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公开(公告)号：US4052418A
公开(公告)日：1977-10-04
申请号：US602343
申请日：1975-08-06
IPC分类号： C07D307/60 , B01J23/00 , C07B61/00 , C07C51/215 , C07C51/25 , B01J21/02 , B01J23/16 , B01J23/84
CPC分类号： C07C51/25 , C07C51/215 , C07C51/252
摘要： Catalysts comprising the combined oxides of vanadium and at least one element selected from the group consisting of boron, niobium, tantalum, antimony, tungsten and chromium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene, or a mixture thereof with molecular oxygen in the vapor phase to yield maleic anhydride. The catalysts of the present invention may be further promoted with additional elements to enhance activity, stability and selectivity. The reaction with n-butane gives an especially pure product in good yield and selectivity.
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公开(公告)号：US4293443A
公开(公告)日：1981-10-06
申请号：US108764
申请日：1979-12-31
IPC分类号： B01J23/22 , B01J23/26 , B01J23/34 , B01J23/84 , C07C51/215 , C07C51/25 , B01J21/02 , B01J21/00 , B01J23/10 , B01J23/16
CPC分类号： C07C51/25 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/84 , C07C51/215 , C07C51/252
摘要： Catalysts comprising the combined oxides of vanadium and at least one element selected from the group consisting of boron, niobium, tantalum, antimony, tungsten and chromium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene, or a mixture thereof with molecular oxygen in the vapor phase to yield maleic anhydride. The catalysts of the present invention may be further promoted with additional elements to enhance activity, stability and selectivity. The reaction with n-butane gives an especially pure product in good yield and selectivity.
摘要翻译： 已经发现包含钒的组合氧化物和选自硼，铌，钽，锑，钨和铬中的至少一种元素的催化剂在正丁烷，正丁烯和丁二烯的氧化中是特别有效的， 或其与气相中的分子氧的混合物，得到马来酸酐。 本发明的催化剂可以通过附加元素进一步促进，以增强活性，稳定性和选择性。 与正丁烷的反应以良好的产率和选择性得到特别纯的产物。
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公开(公告)号：US4234461A
公开(公告)日：1980-11-18
申请号：US891786
申请日：1978-03-30
IPC分类号： B01J23/22 , B01J23/26 , B01J23/34 , B01J23/84 , C07C51/215 , C07C51/25 , C07C51/265 , B01J23/10 , B01J21/00 , B01J21/02 , B01J23/16
CPC分类号： C07C51/252 , B01J23/22 , B01J23/26 , B01J23/34 , B01J23/84 , C07C51/215 , C07C51/25 , C07C51/265
摘要： Catalysts comprising the combined oxides of vanadium and at least one element selected from the group consisting of boron, niobium, tantalum, antimony, tungsten and chromium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene, or a mixture thereof with molecular oxygen in the vapor phase to yield maleic anhydride. The catalysts of the present invention may be further promoted with additional elements to enhance activity, stability and selectivity. The reaction with n-butane gives an especially pure product in good yield and selectivity.
摘要翻译： 已经发现包含钒的组合氧化物和选自硼，铌，钽，锑，钨和铬中的至少一种元素的催化剂在正丁烷，正丁烯和丁二烯的氧化中是特别有效的， 或其与气相中的分子氧的混合物，得到马来酸酐。 本发明的催化剂可以通过附加元素进一步促进，以增强活性，稳定性和选择性。 与正丁烷的反应以良好的产率和选择性得到特别纯的产物。
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公开(公告)号：US4855275A
公开(公告)日：1989-08-08
申请号：US157428
申请日：1988-02-18
IPC分类号： B01J21/02 , B01J23/18 , B01J27/188 , C07C253/26
CPC分类号： B01J23/18 , B01J21/02 , B01J27/188 , C07C253/26 , Y02P20/52
摘要： A process for improving the performance of an ammoxidation catalyst comprising contacting said catalyst with a boron containing or heat decomposable boron compound to deposit boron on the catalyst.
摘要翻译： 一种用于改善氨氧化催化剂性能的方法，包括使所述催化剂与含硼或可热分解的硼化合物接触以在催化剂上沉积硼。
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5.发明授权Production of unsaturated nitriles using catalysts containing boron, gallium or indium 失效使用含有硼，镓或铟的催化剂生产不饱和腈
公开(公告)号：US4766232A
公开(公告)日：1988-08-23
申请号：US624498
申请日：1984-06-25
IPC分类号： B01J23/88 , B01J23/881 , B01J23/89 , C07C120/14
CPC分类号： B01J23/8874 , B01J23/881 , B01J23/8876 , B01J23/8993 , C07C253/26 , Y02P20/52
摘要： Certain catalysts containing iron and molybdenum plus bismuth or tellurium and nickel, cobalt, manganese, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when boron, gallium or indium are incorporated into the catalyst.
