公开(公告)号：US4836878A

公开(公告)日：1989-06-06

申请号：US176578

申请日：1988-04-01

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： C08G59/00 ,  C08F283/10 ,  C08F299/02 ,  C08G59/40 ,  C08G59/62 ,  C08G59/66 ,  C09J163/00

CPC分类号： C08G59/66 ,  C08F283/10 ,  C08F299/026 ,  C08G59/621

摘要： Curable compositions, especially suitable for use as adhesives, contain(A) an anaerobically polymerizable mixture which is stable in oxygen but polymerizes when oxygen is excluded, comprising(i) a free radical polymerizable compound, such as an acrylate or methacrylate ester,(ii) an organic free radical initiator, such as a peroxide or hydroperoxide, and(iii) an organic accelerator of free radical polymerization(B) an epoxide resin, and(C) a curing agent for epoxide resins that is a basic curing agent, a polymercaptan, or a polyhydric phenol.These compositions cure rapidly by an araerobic curing mechanism and then develop high strength by cure of the epoxide resin.

摘要翻译： 特别适合用作粘合剂的可固化组合物含有（A）在氧气中稳定的可厌氧聚合的混合物，但当排除氧时聚合，包括（i）可自由基聚合的化合物，例如丙烯酸酯或甲基丙烯酸酯，（ii） ）有机自由基引发剂，例如过氧化物或氢过氧化物，和（iii）自由基聚合的有机促进剂（B）环氧树脂，和（C）作为碱性固化剂的环氧树脂的固化剂， 聚硫醇或多元酚。 这些组合物通过厌氧固化机理快速固化，然后通过环氧树脂的固化发展出高强度。

公开(公告)号：US4966923A

公开(公告)日：1990-10-30

申请号：US120044

申请日：1987-11-13

申请人： Christopher P. Banks ,  Edward Irving ,  Alfred Renner ,  Terence J. Smith

发明人： Christopher P. Banks ,  Edward Irving ,  Alfred Renner ,  Terence J. Smith

IPC分类号： C08F220/20 ,  C07D209/76 ,  C08F2/46 ,  C08F20/10 ,  C08F26/00 ,  C08F226/06 ,  C08J5/24 ,  G03F7/027 ,  G03F7/038

CPC分类号： G03F7/027 ,  C07D209/76 ,  C08F226/06 ,  C08J5/24

摘要： A polymerizable composition comprises a mixture of(A) a substance having at least one allyl- or methallyl-substituted bicyclo[2.2.1]-hept-5-ene-2,3-dicarboxylic acid imide residue, and(B) a substance having at least one polymerizable residue of formulaCH.sub.2 =C(R.sup.1)COO-- I where R.sup.1 denotes a hydrogen atom or a methyl group.Typically, (A) is bis[4-(allylbicyclo[2.2.1]hept-5-ene-2,3-dicarboximidophenyl)]methane and (B) is an acrylate or methacrylate of a polyhydric alcohol. The compositions can be photopolymerized or heat-cured. They are suitable for use in prepreg manufacture and in image formation.

摘要翻译： 可聚合组合物包含（A）具有至少一个烯丙基或甲代烯丙基取代的双环[2.2.1] - 庚-5-烯-2,3-二羧酸酰亚胺残基的物质和（B）物质 具有式CH 2 = C（R 1）COO-I的至少一个可聚合残基，其中R 1表示氢原子或甲基。 通常，（A）是双[4-（烯丙基双环[2.2.1]庚-5-烯-2,3-二甲酰苯基）]甲烷，（B）是多元醇的丙烯酸酯或甲基丙烯酸酯。 组合物可以光聚合或热固化。 它们适用于预浸料制造和成像。

公开(公告)号：US4546067A

公开(公告)日：1985-10-08

申请号：US571211

申请日：1984-01-16

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： G03F7/038 ,  G03C5/16

CPC分类号： G03F7/038

摘要： A layer of a liquid composition containing(A) a heat-activated latent polymerizing agent for 1,2-epoxides with(B) a light-sensitive compound having in the same molecule at least one 1,2-epoxide group and at least one chalcone or cinnamate group, or with a mixture of(C) a compound containing at least one 1,2-epoxide group together with(D) a compound containing at least one chalcone or cinnamate group,is heated so that the layer solidifies due to thermal polymerization through the 1,2-epoxide group, remaining, however, photocrosslinkable. The solidified layer is exposed in a predetermined pattern to actinic radiation, the parts so exposed becoming photocrosslinked through the chalcone or cinnamate unit(s) and hence insoluble. An image is produced which can be developed by means of suitable solvents.An example of a suitable latent polymerizing agent (A) is boron trichloride-N-methylpiperidine complex, and a suitable light-sensitive compound (B) is 1-(p-(glycidyloxy)phenyl)-5-phenylpenta-1,4-dien-3-one.

