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1.发明授权Low viscosity mixtures of amphiphilic nonionic graft copolymers and viscosity-reducing additives 失效两亲性非离子接枝共聚物和粘度降低添加剂的低粘度混合物
公开(公告)号：US5635554A
公开(公告)日：1997-06-03
申请号：US501340
申请日：1995-07-12
申请人： Dieter Boeckh , Hans-Peter Seelmann-Eggebert , Hans-Ulrich Jager , Rolf-Dieter Kahl , Gunnar Schornick
发明人： Dieter Boeckh , Hans-Peter Seelmann-Eggebert , Hans-Ulrich Jager , Rolf-Dieter Kahl , Gunnar Schornick
IPC分类号： C08L51/00 , C08L51/08 , C09K3/00 , C11D1/44 , C11D1/72 , C11D3/20 , C11D3/37 , C11D1/00 , C11D1/66
CPC分类号： C11D3/3788 , C08L51/003 , C08L51/08 , C11D1/44 , C11D1/72 , C11D3/2068
摘要： Low viscosity mixtures of(I) from 40 to 97.5% by weight of amphiphilic nonionic graft copolymers comprising, in copolymerized form,(a) at least 20% by weight of polyalkylene oxide units or polyvinylpyrrolidone units as hydrophilic part of the molecule and(b) at least 40% by weight of vinyl ester and/or (meth)acrylic ester units as hydrophobic part of the molecule, and(II) from 2.5 to 60% by weight of at least one viscosity-reducing additive selected from the group consisting of polyalkylene glycols, alkoxylated alcohols, alkoxylated alkylphenols, alkoxylated amines and hydroxy compounds having from 1 to 4 OH groups and from 2 to 10 carbon atoms, the molecular mass M.sub.N of the polymers in each case being not more than 2500, and(III) from 0 to 40% by weight of homogenizing or phase-stabilizing additives, for example water, monobasic and dibasic carboxylic acids having from 8 to 25 carbon atoms, fatty alcohol sulfates and fatty alcohol sulfonates or mixtures thereof,are useful as detergent and cleaner additives.
摘要翻译： （I）40至97.5重量％的两亲性非离子接枝共聚物的低粘度混合物，其以共聚形式包含（a）至少20重量％的作为分子的亲水部分的聚环氧烷单元或聚乙烯吡咯烷酮单元和（b ）至少40重量％的作为分子的疏水部分的乙烯基酯和/或（甲基）丙烯酸酯单元，和（II）2.5至60重量％的至少一种降粘添加剂，其选自 聚亚烷基二醇，烷氧基化醇，烷氧基化烷基酚，烷氧基化胺和具有1至4个OH基和2至10个碳原子的羟基化合物，每种情况下聚合物的分子量MN不超过2500，（III） 0至40重量％的均化或相稳定添加剂，例如具有8至25个碳原子的水，一元和二元羧酸，脂肪醇硫酸盐和脂肪醇磺酸盐或其混合物，可用作dete 更清洁的添加剂。
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2.发明授权Process for preparing fine-particle mixtures of amphiphilic polymers and inorganic solids 失效制备两亲聚合物和无机固体的微粒混合物的方法
公开(公告)号：US5834548A
公开(公告)日：1998-11-10
申请号：US836205
申请日：1997-05-16
CPC分类号： C11D11/0082 , C08J3/201 , C08K7/00 , C11D3/046 , C11D3/3715 , C11D3/3788
摘要： Finely divided mixtures of 97-10% by weight of at least one amphiphilic polymer whose softening point is above 35.degree. C., and 3-90% by weight of at least one inorganic solid with a particle size not exceeding 500 .mu.m are prepared by heating the two components to a temperature which is above the softening point of the polymer, mixing the components, dispersing the melt and rapidly cooling to a temperature at which virtually no inhomogeneity occurs and, where appropriate, further comminuting the particles at temperatures below 50.degree. C. to a particle size of from 50 .mu.m to 5 mm, and are used as additive to detergents.
