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1.发明授权Metal impurity and high molecular weight components removal of biomass derived biocrude 有权金属杂质和高分子量成分除去生物质衍生生物公开(公告)号：US08961794B2
公开(公告)日：2015-02-24
申请号：US13177738
申请日：2011-07-07
申请人： Kristi Fjare , Jianhua Yao , Edward L. Sughrue , Jaehoon Bae , TiePan Shi , Yun Bao , Edgar Lotero
发明人： Kristi Fjare , Jianhua Yao , Edward L. Sughrue , Jaehoon Bae , TiePan Shi , Yun Bao , Edgar Lotero
IPC分类号： B01D11/04 , B01D11/02 , C10G21/06 , C10G21/14 , C10G21/16 , C10G3/00 , C10G1/02 , C10G21/02 , C10L1/02 , C10L1/00
CPC分类号： C10G3/40 , B01D11/0288 , B01D11/0492 , C10G1/02 , C10G21/02 , C10G2300/1014 , C10G2300/205 , C10G2300/208 , C10G2300/44 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10L1/02 , C10L1/023 , C10L1/026 , Y02P30/20
摘要： This invention relates to a process for production of transportation fuels from biomass. More particularly, this invention relates to a process for using solvent to remove metal impurities and high molecular weight components from biomass derived biocrude to prevent potential catalyst poisoning and catalyst bed plugging in biocrude-to-transportation fuel upgrading process.
摘要翻译： 本发明涉及从生物质生产运输燃料的方法。 更具体地说，本发明涉及一种使用溶剂从生物质衍生的生物原料中除去金属杂质和高分子量组分的方法，以防止潜在的催化剂中毒和催化剂床堵塞在生物重运输燃料升级过程中。
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公开(公告)号：US20100099933A1
公开(公告)日：2010-04-22
申请号：US12644438
申请日：2009-12-22
IPC分类号： C07C1/20
CPC分类号： C10G3/42 , C08B15/00 , C08B30/12 , C08B30/18 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G3/52 , C10G2300/1014 , C10G2400/02 , C10L1/06 , Y02P20/125 , Y02P30/20
摘要： An integrated process for the conversion of carbohydrate containing materials to gasoline boiling range hydrocarbons is disclosed. A carbohydrate containing material may be converted to a hydrogenated carbohydrate containing material with a bi-functional catalyst. The hydrogenated carbohydrate containing material may be reacted in the presence of another catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.
摘要翻译： 公开了将含碳水化合物材料转化为汽油沸程烃的综合方法。 含有碳水化合物的材料可以用双功能催化剂转化成含氢化碳水化合物的材料。 含氢化碳水化合物的材料可以在另一种催化剂的存在下反应，形成含有非芳族和芳族汽油沸程烃的反应产物。
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公开(公告)号：US20080274877A1
公开(公告)日：2008-11-06
申请号：US12175257
申请日：2008-07-17
IPC分类号： B01J20/284 , B01J20/00 , B01J20/04 , B01J20/10 , B01J20/12 , B01J20/16 , B01J20/283
CPC分类号： B01J20/06 , B01D53/02 , B01D53/8665 , B01D2253/102 , B01D2253/104 , B01D2253/108 , B01D2253/112 , B01D2257/602 , B01D2259/414 , B01J20/0214 , B01J20/3204 , B01J20/3236 , Y10S210/914 , Y10S502/516
摘要： A composition comprising a vanadium oxide compound and an alkali metal promoter loaded onto a porous support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.
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公开(公告)号：US08729322B2
公开(公告)日：2014-05-20
申请号：US12849109
申请日：2010-08-03
申请人： Edward L. Sughrue , Jianhua Yao
发明人： Edward L. Sughrue , Jianhua Yao
IPC分类号： C07C1/00
CPC分类号： C10G3/45 , C01B3/34 , C01B2203/0205 , C10G3/46 , C10G3/47 , C10G3/50 , C10G45/08 , C10G2300/1011 , C10G2300/1014 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/305 , C10G2400/02 , Y02P20/133 , Y02P20/145 , Y02P30/20
摘要： Conversion of renewable hydrocarbons to transportation fuels is required to reduce carbon emission, limit the use of fossil fuels, and develop renewable energy sources. Sorbitol, xylitol and trehelose are polyalcohols generated from the liquefaction of various sugars and carbohydrates in biomass from algae, corn, sugarcane, switchgrasses, and biological wastes. Mixtures of aqueous polyols and fuel feedstocks are catalyzed over metal catalysts to produce hexanes, pentanes, and lighter hydrocarbons. By managing the catalyst, reaction conditions and sulfur content, the octane value of the product fuel is dramatically increased.