摘要翻译： 一种含有（A）用于1,2-环氧化物的热活化潜在聚合剂的液体组合物层，（B）具有相同分子中至少一个1,2-环氧基的光敏化合物和至少一种 查耳酮或肉桂酸酯基，或与（C）含有至少一个1,2-环氧基的化合物与（D）含有至少一个查耳酮或肉桂酸酯基的化合物的混合物的混合物加热，使得由于 通过1,2-环氧基进行热聚合，剩下的是可光交联的。 固化层以预定图案暴露于光化辐射，所暴露的部分通过查耳酮或肉桂酸酯单元光交联并因此不溶。 产生可以通过合适的溶剂开发的图像。 合适的潜在聚合剂（A）的实例是三氯化硼-N-甲基哌啶络合物，合适的光敏化合物（B）是1-（对 - （缩水甘油氧基）苯基）-5-苯基戊-1,4- 二烯-3-酮。

公开(公告)号：US4500629A

公开(公告)日：1985-02-19

申请号：US517095

申请日：1983-07-25

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： G03F7/40 ,  G03F7/027 ,  G03F7/038 ,  G03F7/16 ,  G03F7/38 ,  G03C5/00

CPC分类号： G03F7/168 ,  G03F7/027 ,  Y10S430/136 ,  Y10S522/904

摘要： Images are prepared by a process in which a layer, supported on a substrate, of a liquid composition comprising(a) an anaerobically polymerizable material and(b) a photopolymerizable material is maintained in a substantially oxygen-free environment such that the composition solidifies. It is then exposed imagewise to actinic radiation and treated with a developer to remove parts of the layer which have not been struck by the radiation.The anaerobically polymerizable and photopolymerizable materials may be a mixture of two or more materials having these different functions, such as an acrylate ester with an azido compound, or the two functions may be combined in a single molecule. The products are suitable for use in producing printing plates and printed circuits.

摘要翻译： 图像通过其中支撑在基底上的包含（a）可厌氧聚合材料和（b）可光聚合材料）的液体组合物的层保持在基本上无氧的环境中以使得组合物固化的方法制备。 然后将其以成像方式曝光于光化辐射，并用显影剂处理以除去未被辐射击穿的层的部分。 可厌氧聚合和可光聚合的材料可以是具有这些不同功能的两种或更多种材料的混合物，例如具有叠氮化合物的丙烯酸酯，或者这两种功能可以在单一分子中组合。 该产品适用于生产印版和印刷电路。

公开(公告)号：US4634644A

公开(公告)日：1987-01-06

申请号：US679973

申请日：1984-12-10

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： G03C1/74 ,  G03C5/00 ,  G03F7/16 ,  G03F7/20 ,  G03F7/26 ,  H05K3/00 ,  G03C5/16

CPC分类号： G03F7/168 ,  H05K3/0073

摘要： A layer of a liquid composition containing a residue that is polymerizable on contact with a gaseous polymerizing agent and a photocurable residue, which residues may be on the same or different molecules, is contained with a gaseous polymerizing agent so that the layer solidifies but remains photocurable. Subsequently the solidified layer is exposed to actinic radiation in a predetermined pattern and those parts of the layer that are not photocured are removed by treatment with a suitable solvent.Typical polymerizable residues include cyanoacrylates that polymerize on exposure to water vapor, ammonia, or an amine. Typical photocurable residues include acrylates, and methacrylates.The process is suitable for the manufacture of printing plates and printed circuits.

摘要翻译： 含有可与气态聚合剂接触聚合的残基的液体组合物层和残留物可以在相同或不同分子上的可光固化残余物与气态聚合剂一起包含，使得该层固化但保持光固化 。 随后，将固化层以预定图案暴露于光化辐射，并且通过用合适的溶剂处理除去未光固化的那些部分。 典型的可聚合残基包括在暴露于水蒸汽，氨或胺时聚合的氰基丙烯酸酯。 典型的光固化残余物包括丙烯酸酯和甲基丙烯酸酯。 该工艺适用于制造印版和印刷电路。

公开(公告)号：US4604344A

公开(公告)日：1986-08-05

申请号：US694178

申请日：1985-01-23

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： G03C1/74 ,  G03C1/00 ,  G03F7/09 ,  G03F7/11 ,  G03F7/16 ,  H05K3/00 ,  G03C7/26 ,  G03C5/16

CPC分类号： G03F7/168 ,  H05K3/0079

摘要： A polymerizing agent is applied to a substrate followed by a layer of a liquid composition containing both a polymerizable residue and a photocurable residue. The polymerizable residue is polymerized by the polymerizing agent first applied so that the layer solidifies but remains photocurable. Subsequently this solidified layer is exposed to actinic radiation in a predetermined pattern and those parts of the layer that are not photocured are removed by treatment with a suitable solvent.Typical polymerizable residues include cyanoacrylates, the polymerizing agents for which may be water, ammonium hydroxide solution, an alkali metal hydroxide solution, or an amine. Typical photocurable residues include acrylates and methacrylates.The process is suitable for the manufacture of printing plates and printed circuits.