摘要翻译： PCT No.PCT / EP95 / 04373 Sec。 371日期：1997年5月16日 102（e）日期1997年5月16日PCT提交1995年11月7日PCT公布。 公开号WO96 / 16149 日期：1996年5月30日将至少一种软化点高于35℃的至少一种两亲性聚合物和3-90重量％至少一种粒度不超过500的无机固体的97-10重量％ 通过将两种组分加热到高于聚合物软化点的温度，混合组分，分散熔体并迅速冷却至几乎不发生不均匀性的温度，并在适当情况下进一步粉碎颗粒， 在50℃以下，粒度为50〜5mm，用作洗涤剂的添加剂。
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3.发明授权Amphiphilic polyesters, preparation thereof, and use thereof in laundry detergents 失效两亲性聚酯，其制备方法及其在衣物洗涤剂中的用途
公开(公告)号：US5777046A
公开(公告)日：1998-07-07
申请号：US687322
申请日：1996-08-05
IPC分类号： C08G63/66 , C08G63/672 , C11D3/37 , C08F20/00
CPC分类号： C11D3/3715 , C08G63/66 , C08G63/672
摘要： Amphiphilic polyesters containing (a) ester units derived from polyalkylene glycols having a molecular weight of from 500 to 7500 and aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and (b) ester units derived from aromatic dicarboxylic acids and polyhydric alcohols and having molecular weights of from 1500 to 25,000, processes for preparing the amphiphilic polyesters by polycondensation, preparing first (a) aliphatic polyesters of polyalkylene glycols having a molecular weight of from 500 to 7500 with aliphatic dicarboxylic acids and/or monohydroxymonocarboxylic acids and then, within the aliphatic polyester thus obtained, (b) aromatic polyesters from aromatic dicarboxylic acids and polyhydric alcohols, reversing the order of the polycondensation, or condensing oligomeric aromatic polyesters (b) with oligomeric aliphatic polyesters (a), and use of the amphiphilic polyesters as additive in laundry detergents, other laundry detergent additives and laundry aftertreatments.
摘要翻译： PCT No.PCT / EP95 / 00300 Sec。 371日期：1996年8月5日 102（e）日期1996年8月5日PCT提交1995年1月28日PCT公布。 公开号WO95 / 21880 日期1995年8月17日含有（a）衍生自分子量为500〜7500的聚亚烷基二醇的酯单元和脂族二羧酸和/或单羟基单羧酸的酯双酯和（b）衍生自芳族二羧酸和多元醇的酯单元和 具有1500至25,000的分子量，通过缩聚制备两亲性聚酯的方法，首先使用脂族二羧酸和/或单羟基单羧酸制备分子量为500至7500的聚亚烷基二醇的脂肪族聚酯，然后在 由此获得的脂肪族聚酯，（b）来自芳族二羧酸和多元醇的芳族聚酯，反转缩聚的顺序，或将低聚芳族聚酯（b）与低聚脂族聚酯（a）缩合，并使用两亲性聚酯作为添加剂 在洗衣洗涤剂，其他洗衣洗涤剂添加剂和l 杂项后期。
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公开(公告)号：US6001798A
公开(公告)日：1999-12-14
申请号：US29247
申请日：1998-03-04
申请人： Richard Baur , Werner Bertleff , Hans-Ulrich Jager , Angelika Funhoff , Matthias Kroner , Gunnar Schornick
发明人： Richard Baur , Werner Bertleff , Hans-Ulrich Jager , Angelika Funhoff , Matthias Kroner , Gunnar Schornick
CPC分类号： C08G73/1092 , C11D3/3719
摘要： The use of modified polyaspartic acids which are obtainable by polycondensation of aspartic acid in the presence of, in each case based on the aspartic acid employed,(a) 2.5 to 25 mol % of amines with at least 6 carbon atoms(b) at least 2% by weight of phosphoric acid, phosphorous acid, hypophosphorous acid, polyphosphoric acids, phosphorus pentoxide, phosphonic acids or mixtures of said acids,at temperatures of at least 120.degree. C. and subsequent hydrolysis with bases to give modified polyaspartic acids with a phosphorus content of from 0.5 to 10% by weight, as additive to detergents, and detergents which contain the modified polyaspartic acids in amounts of from 0.1 to 20% by weight.
