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    DIMERIC BENZYLIDENE MALONATES
    7.
    发明申请
    DIMERIC BENZYLIDENE MALONATES 审中-公开
    二甲苯胆碱

    公开(公告)号：US20110038815A1

    公开(公告)日：2011-02-17

    申请号：US12867777

    申请日：2009-03-04

    申请人： Markus Hansch ,  Thomas Ehlis ,  Barbara Wagner

    发明人： Markus Hansch ,  Thomas Ehlis ,  Barbara Wagner

    IPC分类号： A61K8/37 ,  C07C67/31 ,  A61Q17/04

    CPC分类号： A61Q17/04 ,  A61K8/37 ,  A61K8/585 ,  C07C67/03 ,  C07C67/31 ,  C07C67/343 ,  C07C69/734 ,  C07C2601/14 ,  C07F7/0889 ,  C07C69/732

    摘要： Disclosed is the use of benzylidene malonates of formula (1), wherein R1 and R2, independently from each other are hydrogen; OH; C1-C12alkyl; C1-C12alkoxy; C1-C12alkylamino; C1-C12dialkylamino; water-solubilizing groups, selected from carboxylate, sulfonates or ammonium radicals; R3 is COOR5; COR5; CONR5R6; CN; or SO2R7, R4 is COOR8; COR9; CONR8R9; CN; or SO2R10; R5, R6, R7, R8, R9 and R10 independently from each other are C1-C18alkyl; unsubstituted or by one or more than one C1-C4alkyl substituted C3-C12-cycloalkyl; unsubstituted or C1-C6alkyl-substituted C6-C20aryl; organosilanyl, or organosiloxanyl; A is —C1-C20alkylene-, —CH2CH(OH)CH2—, —C5-C20cycloalkylene, —C2-C20alkenylene-, —C5-C10arylene-, or —C5-C10arylene-(C1-C10alkylene)- which are unsubstituted or substituted, straight-chain or branched, optionally interrupted by one or more than one heteroatoms selected from —O, —S— or —NH—; for the protection of human and animal hair and skin against UV radiation.

    摘要翻译： 公开了式（1）的亚苄基丙二酸酯的用途，其中R 1和R 2彼此独立地为氢; 哦; C 1 -C 12烷基; C1-C12烷氧基; C 1 -C 12烷基氨基; C1-C12二烷基氨基; 选自羧酸盐，磺酸盐或铵基的水溶性基团; R3为COOR5; COR5; CONR5R6; CN; 或SO 2 R 7，R 4为COOR 8; COR9; CONR8R9; CN; 或SO2R10; R 5，R 6，R 7，R 8，R 9和R 10彼此独立地为C 1 -C 18烷基; 未取代或被一个或多个C 1 -C 4烷基取代的C 3 -C 12 - 环烷基取代; 未取代的或C 1 -C 6烷基取代的C 6 -C 20芳基; 有机硅烷基或有机硅氧烷基; A是未取代或取代的-C 1 -C 20亚烷基 - ， - CH 2 CH（OH）CH 2 - ， - C 5 -C 20亚环烷基，-C 2 -C 20亚烯基，-C 5 -C 10亚芳基或-C 5 -C 10亚芳基 - （C 1 -C 10亚烷基） 直链或支链，任选被一个或多于一个选自-O，-S-或-NH-的杂原子中断; 用于保护人和动物的头发和皮肤免受紫外线辐射。

    UV filter combinations comprising benzylidene malonates
    8.
    发明授权
    UV filter combinations comprising benzylidene malonates 有权

    公开(公告)号：US09764169B2

    公开(公告)日：2017-09-19

    申请号：US13381965

    申请日：2010-06-29

    申请人： Julie Grumelard ,  Thomas Ehlis ,  Markus Hansch ,  Myriam Sohn

    发明人： Julie Grumelard ,  Thomas Ehlis ,  Markus Hansch ,  Myriam Sohn

    IPC分类号： A61Q17/04 ,  A61K8/37

    CPC分类号： A61Q17/04 ,  A61K8/37

    摘要： Disclosed is the use of a UV filter combination, comprising (a) a first UV filter selected from benzylidene malonates of formula (1), wherein R1 methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (II); formula (III); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; and (b) a second UV filter selected from (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b2) Butyl Methoxydibenzoylmethane; (b3)Diethylhexyl Butamido Triazone; (b4) Ethylhexyl Triazone; (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b6) Ethylhexyl Methoxycinnamate; (b7) Ethylhexyl Salicylate; (b8) Homosalate; (b9) Octocrylene; (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b11) Phenylbenzimidazole Sulfonic Acid; (b12) Titanium Dioxide; (b13) micronized Tris-Biphenyl Triazine; and (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone;(b15) benzoicacid,4,4-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b14); for the protection of human and animal hair and skin against UV radiation.

    BENZYLIDENE MALONATES
    10.
    发明申请
    BENZYLIDENE MALONATES 审中-公开
    苯并噻唑啉酮

    公开(公告)号：US20120128745A1

    公开(公告)日：2012-05-24

    申请号：US13322628

    申请日：2010-05-19

    申请人： Markus Hansch ,  Thomas Ehlis ,  Olof Wallquist ,  Barbara Wagner ,  Bernd Herzog ,  Jochen Giesinger

    发明人： Markus Hansch ,  Thomas Ehlis ,  Olof Wallquist ,  Barbara Wagner ,  Bernd Herzog ,  Jochen Giesinger

    IPC分类号： A61K8/02 ,  C07C69/734 ,  A61K8/41 ,  A61K8/49 ,  A61K8/37 ,  A61Q17/04

    CPC分类号： A61K8/37 ,  A61Q17/04 ,  C07C69/73

    摘要： Disclosed is the use of benzylidene malonates of formula (1) wherein R1 is methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; a radical of formula (1a) or a radical of formula (1b) wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; for the protection of human and animal hair and skin against UV radiation.

    摘要翻译： 公开了使用式（1）的亚苄基丙二酸酯，其中R 1是甲基; 乙基; 丙基; 或正丁基; 如果R1是甲基，那么R是叔丁基。 丁基; 式（1a）的基团或式（1b）的基团，其中R2和R3彼此独立地为氢; 或甲基; R4是甲基; 乙基; 或正丙基​​; R5和R6彼此独立地是氢; 或C 1 -C 3烷基; 如果R1是乙基; 丙基; 或正丁基，那么R是异丙基; 用于保护人和动物的头发和皮肤免受紫外线辐射。