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公开(公告)号：US07615509B2
公开(公告)日：2009-11-10
申请号：US11974079
申请日：2007-10-11
申请人： Chuansheng Bai , EL-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Peter W. Jacobs , Jun Han , Daniel M. Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe, Jr. , David M. Lowe
发明人： Chuansheng Bai , EL-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Peter W. Jacobs , Jun Han , Daniel M. Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe, Jr. , David M. Lowe
IPC分类号： B01J21/18
CPC分类号： B01J37/20 , B01J21/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/885 , B01J23/8873 , B01J23/8898 , B01J31/0201 , B01J31/0254 , B01J31/2234 , B01J31/2239 , B01J35/08 , B01J35/1019 , B01J35/1047 , B01J35/1061 , B01J37/0203 , B01J37/0205 , B01J37/08 , B01J37/084 , B01J2231/62 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08
摘要： Supported metallic catalysts comprised of a Group VIII metal, a Group VIB metal, and an organic additive, and methods for synthesizing supported metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic additive, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要翻译： 提供了由VIII族金属，VIB族金属和有机添加剂组成的负载金属催化剂，以及用于合成负载型金属催化剂的方法。 催化剂通过其中两种金属的前体混合并与至少一种有机添加剂相互作用，干燥，煅烧和硫化的方法制备。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。
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公开(公告)号：US20080146438A1
公开(公告)日：2008-06-19
申请号：US11974079
申请日：2007-10-11
申请人： Chuangsheng Bai , EL-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Peter W. Jacobs , Jun Han , Daniel M. Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe , David M. Lowe
发明人： Chuangsheng Bai , EL-Mekki El-Malki , Jeff Elks , Zhiguo Hou , Jon M. McConnachie , Pallassana S. Venkataraman , Jason Wu , Peter W. Jacobs , Jun Han , Daniel M. Giaquinta , Alfred Hagemeyer , Valery Sokolovskii , Anthony F. Volpe , David M. Lowe
CPC分类号： B01J37/20 , B01J21/04 , B01J23/85 , B01J23/882 , B01J23/883 , B01J23/885 , B01J23/8873 , B01J23/8898 , B01J31/0201 , B01J31/0254 , B01J31/2234 , B01J31/2239 , B01J35/08 , B01J35/1019 , B01J35/1047 , B01J35/1061 , B01J37/0203 , B01J37/0205 , B01J37/08 , B01J37/084 , B01J2231/62 , B01J2531/64 , B01J2531/66 , B01J2531/845 , B01J2531/847 , C10G45/08
摘要： Supported metallic catalysts comprised of a Group VIII metal, a Group VIB metal, and an organic additive, and methods for synthesizing supported metallic catalysts are provided. The catalysts are prepared by a method wherein precursors of both metals are mixed and interacted with at least one organic additive, dried, calcined, and sulfided. The catalysts are used for hydroprocessing, particularly hydrodesulfurization and hydrodenitrogenation, of hydrocarbon feedstocks.
摘要翻译： 提供了由VIII族金属，VIB族金属和有机添加剂组成的负载金属催化剂，以及用于合成负载型金属催化剂的方法。 催化剂通过其中两种金属的前体混合并与至少一种有机添加剂相互作用，干燥，煅烧和硫化的方法制备。 催化剂用于烃原料的加氢处理，特别是加氢脱硫和加氢脱氮。
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3.发明申请Selective Catalysts Having Silica Supports For Naphtha Hydrodesulfurization 有权具有二氧化硅支持石脑油加氢脱硫的选择性催化剂公开(公告)号：US20100320123A1
公开(公告)日：2010-12-23
申请号：US12087978
申请日：2007-01-12
申请人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. Mcconnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, JR. , Jun Han
发明人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. Mcconnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, JR. , Jun Han
CPC分类号： C10G45/08 , B01J21/08 , B01J23/882 , B01J31/04 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2208 , B01J35/10 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/0203 , B01J37/20 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2300/80 , C10G2400/02
摘要： A method for hydrodesulfurizing FCC naphtha is described. More particularly, a Co/Mo metal hydrogenation component is loaded on a silica or modified silica support in the presence of organic ligand and sulfided to produce a catalyst which is then used for hydrodesulfurizing FCC naphtha. The silica support has a defined pore size distribution which minimizes olefin saturation.