摘要翻译： PCT No.PCT / EP96 / 03797 371日期：1998年3月4日 102（e）1998年3月4日PCT PCT 1996年8月29日PCT公布。 出版物WO97 / 09409 日期1997年3月13日使用通过天冬氨酸缩聚获得的改性聚天冬氨酸，在每种情况下，基于所使用的天冬氨酸，（a）2.5至25mol％具有至少6个碳原子的胺 （b）在至少120℃的温度下至少2重量％的磷酸，亚磷酸，次磷酸，多磷酸，五氧化二磷，膦酸或所述酸的混合物，随后用碱水解，得到改性的 磷含量为0.5〜10重量％的聚天冬氨酸，作为洗涤剂的添加剂，以及含有0.1〜20重量％的改性聚天冬氨酸的洗涤剂。
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5.发明授权Use of polycationic condensation products as an additive for detergents or detergent after treatment agents in order to inhibit running of colors and to reduce color loss 有权使用聚阳离子缩合产物作为洗涤剂或洗涤剂后处理剂的添加剂，以抑制颜色的运行并减少色差
公开(公告)号：US6025322A
公开(公告)日：2000-02-15
申请号：US284479
申请日：1999-04-21
CPC分类号： C11D3/3723 , C11D3/0021 , C11D3/3776
摘要： Polycationic condensates obtainable by condensing(a) piperazine, 1-alkylpiperazines having 1 to 25 carbon atoms in the alkyl group, 1,4-dialkylpiperazines having 1 to 25 carbon atoms in the alkyl group, 1,4-bis(3-aminopropyl)piperazine, 1-(2-aminoethyl)piperazine, 1-(2-hydroxyalkyl)piperazines having 2 to 25 carbon atoms in the alkyl group, imidazole, C.sub.1 -C.sub.25 -alkylimidazoles or mixtures of said compounds with(b) alkylene dihalides, epihalohydrins and/or bisepoxidesin the molar ratio from 1:0.8 to 1:1.1 and, where appropriate, quaternization of the condensates with C.sub.4 -C.sub.25 -alkylating agents or by heating triethanolamine or triisopropanolamine in the presence of acidic catalysts and quaternizing the condensates with C.sub.4 -C.sub.25 -alkylating agents as color-fixing additive to detergents and fabric conditioners, and detergents which comprise(i) 1-50% by weight of at least one nonionic surfactant,(ii) 0-4.0% by weight of an anionic surfactant and(iii) 0.05-2.5% by weight of the polycationic condensateare used as color transfer inhibiting and color release reducing additive, and fabric conditioners which comprise a fabric softener, a nonionic surfactant and 0.1-2.5% by weight of said polycationic condensates.
