-
公开(公告)号：US20100018926A1
公开(公告)日：2010-01-28
申请号：US12145559
申请日：2008-06-25
CPC分类号： B01D71/028 , B01D67/0079 , B01D69/148 , B01D2323/21 , B01D2323/36 , B01D2325/16
摘要： The present invention discloses mixed matrix membranes (MMMs) comprising ion-exchanged molecular sieves such as UZM-5 zeolite ion-exchanged with Li+ cation (Li-UZM-5) and a continuous polymer matrix and methods for making and using these membranes. These MMMs, comprising ion-exchanged molecular sieves, in the form of symmetric dense films, asymmetric flat sheets, asymmetric hollow fibers, or thin-film composites, have exhibited simultaneously increased selectivity and permeability (or permeance) over polymer-only membranes and the mixed matrix membranes made from molecular sieves that have not been ion exchanged for gas separations. These MMMs are suitable for a variety of liquid, gas, and vapor separations such as desalination of water by reverse osmosis, deep desulfurization of gasoline and diesel fuels, ethanol/water separations, pervaporation dehydration of aqueous/organic mixtures, CO2/CH4, CO2/N2, H2/CH4, O2/N2, olefin/paraffin, iso/normal paraffins separations, and other light gas mixture separations.
摘要翻译： 本发明公开了包含离子交换分子筛（例如与Li +阳离子（Li-UZM-5）离子交换的UZM-5沸石）和连续聚合物基质的混合基质膜（MMM）以及制造和使用这些膜的方法。 这些包含离子交换分子筛，以对称致密膜，不对称平板，不对称中空纤维或薄膜复合材料形式的MMM已经显示出与聚合物膜相比增加的选择性和渗透性（或渗透性），并且 由分子筛制成的未经离子交换进行气体分离的混合基质膜。 这些MMM适用于各种液体，气体和蒸汽分离，如通过反渗透脱水，汽油和柴油燃料的深度脱硫，乙醇/水分离，水/有机混合物的渗透蒸发脱水，CO 2 / CH 4，CO 2 / N2，H2 / CH4，O2 / N2，烯烃/石蜡，异/正链烷烃分离和其他轻质气体混合物分离。
-
2.发明授权Microporous UZM-5 inorganic zeolite membranes for gas, vapor, and liquid separations 失效用于气体，蒸汽和液体分离的微孔UZM-5无机沸石膜公开(公告)号：US08540800B2
公开(公告)日：2013-09-24
申请号：US13052720
申请日：2011-03-21
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0048 , B01D67/0051 , B01D67/0088 , B01D69/10 , B01D2323/14 , B01J20/186 , B01J20/28007 , B01J20/28035 , B01J20/3057 , B01J20/3078 , B01J20/3085 , B01J20/3238 , B01J20/3272 , B82Y30/00
摘要： The present invention discloses microporous UZM-5 zeolite membranes, methods for making the same, and methods of separating gases, vapors, and liquids using the same. The small-pore microporous UZM-5 zeolite membrane is prepared by two different methods, including in-situ crystallization of one or more layers of UZM-5 zeolite crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of UZM-5 zeolite crystals on a seed layer of UZM-5 zeolite crystals supported on a porous membrane support. The membranes in the form of disks, tubes, or hollow fibers have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas, vapor, and liquid separations.