摘要翻译： 描述了FCC石脑油加氢脱硫方法。 更具体地说，在有机配体存在下将Co / Mo金属氢化组分负载在二氧化硅或改性二氧化硅载体上并硫化以产生催化剂，然后将其用于加氢脱硫FCC石脑油。 二氧化硅载体具有确定的最小化烯烃饱和度的孔径分布。
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4.发明授权Selective catalysts having silica supports for naphtha hydrodesulfurization 有权具有用于石脑油加氢脱硫的二氧化硅载体的选择性催化剂公开(公告)号：US08216958B2
公开(公告)日：2012-07-10
申请号：US12087978
申请日：2007-01-12
申请人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. McConnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, Jr. , Jun Han
发明人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. McConnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, Jr. , Jun Han
CPC分类号： C10G45/08 , B01J21/08 , B01J23/882 , B01J31/04 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2208 , B01J35/10 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/0203 , B01J37/20 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2300/80 , C10G2400/02
摘要： A method for hydrodesulfurizing FCC naphtha is described. More particularly, a Co/Mo metal hydrogenation component is loaded on a silica or modified silica support in the presence of organic ligand and sulfided to produce a catalyst which is then used for hydrodesulfurizing FCC naphtha. The silica support has a defined pore size distribution which minimizes olefin saturation.
摘要翻译： 描述了FCC石脑油加氢脱硫方法。 更具体地说，在有机配体存在下将Co / Mo金属氢化组分负载在二氧化硅或改性二氧化硅载体上并硫化以产生催化剂，然后将其用于加氢脱硫FCC石脑油。 二氧化硅载体具有确定的最小化烯烃饱和度的孔径分布。
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公开(公告)号：US08263519B2
公开(公告)日：2012-09-11
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
IPC分类号： B01J29/06
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。
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公开(公告)号：US20100075831A1
公开(公告)日：2010-03-25
申请号：US12316979
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/068 , B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/405 , B01J29/44 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/12 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括至少两种沸石，包括具有低二氧化硅与氧化铝比的沸石。 催化剂可以与低表面粘合剂组合，或者配制的催化剂可以具有高比例的沸石表面积与外表面积。
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公开(公告)号：US08030240B2
公开(公告)日：2011-10-04
申请号：US12316979
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
发明人： Christine N. Elia , Mohan Kalyanaraman , Lei Zhang , Michel A. Daage , Darden Sinclair , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, Jr.
IPC分类号： B01J29/06
CPC分类号： B01J29/80 , B01J29/18 , B01J29/22 , B01J29/405 , B01J29/44 , B01J29/70 , B01J29/74 , B01J37/0009 , B01J2229/12 , B01J2229/20 , B01J2229/32 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include at least two zeolites, including a zeolite with a low silica to alumina ratio. The catalysts may be combined with a low surface binder, or alternatively the catalysts as formulated may have a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括至少两种沸石，包括具有低二氧化硅与氧化铝比的沸石。 催化剂可以与低表面粘合剂组合，或者配制的催化剂可以具有高比例的沸石表面积与外表面积。
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公开(公告)号：US20090176643A1
公开(公告)日：2009-07-09
申请号：US12316977
申请日：2008-12-18
申请人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
发明人： Christine N. Elia , Mohan Kalyanaraman , Michel A. Daage , Stephen H. Brown , Lei Zhang , Robert A. Crane , Valery Sokolovskii , David M. Lowe , Jun Han , Nicholas Ohler , Daniel M. Giaquinta , Anthony F. Volpe, JR.
IPC分类号： B01J29/44 , B01J29/06 , B01J29/40 , B01J29/068
CPC分类号： B01J29/703 , B01J21/06 , B01J21/063 , B01J29/7046 , B01J29/7461 , B01J29/7492 , B01J35/1014 , B01J37/0009 , B01J2229/20 , B01J2229/36 , B01J2229/42 , C10G45/64
摘要： Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
摘要翻译： 提供用于烃进料脱蜡的催化剂，特别是具有升高的硫和氮水平的进料。 脱蜡催化剂包括具有低二氧化硅与氧化铝比率与低表面粘合剂组合的沸石，或者配制的催化剂具有高比例的沸石表面积与外表面积。
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公开(公告)号：US20080287289A1
公开(公告)日：2008-11-20
申请号：US12183244
申请日：2008-07-31
申请人： Tao Wang , Les Wade , Ioan Nicolau , Barbara Kimmich , Victor Wong , Yumin Liu , Jun Han , Valery Sokolovskii , Alfred Hagemeyer , David M. Lowe , Anthony Volpe , Karin Yaccato
发明人： Tao Wang , Les Wade , Ioan Nicolau , Barbara Kimmich , Victor Wong , Yumin Liu , Jun Han , Valery Sokolovskii , Alfred Hagemeyer , David M. Lowe , Anthony Volpe , Karin Yaccato
CPC分类号： B01J23/58 , B01J23/464 , B01J23/52 , B01J33/00 , B01J35/002 , B01J35/0026 , B01J35/008 , B01J35/0086 , B01J35/026 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/0244 , B01J37/16 , C07C67/055 , C07C69/15
摘要： The present invention addresses at least four different aspects relating to catalyst structure, methods of making those catalysts and methods of using those catalysts for making alkenyl alkanoates. Separately or together in combination, the various aspects of the invention are directed at improving the production of alkenyl alkanoates and VA in particular, including reduction of by-products and improved production efficiency. A first aspect of the present invention pertains to a unique palladium/gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect pertains to a palladium/gold catalyst or pre-catalyst that is based on a layered support material where one layer of the support material is substantially free of catalytic components. A third aspect pertains to a palladium/gold catalyst or pre-catalyst on a zirconia containing support material. A fourth aspect pertains to a palladium/gold catalyst or pre-catalyst that is produced from substantially chloride free catalytic components.