摘要翻译： 将聚合剂施加到基材上，随后加入含有可聚合残余物和可光固化残余物的液体组合物层。 可聚合的残余物首先通过聚合剂聚合，使得层固化，但保持光固化。 随后，该固化层以预定图案暴露于光化辐射，并且通过用合适的溶剂处理除去未光固化的那些部分。 典型的可聚合残基包括氰基丙烯酸酯，其聚合剂可以是水，氢氧化铵溶液，碱金属氢氧化物溶液或胺。 典型的光固化残基包括丙烯酸酯和甲基丙烯酸酯。 该工艺适用于制造印版和印刷电路。

公开(公告)号：US4548895A

公开(公告)日：1985-10-22

申请号：US586897

申请日：1984-03-07

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： G03F7/027 ,  G03F7/038 ,  H04N1/23 ,  G03C5/00

CPC分类号： G03F7/038 ,  G03F7/027

摘要： A layer of a liquid composition containing (A) a heat-activated polymerizing agent for 1,2-epoxides, (B) a light-sensitive compound having in the same molecule at least one 1,2-epoxide group of formula ##STR1## and at least one unsaturated ester group of formulaCH.sub.2 .dbd.C(R.sup.1)COO-- IIwhere R.sup.1 =H, Cl, Br, or C.sub.1 -C.sub.4 alkyl, a mixture of (C) a compound containing at least one 1,2-epoxide group of formula I together with (D) a compound containing at least one unsaturated ester group of formula II, or a mixture of (B) with (C) and/or (D), is heated to solidify the layer, and subsequently it is exposed to actinic radiation in a predetermined pattern and those parts of the layer that have not become photopolymerized are removed by treatment with a suitable solvent.An example of a suitable polymerizing agent (A) is the complex of boron trifluoride with monoethylamine. An example of a light-sensitive compound (B) is glycidyl methacrylate. The epoxide compound (C) may be the diglycidyl ether of 2,2-bis(4-hydroxyphenyl)propane, and the unsaturated ester (D) may be 1,4-bis(2-hydroxy-3-acryloyloxypropoxy)butane.

摘要翻译： 一种含有（A）1,2-环氧化物的热活化聚合剂的液体组合物层，（B）具有相同分子的至少一个具有式的1,2-环氧基团的光敏化合物， I和至少一种式CH 2 = C（R 1）COO-II的不饱和酯基，其中R 1 = H，Cl，Br或C 1 -C 4烷基，（C）含有至少一个1,2- 将式I的环氧基团与（D）含有至少一个式II的不饱和酯基的化合物或（B）与（C）和/或（D）的混合物加热以固化该层，随后 以预定图案曝光于光化辐射，并且通过用合适的溶剂处理除去未变成光聚合的那些部分。 合适的聚合剂（A）的实例是三氟化硼与单乙胺的络合物。 光敏化合物（B）的实例是甲基丙烯酸缩水甘油酯。 环氧化合物（C）可以是2,2-双（4-羟基苯基）丙烷的二缩水甘油醚，不饱和酯（D）可以是1,4-双（2-羟基-3-丙烯酰氧基丙氧基）丁烷。

公开(公告)号：US5208110A

公开(公告)日：1993-05-04

申请号：US368452

申请日：1989-06-19

申请人： Terence J. Smith ,  Edward Irving

发明人： Terence J. Smith ,  Edward Irving

IPC分类号： B32B7/12 ,  B42D15/10 ,  C09J4/00 ,  C09J4/02 ,  C09J7/02 ,  C09J163/00 ,  G03C11/08

CPC分类号： B42D25/47 ,  B32B37/12 ,  B42D25/00 ,  G03C11/08 ,  B32B2310/0831 ,  B32B2425/00 ,  B42D2033/04 ,  B42D2033/28 ,  B42D2033/30 ,  B42D2033/32 ,  Y10S428/913 ,  Y10S428/915 ,  Y10S428/916 ,  Y10T428/24884 ,  Y10T428/31507 ,  Y10T428/31515 ,  Y10T428/31565 ,  Y10T428/31576 ,  Y10T428/31754 ,  Y10T428/31772 ,  Y10T428/31775 ,  Y10T428/31786 ,  Y10T428/31913

摘要： A security card comprises a data-carrying sheet having a gelatin layer thereon and a transparent polymeric film having a gelatin layer thereon, said sheet and said film being bonded together by an adhesive composition polymerized between and in contact with the gelatin layers, the adhesive composition comprising a carboxylic acid having at least one polymerizable acrylic group.