摘要翻译： 本发明公开了微孔UZM-5沸石膜，其制造方法，以及使用其分离气体，蒸汽和液体的方法。 小孔微孔UZM-5沸石膜通过两种不同的方法制备，包括在多孔膜载体上的一层或多层UZM-5沸石晶体的原位结晶，以及通过原位结晶的接种方法 在支撑在多孔膜载体上的UZM-5沸石晶种的种子层上连续的第二层UZM-5沸石晶体。 圆盘，管或中空纤维形式的膜具有优异的热稳定性和化学稳定性，良好的抗侵蚀性，高的二氧化碳抗塑化性，并且对于气体，蒸汽和液体分离，在聚合物膜上显着提高了选择性。
-
3.发明申请MICROPOROUS UZM-5 INORGANIC ZEOLITE MEMBRANES FOR GAS, VAPOR, AND LIQUID SEPARATIONS 失效用于气体，蒸气和液体分离的微波UZM-5无机沸石膜公开(公告)号：US20120240763A1
公开(公告)日：2012-09-27
申请号：US13052720
申请日：2011-03-21
CPC分类号： B01D71/028 , B01D53/228 , B01D67/0048 , B01D67/0051 , B01D67/0088 , B01D69/10 , B01D2323/14 , B01J20/186 , B01J20/28007 , B01J20/28035 , B01J20/3057 , B01J20/3078 , B01J20/3085 , B01J20/3238 , B01J20/3272 , B82Y30/00
摘要： The present invention discloses microporous UZM-5 zeolite membranes, methods for making the same, and methods of separating gases, vapors, and liquids using the same. The small-pore microporous UZM-5 zeolite membrane is prepared by two different methods, including in-situ crystallization of one or more layers of UZM-5 zeolite crystals on a porous membrane support, and a seeding method by in-situ crystallization of a continuous second layer of UZM-5 zeolite crystals on a seed layer of UZM-5 zeolite crystals supported on a porous membrane support. The membranes in the form of disks, tubes, or hollow fibers have superior thermal and chemical stability, good erosion resistance, high CO2 plasticization resistance, and significantly improved selectivity over polymer membranes for gas, vapor, and liquid separations.
摘要翻译： 本发明公开了微孔UZM-5沸石膜，其制造方法，以及使用其分离气体，蒸汽和液体的方法。 小孔微孔UZM-5沸石膜通过两种不同的方法制备，包括在多孔膜载体上的一层或多层UZM-5沸石晶体的原位结晶，以及通过原位结晶的接种方法 在支撑在多孔膜载体上的UZM-5沸石晶种的种子层上连续的第二层UZM-5沸石晶体。 圆盘，管或中空纤维形式的膜具有优异的热稳定性和化学稳定性，良好的抗侵蚀性，高的二氧化碳抗塑化性，并且对于气体，蒸汽和液体分离，在聚合物膜上显着提高了选择性。
-
公开(公告)号：US20110316181A1
公开(公告)日：2011-12-29
申请号：US12823154
申请日：2010-06-25
申请人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Jaime G. Moscoso
发明人： Chunqing Liu , Raisa Minkov , Syed A. Faheem , Jaime G. Moscoso
CPC分类号： B01D71/62 , B01D53/228 , B01D67/0079 , B01D67/0083 , B01D67/0088 , B01D69/08 , B01D71/028 , B01D71/64 , D01D5/04 , D01D5/24 , D01F6/74
摘要： The present invention provides a process for making an integrally skinned asymmetric polybenzoxazole hollow fiber membrane comprising spinning a dope solution via a dry-wet phase inversion technique to form a porous integrally skinned asymmetric o-hydroxy substituted polyimide or an o-hydroxy substituted polyamide hollow fiber membrane comprising microporous inorganic molecular sieve followed by thermal rearrangement at a temperature from about 250° to 500° C. to convert the polyimide or polyamide membrane into a polybenzoxazole membrane. These membranes contain microporous inorganic molecular sieve materials that can have a particle size from about 20 nm to 10 μm.
摘要翻译： 本发明提供一种制备整体表皮的不对称聚苯并恶唑中空纤维膜的方法，包括通过干 - 湿相转化技术纺丝掺杂溶液以形成多孔整体表皮的不对称羟基取代的聚酰亚胺或邻羟基取代的聚酰胺中空纤维 膜，其包含微孔无机分子筛，随后在约250℃至500℃的温度下热重排，以将聚酰亚胺或聚酰胺膜转化为聚苯并恶唑膜。 这些膜含有可以具有约20nm至10μm的粒度的微孔无机分子筛材料。
-
公开(公告)号：US06756030B1
公开(公告)日：2004-06-29
申请号：US10395466
申请日：2003-03-21
申请人： Lisa M. Rohde , Gregory J. Lewis , Mark A. Miller , Jaime G. Moscoso , Jana L. Gisselquist , R. Lyle Patton , Stephen T. Wilson , Deng Yang Jan
发明人： Lisa M. Rohde , Gregory J. Lewis , Mark A. Miller , Jaime G. Moscoso , Jana L. Gisselquist , R. Lyle Patton , Stephen T. Wilson , Deng Yang Jan
IPC分类号： C01B3948
CPC分类号： C10G45/62 , B01J29/70 , B01J29/74 , C01B39/06 , C01B39/065 , C01B39/48 , C10G45/10 , C10G45/12 , C10G45/64 , C10G47/14 , C10G47/20 , C10G49/06 , C10G49/08
摘要： Applicants have synthesized a family of microporous aluminosilicate zeolites and substituted versions thereof which are identified as UZM-8. These new compositions can be prepared using either only one or more organoammonium cations, such as diethyldimethylammonium or ethyltrimethylammonium cations and optionally an alkali and/or an alkaline earth cation as structure directing agents. The UZM-8 compositions are described by an empirical formula of Mmn+Rrp+Al1-xExSiyOz and have a unique x-ray diffraction pattern.