摘要翻译： PCT No.PCT / EP97 / 05606 Sec。 371 1999年4月21日第 102（e）1999年4月21日PCT PCT 1997年10月10日PCT公布。 公开号WO98 / 17762 日期：1998年04月30日通过缩合（a）在烷基中具有1至25个碳原子的哌嗪，1-烷基哌嗪，在烷基中具有1至25个碳原子的1,4-二烷基哌嗪，1,4-双 （3-氨基丙基）哌嗪，1-（2-氨基乙基）哌嗪，烷基中具有2至25个碳原子的1-（2-羟烷基）哌嗪，咪唑，C 1 -C 25烷基咪唑或所述化合物与（b ）亚烷基二卤化物，表卤代醇和/或双过氧化物，摩尔比为1:0.8至1:1.1，并且在适当时，缩合物与C 4 -C 25烷基化试剂季铵化或通过在酸性催化剂存在下加热三乙醇胺或三异丙醇胺，和 用C4-C25-烷基化剂作为着色固定添加剂对洗涤剂和织物调理剂季铵化缩合物，以及洗涤剂，其包含（i）1-50重量％的至少一种非离子表面活性剂，（ii）0-4.0重量％ 的阴离子表面活性剂和（iii）0.05-2.5重量％的t 使用聚阳离子缩合物作为转色抑制和减色添加剂，以及包含织物柔软剂，非离子表面活性剂和0.1-2.5重量％所述聚阳离子缩合物的织物调理剂。
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6.发明授权Preparation of finely divided mixtures of amphiphilic polymers and polycarboxylates and use thereof 失效制备两亲聚合物和多羧酸盐的细碎混合物及其用途
公开(公告)号：US5652283A
公开(公告)日：1997-07-29
申请号：US598704
申请日：1996-02-08
CPC分类号： C08J3/122 , C08J2367/00
摘要： A process for preparing finely divided mixtures of amphiphilic polymers and polycarboxylates, which comprises mixing(a) aqueous dispersions or colloidal aqueous solutions with at least one amphiphilic polymer, and(b) an aqueous solution of a polycarboxylatein a weight ratio of (a):(b) of from 1:1 to 1:20, each based on the solids, or dispersing at least one amphiphilic polymer in an aqueous solution of a polycarboxylate, and spray-drying the dispersions thus obtainable to form finely divided polymer mixtures, use of the finely divided polymer mixtures as ingredient of detergent and as laundry aftertreatment, and finely divided polymer mixtures having a particle size from 20 .mu.m to 3 mm prepared by the above-indicated process.
摘要翻译： 一种制备两亲聚合物和多羧酸盐的细碎混合物的方法，其包括将（a）水性分散体或胶体水溶液与至少一种两亲聚合物混合，和（b）重量比为（a）的聚羧酸盐的水溶液， ：（b）为1：1至1:20，各自基于固体，或将至少一种两亲性聚合物分散在聚羧酸酯的水溶液中，并喷雾干燥由此可得到的分散体以形成细分散的聚合物混合物， 使用精细分散的聚合物混合物作为洗涤剂的成分和洗涤后处理，以及通过上述方法制备的具有20μm至3mm的粒度的细碎聚合物混合物。
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公开(公告)号：US5962613A
公开(公告)日：1999-10-05
申请号：US952114
申请日：1997-11-24
IPC分类号： C08F2/38 , C08F26/00 , C08F226/06 , C08L39/00 , C11D3/37 , C08F220/54
CPC分类号： C08F226/06 , C11D3/3776
摘要： Water-soluble copolymers which are obtainable by free-radical solution polymerization ofa) 10-99.5% by weight of at least one vinylimidazole of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl, monomers of the formula ##STR2## where R.sup.4 and R.sup.5 are identical or different and are H, C.sub.1 -C.sub.4 -alkyl or together form a ring of 3 to 5 methylene groups,N-vinyloxazolidone, N-vinyltriazole, 4-vinylpyridine N-oxide or mixtures of said monomers,b) 0-89.5% by weight of other copolymerizable monoethylenically unsaturated monomers andc) 0.5-30% by weight of at least one monomer which acts as crosslinker and has at least two non-conjugated ethylenic double bondsin water and/or polar organic solvents in the presence of polymerization regulators, using from 0.1 to 5 parts by weight of polymerization regulator per 1 part by weight of crosslinker, a process for preparing the copolymers by free-radical solution polymerization of the monomers in the presence of polymerization regulators and the use of the copolymers as additive to detergents.