摘要翻译： 安全卡包括其上具有明胶层的数据载体片和在其上具有明胶层的透明聚合物膜，所述片和所述膜通过在明胶层之间聚合并与明胶层接触的粘合剂组合物粘合在一起，粘合剂组合物 包含具有至少一个可聚合丙烯酸基团的羧酸。

公开(公告)号：US4776992A

公开(公告)日：1988-10-11

申请号：US888914

申请日：1986-07-25

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： B05D7/24 ,  B05D3/06 ,  B29C35/08 ,  B29C37/00 ,  B29C41/02 ,  B29K61/04 ,  B29K63/00 ,  B29K105/08 ,  C08F2/48 ,  C08G8/28 ,  C08G18/28 ,  C08G59/16 ,  C08J5/00 ,  C08J5/04 ,  C08L61/06

CPC分类号： B29C37/0032 ,  C08G18/28 ,  C08G59/1461 ,  C08G8/28 ,  C08J5/00 ,  C08J5/04 ,  C08J5/24 ,  C08L61/06 ,  B29C2035/0833 ,  B29C2037/0035 ,  Y10S430/148 ,  Y10S522/913

摘要： Coated, reinforced composites are prepared by a process in which(i) a liquid composition comprising a photocurable residue and a residue having at least one epoxide group or phenolic hydroxyl group is applied to the surface of a mould,(ii) the composition is exposed to actinic radiation until it solidifies,(iii) reinforcement and a thermosettable composition are applied to the solidified layer, this composition containing an epoxide resin or a phenolic resin,(iv) the assembly is heated to form a cured moulding, and(v) the moulding is removed from the mould.The composition used in the first stage may be a mixture of a photocurable resin and an epoxide or phenolic resin, or a dual-functional resin having, in the same molecule, at least one photocurable group and at least one epoxide or phenolic hydroxyl group, which resin photocures in stage (ii) to produce a thermosettable resin, or it may be an epoxide resin or a phenolic resin together with a curing agent that is activated by heat and one that is activated by actinic radiation.

摘要翻译： 涂覆的增强复合材料通过以下方法制备，其中（i）包含可光固化残余物和具有至少一个环氧基团或酚羟基的残基的液体组合物施加到模具的表面，（ii）组合物暴露 （iii）将增强物和可热固组合物施加到固化层上，该组合物含有环氧树脂或酚醛树脂，（iv）将组合物加热以形成固化的模塑件，和（v） 模具从模具中取出。 在第一阶段中使用的组合物可以是光固化树脂和环氧化物或酚醛树脂的混合物，或者在相同分子中具有至少一个光固化基团和至少一个环氧化物或酚羟基的双官能树脂， 阶段（ii）中的树脂光固化以产生可热固化的树脂，或者它可以是环氧树脂或酚醛树脂以及由热激活的固化剂和由光化辐射活化的固化剂。

公开(公告)号：US4755571A

公开(公告)日：1988-07-05

申请号：US933295

申请日：1986-11-20

申请人： Edward Irving ,  Terence J. Smith

发明人： Edward Irving ,  Terence J. Smith

IPC分类号： C08G59/00 ,  C08F283/10 ,  C08F299/02 ,  C08G59/40 ,  C08G59/62 ,  C08G59/66 ,  C09J163/00 ,  C08L33/08 ,  C08L33/10 ,  C08L63/02

CPC分类号： C08G59/66 ,  C08F283/10 ,  C08F299/026 ,  C08G59/621

摘要： Curable compositions, especially suitable for use as adhesives, contain(A) an anaerobically polymerisable mixture which is stable in oxygen but polymerises when oxygen is excluded, comprising(i) a free radical polymerisable compound, such as an acrylate or methacrylate ester,(ii) an organic free radical initiator, such as a peroxide or hydroperoxide, and(iii) an organic accelerator of free radical polymerisation(B) an epoxide resin, and(C) a curing agent for epoxide resins that is a basic curing agent, a polymercaptan, or a polyhydric phenol.These compositions cure rapidly by an anaerobic curing mechanism and then develop high strength by cure of the epoxide resin.

摘要翻译： 特别适合用作粘合剂的可固化组合物含有（A）在氧气中稳定的可厌氧可聚合的混合物，当排除氧时聚合，包括（i）自由基可聚合化合物，例如丙烯酸酯或甲基丙烯酸酯，（ii） ）有机自由基引发剂，例如过氧化物或氢过氧化物，和（iii）自由基聚合的有机促进剂（B）环氧树脂，和（C）作为碱性固化剂的环氧树脂的固化剂， 聚硫醇或多元酚。 这些组合物通过厌氧固化机理快速固化，然后通过环氧树脂的固化发展出高强度。