摘要翻译： 申请人已经合成了一系列微孔硅铝酸盐沸石及其取代形式，其被鉴定为UZM-8。 这些新的组合物可以使用仅一种或多种有机铵阳离子，如二乙基二甲基铵或乙基三甲基铵阳离子和任选的碱和/或碱土金属阳离子作为结构定向剂来制备。 UZM-8组合物由经验公式描述并具有独特的x射线衍射图。
-
公开(公告)号：US06890511B2
公开(公告)日：2005-05-10
申请号：US10395399
申请日：2003-03-21
申请人： Lisa M. Rohde , Gregory J. Lewis , Stephen T. Wilson , Deng-Yang Jan , R. Lyle Patton , Susan C. Koster , Jaime G. Moscoso , Mark A. Miller , Michael G. Gatter
发明人： Lisa M. Rohde , Gregory J. Lewis , Stephen T. Wilson , Deng-Yang Jan , R. Lyle Patton , Susan C. Koster , Jaime G. Moscoso , Mark A. Miller , Michael G. Gatter
CPC分类号： B01J29/87 , B01J29/70 , B01J2229/16 , B01J2229/32 , B01J2229/36 , B01J2229/37 , C01B39/026 , C01B39/082 , C01B39/48 , C01P2002/72 , C07C7/13
摘要： An aluminosilicate zeolite and substituted versions designated UZM-15 have been synthesized. These zeolites are prepared using an organoammonium cation as a template in which at least one organic group has at least 2 carbon atoms. An example of such a cation is diethyldimethylammonium cation. The template can optionally comprise other organoammonium cations, alkali metals and alkaline earth metals. These UZM-15 materials can be dealuminated by various processes to provide UZM-15HS compositions. Both the UZM-15 and UZM-15HS compositions are useful as catalysts or catalyst supports in various process such as the conversion of cyclic hydrocarbons to non-cyclic hydrocarbons and olefin oligomerization.
摘要翻译： 已经合成了一种硅铝酸盐沸石，并且被认为是UZM-15的取代物。 使用有机铵阳离子作为模板制备这些沸石，其中至少一个有机基团具有至少2个碳原子。 这种阳离子的实例是二乙基二甲基铵阳离子。 模板可任选地包含其它有机铵阳离子，碱金属和碱土金属。 这些UZM-15材料可以通过各种工艺脱铝以提供UZM-15HS组合物。 UZM-15和UZM-15HS组合物可用作各种方法中的催化剂或催化剂载体，例如将环烃转化为非环烃和烯烃低聚。
-
公开(公告)号：US07713513B2
公开(公告)日：2010-05-11
申请号：US11340914
申请日：2006-01-27
申请人： Deng-Yang Jan , Jaime G. Moscoso , Susan C. Koster , Lisa M. Knight , Gregory J. Lewis , Mark A. Miller , R. Lyle Patton , Stephen T. Wilson
发明人： Deng-Yang Jan , Jaime G. Moscoso , Susan C. Koster , Lisa M. Knight , Gregory J. Lewis , Mark A. Miller , R. Lyle Patton , Stephen T. Wilson
CPC分类号： C01B39/026 , C01B39/48 , C01P2002/72 , C10G11/05 , C10G35/095 , C10G45/12 , C10G47/16
摘要： A family of crystalline aluminosilicate zeolites designated UZM-8HS and derived from UZM-8 have been synthesized. The aluminum content of the UZM-8HS is lower than that of the starting UZM-8 thus changing its ion exchange capacity and acidity. These UZM-8HS are represented by the empirical formula: M1an+Al(1−x)ExSiy′Oz″ and are prepared by treatments such as acid extraction and AFS treatments.