摘要翻译： 将可再生碳氢化合物转化为运输燃料需要减少碳排放，限制化石燃料的使用和开发可再生能源。 山梨糖醇，木糖醇和古洛糖是来自藻类，玉米，甘蔗，柳枝稷和生物废物的生物质中各种糖和碳水化合物的液化所产生的多元醇。 含水多元醇和燃料原料的混合物在金属催化剂上催化产生己烷，戊烷和轻质烃。 通过管理催化剂，反应条件和硫含量，产品燃料的辛烷值显着增加。
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公开(公告)号：US08450542B2
公开(公告)日：2013-05-28
申请号：US12644438
申请日：2009-12-22
CPC分类号： C10G3/42 , C08B15/00 , C08B30/12 , C08B30/18 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G3/52 , C10G2300/1014 , C10G2400/02 , C10L1/06 , Y02P20/125 , Y02P30/20
摘要： An integrated process for the conversion of carbohydrate containing materials to gasoline boiling range hydrocarbons is disclosed. A carbohydrate containing material may be converted to a hydrogenated carbohydrate containing material with a bi-functional catalyst. The hydrogenated carbohydrate containing material may be reacted in the presence of another catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.
摘要翻译： 公开了将含碳水化合物材料转化为汽油沸程烃的综合方法。 含有碳水化合物的材料可以用双功能催化剂转化成含氢化碳水化合物的材料。 含氢化碳水化合物的材料可以在另一种催化剂的存在下反应，形成含有非芳族和芳族汽油沸程烃的反应产物。
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公开(公告)号：US20120157742A1
公开(公告)日：2012-06-21
申请号：US13332000
申请日：2011-12-20
申请人： Yun Bao , Dhananjay B. Ghonasgi , Joseph E. Bares , Sundararajan Uppili , Jianhua Yao , Xiaochun Xu , Edward L. Sughrue , Lisa L. Myers
发明人： Yun Bao , Dhananjay B. Ghonasgi , Joseph E. Bares , Sundararajan Uppili , Jianhua Yao , Xiaochun Xu , Edward L. Sughrue , Lisa L. Myers
IPC分类号： C07C7/148
CPC分类号： C10G45/08 , C10G3/46 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/202 , C10G2300/4006 , C10G2400/04 , Y02P30/20
摘要： The present disclosure relates to a process for the conversion of oxygen-containing hydrocarbons into long-chain hydrocarbons suitable for use as a fuel. These hydrocarbons may be derived from biomass, and may optionally be mixed with petroleum-derived hydrocarbons prior to conversion. The process utilizes a catalyst comprising Ni and Mo to convert a mixture comprising oxygenated hydrocarbons into product hydrocarbons containing from ten to thirty carbons. Hydro-conversion can be performed at a significantly lower temperature than is required for when utilizing a hydrotreating catalyst comprising Co and Mo (CoMo), while still effectively removing sulfur compounds (via hydrodesulfurization) to a level of 10 ppm (by weight) or less.
摘要翻译： 本公开涉及将含氧烃转化为适合用作燃料的长链烃的方法。 这些烃可以衍生自生物质，并且可以任选地在转化之前与石油衍生的烃混合。 该方法利用包含Ni和Mo的催化剂将含有氧化烃的混合物转化为含有10至30个碳的产物烃。 可以在比使用包含Co和Mo（CoMo）的加氢处理催化剂所需的温度低得多的温度下进行水力转化，同时仍然有效地将硫化合物（通过加氢脱硫）除去至10ppm（重量）以下的水平 。
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公开(公告)号：US20080254979A1
公开(公告)日：2008-10-16
申请号：US12141997
申请日：2008-06-19
CPC分类号： B01D53/64 , B01D53/8665 , B01D2253/10 , B01D2257/602 , B01J20/0214 , B01J20/06 , B01J20/3204 , B01J20/3234 , B01J20/3236 , B01J2220/42 , Y10S210/912 , Y10S210/913 , Y10S210/914 , Y10S502/514 , Y10S502/516
摘要： A sorbent composition comprising a vanadium compound and a TiO2 support material is disclosed. Methods of making and using the composition to remove heavy metals or heavy metal containing compounds from a fluid stream are also provided. Such methods are particularly useful in the removal of mercury and mercury compounds from flue gas streams produced from the combustion of hydrocarbon-containing materials such as coal and petroleum fuels.