摘要翻译： PCT No.PCT / EP96 / 02179 371日期：1997年11月24日 102（e）1997年11月24日PCT PCT 1996年5月21日PCT公布。 第WO96 / 37525号公报 日期1996年11月28日可通过自由基溶液聚合获得的水溶性共聚物a）10-99.5重量％的至少一种下式的其中R 1，R 2和R 3相同或不同的乙烯基咪唑是H，C1 C 1-4烷基，其中R 4和R 5相同或不同并且是H，C 1 -C 4 - 烷基或一起形成3至5个亚甲基的环，N-乙烯基恶唑烷酮，N-乙烯基三唑，4-乙烯基吡啶N - 所述单体的混合物，b）0-89.5重量％的其它可共聚单烯属不饱和单体和c）0.5-30重量％的至少一种充当交联剂并且具有至少两个非共轭烯属双键的单体 在聚合调节剂存在下，在水和/或极性有机溶剂中键合，每1重量份交联剂使用0.1至5重量份的聚合调节剂，通过单体的自由基溶液聚合制备共聚物的方法 在po的存在 裂解调节剂以及共聚物作为洗涤剂添加剂的用途。
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公开(公告)号：US20050121114A1
公开(公告)日：2005-06-09
申请号：US10500306
申请日：2002-12-27
IPC分类号： C08L61/34 , C09D5/02 , C09D7/12 , C09D161/34 , C09D179/02 , C09D179/04 , C09J11/00 , C09J161/34 , C23C18/16 , C23C26/00 , C23F11/00 , C25D3/02 , C23C22/00
CPC分类号： C25D3/02 , C09D179/02 , C09D179/04 , C23F11/173
摘要： A composition for the treatment of metal surfaces and for the deposition of metals or metal alloys on plastics surfaces contains a) at least one polymer as component A, composed of the structural element (1) and at least three structural elements selected from the group consisting of b) water or another solvent which is suitable for dissolving, dispersing, suspending or emulsifying the polymer, as component B; c) if required, surface-active compounds, dispersants, suspending media and/or emulsifiers as component C. In a process for the treatment of a metal surface and a process for the deposition of metals or metal alloys on a plastics surface, the metal or plastics surface is brought into contact with a polymer (component A). Furthermore, polymers (component A) are used for the treatment of metal surfaces and for the deposition of metals or metal alloys on a plastics surface, and polymers composed of special components A′a, A′b and A′c.
摘要翻译： 用于处理金属表面和用于在塑料表面上沉积金属或金属合金的组合物包含a）至少一种作为组分A的聚合物，其由结构元件（1）和至少三种选自以下的结构元素组成： b）适于溶解，分散，悬浮或乳化聚合物的水或其它溶剂作为组分B; c）如果需要，表面活性化合物，分散剂，悬浮介质和/或乳化剂作为组分C.在用于处理金属表面的方法中以及在塑料表面上沉积金属或金属合金的方法中，金属 或塑料表面与聚合物（组分A）接触。 此外，聚合物（组分A）用于金属表面的处理和金属或金属合金在塑料表面上的沉积，以及由特殊组分A'a，A'b和A'c组成的聚合物。
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9.发明授权Use of quaternized polymerizates containing units of vinyl imidazol as a color fixing and color transfer inhibiting additive to detergent post-treatment agents and detergents 有权使用含有乙烯基咪唑单元的季铵化聚合物作为固色剂和颜色转移抑制添加剂到洗涤剂后处理剂和洗涤剂
公开(公告)号：US06165969A
公开(公告)日：2000-12-26
申请号：US284967
申请日：1999-05-05
申请人： Dieter Bockh , Hans-Ulrich Jager , Jurgen Alfred Lux , Stefan Stein , Jurgen Detering , Christian Schade
发明人： Dieter Bockh , Hans-Ulrich Jager , Jurgen Alfred Lux , Stefan Stein , Jurgen Detering , Christian Schade
CPC分类号： C08F226/06 , C11D3/0021 , C11D3/3776 , D06P1/5242 , D06P5/08
摘要： The use of polymers which comprise at least 5 mol % of quaternized 1-vinylimidazole units of the formula ##STR1## where R is C.sub.1 -C.sub.25 -alkyl, C.sub.5 -C.sub.10 -cycloalkyl or benzylR.sup.1,R.sup.2,R.sup.3 are identical or different and are H, CH.sub.3 and C.sub.2 H.sub.5, andX.sup..crclbar. is an anion,as color-fixing and color transfer-inhibiting additive to laundry aftertreatment aids and to detergents.