摘要翻译： 已经合成了一系列称为UZM-8HS并衍生自UZM-8的结晶硅铝酸盐沸石。 UZM-8HS的铝含量低于起始UZM-8的铝含量，从而改变其离子交换能力和酸度。 这些UZM-8HS由经验公式：M1an + Al（1-x）ExSiy'Oz表示，并且通过诸如酸提取和AFS处理的处理来制备。
-
8.发明授权Processes for making nano zeolites and for recovery of nano zeolites from an aqueous suspension 有权用于制备纳米沸石和从水悬浮液中回收纳米沸石的方法公开(公告)号：US09133037B2
公开(公告)日：2015-09-15
申请号：US12909643
申请日：2010-10-21
申请人： Jaime G. Moscoso
发明人： Jaime G. Moscoso
CPC分类号： C01B39/082 , B01J29/70 , B01J29/84
摘要： Embodiments of a process for recovery of nano zeolites from an aqueous suspension are provided. The process comprises the steps of applying centrifugal force to the aqueous suspension to separate a supernatant phase from a solid phase that comprises the nano zeolites and residuals. The solid phase is contacted with a solution effective to dissolve or digest the residuals and to agglomerate the nano zeolites forming agglomerated nano zeolites. The solution is filtered to recover the agglomerated nano zeolites.
摘要翻译： 提供了从水性悬浮液中回收纳米沸石的方法的实施方案。 该方法包括以下步骤：将离心力施加到水悬浮液中，以将上清液相从包含纳米沸石和残余物的固相中分离出来。 使固相与有效溶解或消化残余物的溶液接触，并使形成凝聚的纳米沸石的纳米沸石凝聚。 将溶液过滤以回收附聚的纳米沸石。
-
公开(公告)号：US08158103B2
公开(公告)日：2012-04-17
申请号：US12750923
申请日：2010-03-31
申请人： Jaime G. Moscoso , Deng-Yang Jan
发明人： Jaime G. Moscoso , Deng-Yang Jan
CPC分类号： C01B39/48
摘要： A new family of crystalline aluminosilicate zeolites has been synthesized. These zeolites are represented by the empirical formula. Mmn+Rr+Al(1−x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the propyltrimethylammonium cation and E is a framework element such as gallium. These zeolites are similar to MWW but are characterized by unique x-ray diffraction patterns and compositions and have catalytic properties for carrying out various hydrocarbon conversion processes.
摘要翻译： 已经合成了一系列结晶硅铝酸盐沸石。 这些沸石由经验公式表示。 Mmn + Rr + Al（1-x）ExSiyOz其中M表示钾和钠可交换阳离子的组合，R是单电荷的有机铵阳离子，例如丙基三甲基铵阳离子，E是骨架元素如镓。 这些沸石类似于MWW，但是其特征在于独特的x射线衍射图和组成，并且具有用于进行各种烃转化方法的催化性能。
-
公开(公告)号：US20110313223A1
公开(公告)日：2011-12-22
申请号：US12820088
申请日：2010-06-21
IPC分类号： C07C5/22
CPC分类号： C07C5/2737 , C07C5/2791 , C07C2523/06 , C07C2523/08 , C07C2523/12 , C07C2523/14 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2527/13 , C07C2529/80 , C07C15/08
摘要： Xylene and ethylbenzene isomerization process is catalyzed by the UZM-35 family of crystalline aluminosilicate zeolitic compositions represented by the empirical formula: Mmn+Rr+Al(1-x)ExSiyOz where M represents a combination of potassium and sodium exchangeable cations, R is a singly charged organoammonium cation such as the dimethyldipropylammonium cation and E is a framework element such as gallium. These UZM-35 zeolitic compositions are active and selective in the isomerization of xylenes and ethylbenzene.
摘要翻译： 二甲苯和乙苯异构化过程由经验式由Mmn + Rr + Al（1-x）ExSiyOz表示的结晶硅铝酸盐沸石组合的UZM-35族催化，其中M表示钾和钠可交换阳离子的组合，R是 单电荷的有机铵阳离子如二甲基二丙基铵阳离子，E是骨架元素如镓。 这些UZM-35沸石组合物在二甲苯和乙苯的异构化中是活性的和选择性的。
-
-
-
-
-
-
-
-
-
搜索结果
85 条记录 (耗时 0.023 秒)