摘要翻译： 公开了一种包含钒化合物和TiO 2载体材料的吸附剂组合物。 还提供了制备和使用该组合物以从流体流中除去重金属或含重金属的化合物的方法。 这种方法特别适用于从含烃材料如煤和石油燃料的燃烧产生的烟道气流中除去汞和汞化合物。
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公开(公告)号：US07449104B2
公开(公告)日：2008-11-11
申请号：US10190457
申请日：2002-07-05
CPC分类号： B01J20/06 , B01J20/0225 , B01J20/08 , B01J20/106 , B01J20/28004 , B01J20/28011 , B01J20/3433 , B01J20/3458 , C10G11/05 , C10G11/18 , C10G25/09
摘要： An integrated fluid catalytic cracking (FCC) and desulfurization system for processing hydrocarbon-containing fluids. The integrated system employs a cracking/desulfurization unit having a reactor, a regenerator, and a reducer. A mixture of solid FCC catalyst particulates and solid sulfur sorbent particulates are circulated through the reactor, regenerator, and reducer to provide for substantially continuous cracking and desulfurization of the hydrocarbon-containing fluid, as well as substantially continuous regeneration of both the FCC catalyst and the sulfur sorbent.
摘要翻译： 用于处理含烃流体的综合流化催化裂化（FCC）和脱硫系统。 集成系统采用具有反应器，再生器和还原剂的裂化/脱硫装置。 固体FCC催化剂颗粒和固体硫吸附剂颗粒的混合物循环通过反应器，再生器和还原剂，以提供含烃流体的基本上连续的裂化和脱硫，以及FCC催化剂和 硫吸附剂。
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公开(公告)号：US07666298B2
公开(公告)日：2010-02-23
申请号：US10821161
申请日：2004-04-07
申请人： Paul F. Meier , Edward L. Sughrue , Jan W. Wells , Douglas W. Hausler , Max W. Thompson , Amos A. Avidan
发明人： Paul F. Meier , Edward L. Sughrue , Jan W. Wells , Douglas W. Hausler , Max W. Thompson , Amos A. Avidan
IPC分类号： C10G25/00
CPC分类号： B01D53/12 , B01D53/0407 , B01D53/508 , B01D2253/1122 , B01D2253/1124 , B01D2253/304 , B01D2256/24 , B01D2257/30 , B01D2259/40086 , B01D2259/403 , B01D2259/414 , B01J8/0055 , B01J8/1872 , B01J8/26 , B01J8/34 , B01J2208/0084 , B01J2219/00006 , C10G25/003 , C10G25/09 , C10G25/12
摘要： A method and apparatus for removing sulfur from a hydrocarbon-containing fluid stream wherein desulfurization is enhanced by improving the contacting of the hydrocarbon-containing fluid stream and sulfur-sorbing solid particulates in a fluidized bed reactor.
摘要翻译： 一种用于从含烃流体物流中除去硫的方法和装置，其中通过改进流化床反应器中含烃流体物流和吸附硫的固体颗粒的接触来增强脱硫。
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公开(公告)号：US07241929B2
公开(公告)日：2007-07-10
申请号：US10660138
申请日：2003-09-11
申请人： Edward L. Sughrue , Marvin J. Johnson , Glen W. Dodwell , Larry E. Reed , Joseph E. Bares , Jason J. Gislason , Robert W. Morton , James L. Malandra
发明人： Edward L. Sughrue , Marvin J. Johnson , Glen W. Dodwell , Larry E. Reed , Joseph E. Bares , Jason J. Gislason , Robert W. Morton , James L. Malandra
IPC分类号： C10L1/16
CPC分类号： B01J20/106 , B01J20/02 , B01J20/0203 , B01J20/06 , B01J20/08 , B01J20/103 , B01J2220/42 , C10G25/003 , C10G2300/202 , C10G2300/207 , C10G2300/305 , C10G2400/02 , C10G2400/04 , C10L1/06 , C10L1/08
摘要： Attrition resistant, sorbent compositions for the removal of elemental sulfur and sulfur compounds, such as hydrogen sulfide and organic sulfides, from cracked-gasoline and diesel fuels are prepared by the impregnation of a sorbent support comprising zinc oxide, expanded perlite, and alumina with a promoter such as nickel, nickel oxide or a precursor of nickel oxide followed by reduction of the valence of the promoter metal in the resulting promoter metal sorbent support composition. Also disclosed is a composition comprising desulfurized, cracked-gasoline wherein the desulfurized cracked-gasoline comprises less than about 1 ppmw thiol compounds and less than about 1 ppmw tetrahydrothiophene compounds.
摘要翻译： 通过将包含氧化锌，膨胀珍珠岩和氧化铝的吸附剂载体浸渍在一起，可以制备用于从裂化汽油和柴油燃料中去除元素硫和硫化合物如硫化氢和有机硫化物的吸附剂组合物 促进剂如镍，氧化镍或氧化镍的前体，随后在所得助催化剂金属吸附剂载体组合物中降低助催化剂金属的价态。 还公开了包含脱硫的裂化汽油的组合物，其中脱硫裂化汽油包含小于约1ppmw的硫醇化合物和小于约1ppmw的四氢噻吩化合物。
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