calculated as NCO, molecular weight=42). The polyisocyanates are used to produce coating compositions, coatings, and coated substrates.
摘要:
Storage-stable blocked polyisocyanates prepared by reacting one or more polyisocyanates with one or more biuretizing agents and optionally, catalysts such that in the blocked end product there are 5-45 equivalent percent of biuret groups according to formula (I) based on the sum total of all free and blocked NCO groups; optionally modifying the resulting biuret polyisocyanates with the aid of isocyanate-reactive compounds and/or catalysts, with further reaction of free NCO groups; and subsequently blocking at least 95 mol percent of the remaining free NCO groups with a blocking agent according to the formula R1R2NH, where R1 and R2 independently of one another are aliphatic or cycloaliphatic C1-C12 alkyl radicals. The blocked polyisocyanates can be used to make polyurethane polymers and coating compositions, which can be used to coat substrates.
摘要:
Process for preparing compounds of the formula (I) where R1, R2 and R3 are independently hydrogen, alkyl or cycloalkyl, characterized in that an aldehyde of the formula (II) is reacted with CH2(CN)2 in the presence of butanol.
摘要:
Disclosed herein are bridged perinones/quinophthalones of the general formula (I) or tautomeric forms thereof where X1, X2, Ar1 Ar2 and B are as described herein and are particularly characterized in that the bridging B is a radical of the formula —T1—W—T2—, where T1 and T2 are independently O or S and W is alkylene, especially C1-C6-alkylene, C6-C10-arylene, especially phenylene or cycloalkylene, which are each optionally substituted or is the radical of the formula (a) where the phenyl rings are optionally substituted and A is a radical of the formula O, S, SO, SO2 or CO, optionally substituted alkylene, or optionally substituted cycloalkylene, said alkylene or cycloalkylene being attached to the adjacent phenyl rings itself or else via its substitutents, or W is a radical of the formulae where s and t are independently from 1 to 6, the ends of the radical B each being attached to an aromatic carbon atom of the two radicals Ar1 and Ar2. EINBETTENEINBETTEN
摘要:
Blocked polyisocyanates and one-component stoving systems containing these blocked polyisocyanates, and the preparation thereof and their use for the preparation of lacquers, paints, adhesives and elastomers, wherein blocked polyisocyanates are prepared by reacting polyisocyanates with secondary amines corresponding to the formula wherein R1—R4 can be identical or different and denote hydrogen, C1–C6-alkyl or cycloalkyl, R5 denotes C1–C10-alkyl, C3–C10-cycloalkyl, y denotes a number from 2 to 8, and B represents wherein R6–R8 can be identical or different and independently of one another denote C1–6-alkyl and/or C3–C6-cycloalkyl, R9 denotes hydrogen or C1–6-alkyl or C3–C6-cycloalkyl.
摘要:
Blocked polyisocyanates and one-component stoving systems containing these blocked polyisocyanates, and the preparation thereof and their use for the preparation of lacquers, paints, adhesives and elastomers. The blocked polyisocyanates are derived from polyisocyanates reacted with secondary amines and cationic, anionic and/or nonionic hydrophilizing agents such that they are incorporated into the polyisocyanate at a ratio of from 20:1 to 1:1, wherein the blocking agents correspond to the formula R1–R4 can be identical or different and independently of one another denote hydrogen, C1–C6-alkyl or C3–C6-cycloalkyl, R5 denotes C1–C10-alkyl, C3–C10-cycloalkyl, and B represents wherein R6–R8 can be identical or different and independently of one another denote C1–C6-alkyl and/or C1–C6-cycloalkyl, R9 denotes hydrogen or C3–C6-alkyl or C3–C6-cycloalkyl.
摘要:
The present invention relates to a process for preparing 1-amino-4-hydroxyanthraquinones of the formula (I) wherein R is an aliphatic or aromatic radical, by reacting 1,4-dihydroxyanthraquinone, optionally as a mixture with 2,3-dihydro-1,4-dihydroxyanthraquinone, with aliphatic or aromatic amines in the presence of N-methyl-2-pyrrolidone.
摘要:
Reaction of pyrazolones and methyleneindolines with orthoformic esters is an advantageous one-step process for preparing asymmetrical methine dyes.