摘要翻译： 本发明涉及与催化剂结构有关的至少四个不同方面，制备这些催化剂的方法和使用这些催化剂制备烯基链烷酸酯的方法。 本发明的单独或一起组合地涉及改进烯基链烷酸酯和VA的生产，特别是包括副产物的还原和提高的生产效率。 本发明的第一方面涉及包含铑或其它金属的独特的钯/金催化剂或预催化剂（任选煅烧的）。 第二方面涉及基于层状载体材料的钯/金催化剂或预催化剂，其中一层载体材料基本上不含催化组分。 第三方面涉及在含氧化锆载体材料上的钯/金催化剂或预催化剂。 第四方面涉及由基本上不含氯的催化组分制备的钯/金催化剂或预催化剂。
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公开(公告)号：US07598198B2
公开(公告)日：2009-10-06
申请号：US12183247
申请日：2008-07-31
申请人： Tao Wang , Leslie Wade , Ioan Nicolau , Yumin Liu , Victor Wong , Barbara Kimmich , Jun Han , Valery Sokolovskii , Alfred Hagemeyer , David M. Lowe , Karin Yaccato , Anthony Volpe
发明人： Tao Wang , Leslie Wade , Ioan Nicolau , Yumin Liu , Victor Wong , Barbara Kimmich , Jun Han , Valery Sokolovskii , Alfred Hagemeyer , David M. Lowe , Karin Yaccato , Anthony Volpe
CPC分类号： B01J23/58 , B01J23/464 , B01J23/52 , B01J33/00 , B01J35/002 , B01J35/0026 , B01J35/008 , B01J35/0086 , B01J35/026 , B01J35/1014 , B01J35/1019 , B01J35/1042 , B01J37/0201 , B01J37/0244 , B01J37/16 , C07C67/055 , C07C69/15
摘要： The present invention addresses at least four different aspects relating to catalyst structure, methods of making those catalysts and methods of using those catalysts for making alkenyl alkanoates. Separately or together in combination, the various aspects of the invention are directed at improving the production of alkenyl alkanoates and VA in particular, including reduction of by-products and improved production efficiency. A first aspect of the present invention pertains to a unique palladium/gold catalyst or pre-catalyst (optionally calcined) that includes rhodium or another metal. A second aspect pertains to a palladium/gold catalyst or pre-catalyst that is based on a layered support material where one layer of the support material is substantially free of catalytic components. A third aspect pertains to a palladium/gold catalyst or pre-catalyst on a zirconia containing support material. A fourth aspect pertains to a palladium/gold catalyst or pre-catalyst that is produced from substantially chloride free catalytic components.
摘要翻译： 本发明涉及与催化剂结构有关的至少四个不同方面，制备这些催化剂的方法和使用这些催化剂制备烯基链烷酸酯的方法。 本发明的单独或一起组合地涉及改进烯基链烷酸酯和VA的生产，特别是包括副产物的还原和提高的生产效率。 本发明的第一方面涉及包含铑或其它金属的独特的钯/金催化剂或预催化剂（任选煅烧的）。 第二方面涉及基于层状载体材料的钯/金催化剂或预催化剂，其中一层载体材料基本上不含催化组分。 第三方面涉及在含氧化锆载体材料上的钯/金催化剂或预催化剂。 第四方面涉及由基本上不含氯的催化组分制备的钯/金催化剂或预催化剂。
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