摘要翻译： PCT No.PCT / EP97 / 05939 Sec。 371日期1999年5月5日 102（e）日期1999年5月5日PCT 1997年10月28日PCT公布。 WO98 / 21301 PCT出版物 日期1998年5月22日使用包含至少5mol％下式的季铵化1-乙烯基咪唑单元的聚合物其中R是C 1 -C 25 - 烷基，C 5 -C 10 - 环烷基或苄基R 1，R 2，R 3相同或不同， 是H，CH 3和C 2 H 5，并且X（ - ）是阴离子，作为用于洗衣后处理助剂和洗涤剂的着色和转色抑制添加剂。
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公开(公告)号：US20050209117A1
公开(公告)日：2005-09-22
申请号：US10518447
申请日：2003-06-18
IPC分类号： C09K3/00 , C08G73/02 , C08J7/04 , C08K3/24 , C08K3/30 , C08K3/32 , C09D179/02 , C23C18/20 , C23C18/36 , C23C18/40 , C25D3/02 , C25D3/22 , C25D3/38 , C25D3/48 , C25F1/00 , H05K3/18 , C11D1/00
CPC分类号： C08J7/047 , C08G73/0233 , C08J2479/00 , C08K3/24 , C08K3/30 , C08K3/32 , C09D179/02 , C23C18/2006 , C23C18/2073 , C23C18/285 , C23C18/30 , C23C18/36 , C23C18/405 , C25D3/02 , C25D3/22 , C25D3/38 , C25D3/48 , C25F1/00 , H05K3/181 , C08L79/08
摘要： A composition for the surface treatment of metals and for the deposition of metals or metal alloys and plastics surfaces comprises a) at least one polymer as component A, comprising at least one structural unit of the formula (I) where this structural unit may be part of a polymer main chain or may be bound to a polymer main chain via an anchor group, and M is hydrogen or an ammonium or metal cation; b) water or another solvent which is suitable for dissolving, dispersing, suspending or emulsifying the polymer (component A), as component B; c) if required, surface-active compounds, dispersants, suspending media and/or emulsifiers as component C; either d) if required, a salt, an acid or a base based on transition metal cations, transition metal oxoanions, fluorometallates or lanthanoids as component D, and/or e) at least one acid selected from the group consisting of phosphoric acid, sulfuric acid, sulfonic acid, nitric acid, hydrofluoric acid and hydrochloric acid as component E, or a base and/or f) at least one metal oxide and/or metal salt as component F. Furthermore, in a process for the surface treatment of metals and in a process for the deposition of metals or metal alloys on a metal surface or plastics surface, the metal surface or plastics surface is brought into contact with a polymer (component A). Moreover, polymers (component A) are used for the surface treatment of metals and for the deposition of metals or metal alloys on a metal surface or plastics surface.
摘要翻译： 用于表面处理金属和金属或金属合金和塑料表面沉积的组合物包括a）至少一种作为组分A的聚合物，其包含至少一种式（I）的结构单元，其中该结构单元可以是部分 的聚合物主链，或者可以通过锚定基团与聚合物主链结合，M是氢或铵或金属阳离子; b）适于溶解，分散，悬浮或乳化聚合物（组分A）的水或其它溶剂作为组分B; c）如果需要，表面活性化合物，分散剂，悬浮介质和/或乳化剂作为组分C; d）如果需要，基于过渡金属阳离子，过渡金属氧代阴离子，氟金属盐或镧系元素作为组分D的盐，酸或碱，和/或e）至少一种选自磷酸，硫酸 酸，磺酸，硝酸，氢氟酸和盐酸作为组分E，或碱和/或f）至少一种作为组分F的金属氧化物和/或金属盐。此外，在金属表面处理方法 并且在金属表面或塑料表面上沉积金属或金属合金的过程中，金属表面或塑料表面与聚合物（组分A）接触。 此外，聚合物（组分A）用于金属表面处理和金属或金属合金在金属表面或塑料表面上的沉积。
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