摘要翻译： 已经发现含有铁和钼加铋或碲和镍，钴，锰，镁，锌，镉，钙或铍的某些催化剂在给定的时间内给出特别大量的丙烯腈或甲基丙烯腈，当硼，镓或铟被掺入时 进入催化剂。
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6.发明授权
公开(公告)号：US4746753A
公开(公告)日：1988-05-24
申请号：US880657
申请日：1986-07-01
IPC分类号： B01J23/31 , B01J23/68 , B01J23/885 , C07C5/48 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , C07C120/14
CPC分类号： C07C253/26 , B01J23/002 , B01J23/31 , B01J23/686 , B01J23/885 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , C07C5/48 , B01J2523/00 , C07C2521/06 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/18 , C07C2523/26 , C07C2523/28 , C07C2523/31 , C07C2523/50 , C07C2523/72 , C07C2527/057 , Y02P20/52
摘要： Bismuth cerium molybdate catalysts promoted with alkali metal and other optional ingredients provide high yields of acrylonitrile in the ammoxidation of propylene.
摘要翻译： 用碱金属和其他任选成分促进的钼酸铋钼催化剂在丙烯的氨氧化中提供高产率的丙烯腈。
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公开(公告)号：US4377534A
公开(公告)日：1983-03-22
申请号：US293822
申请日：1981-08-17
IPC分类号： B01J23/88 , B01J23/887 , B01J23/89 , C07C120/14
CPC分类号： B01J23/8873 , B01J23/8871 , B01J23/8872 , B01J23/8876 , B01J23/8993 , C07C253/26 , Y02P20/52
摘要： Catalysts containing iron, molybdenum, bismuth and nickel, cobalt, magnesium, zinc, cadmium, calcium or beryllium have been found to give especially large volumes of acrylonitrile or methacrylonitrile in a given time when manganese, antimony, thorium, zirconium, yttrium or mixtures thereof are incorporated into the catalyst.
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公开(公告)号：US4309361A
公开(公告)日：1982-01-05
申请号：US108324
申请日：1979-12-28
IPC分类号： B01J23/84 , B01J27/057 , B01J27/186 , C07C45/34 , C07C120/14
CPC分类号： C07C253/26 , B01J23/84 , B01J27/0576 , B01J27/186 , C07C45/34 , B01J2523/00 , Y02P20/52
摘要： Oxide complex catalysts comprising Fe-Sb-Bi-O.sub.x promoted with a wide variety of different elements have been found to be especially useful in the ammoxidation of olefins to nitriles such as acrylonitrile and methacrylonitrile. Not only are the desired nitriles obtained with high yields when these catalysts are used, but also the production of unwanted liquid byproducts such as acrolein, acrylic acid and acetonitrile is significantly reduced.
摘要翻译： 已经发现含有各种不同元素促进的包含Fe-Sb-Bi-Ox的氧化物复合催化剂特别可用于将烯烃氧化成腈类，如丙烯腈和甲基丙烯腈。 当使用这些催化剂时，不仅以高产率获得所需的腈，而且显着降低了不需要的液体副产物如丙烯醛，丙烯酸和乙腈的产生。
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公开(公告)号：US4065468A
公开(公告)日：1977-12-27
申请号：US685879
申请日：1976-05-12
IPC分类号： B01J23/24 , B01J23/88 , B01J27/057 , B01J27/186 , C07C51/215 , C07D307/60
CPC分类号： B01J23/8876 , B01J23/24 , B01J23/8877 , B01J23/8878 , B01J27/0576 , B01J27/186 , C07C51/215 , B01J2523/00
摘要： Maleic anhydride is produced by the reaction of n-butane with a molecular oxygen-containing gas at an elevated temperature in the presence of a catalyst composed of the combined oxides of the elements antimony, molybdenum and at least one member selected from the group consisting of iron and vanadium and optionally one or more oxides of aluminum, boron, tellurium, chromium, cobalt, nickel, copper, bismuth, phosphorus titanium and tungsten.
摘要翻译： 马来酸酐通过正丁烷与含分子氧的气体在升高的温度下在催化剂存在下反应生成，所述催化剂由元素锑，钼和至少一种选自以下的组分的组成的催化剂组成： 铁和钒以及任选的一种或多种铝，硼，碲，铬，钴，镍，铜，铋，磷钛和钨的氧化物。
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10.再颁专利
公开(公告)号：USRE31088E
公开(公告)日：1982-11-23
申请号：US904941
申请日：1978-05-11
IPC分类号： B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/88 , B01J23/887 , B01J27/00 , B01J27/057 , C07C45/35 , C07C51/25 , C07D307/79 , C07D307/80 , C07D307/82 , C07D307/83 , C07D307/92 , C07D333/60 , C07D333/68 , D06L3/12
CPC分类号： B01J23/8875 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/8876 , B01J23/8878 , B01J27/00 , B01J27/0576 , C07C253/26 , C07C45/34 , C07C45/35 , C07C51/252 , C07D307/79 , C07D307/80 , C07D307/82 , C07D307/83 , C07D307/92 , C07D333/60 , C07D333/68 , D06L3/1228 , B01J2523/00 , Y02P20/52
摘要： A process for the catalytic oxidation of olefins to unsaturated aldehydes and acids and the ammoxidation of olefins to unsaturated nitriles in which the catalyst comprises a promoted, reduced, antimony oxidemolybdenum oxide-containing catalyst.
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