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公开(公告)号：US06395841B1
公开(公告)日：2002-05-28
申请号：US09717866
申请日：2000-11-21
IPC分类号： C08F804
摘要： The present invention is a continuous process for hydrogenating an unsaturated polymer comprising: contacting the unsaturated polymer with a hydrogenating agent in a fixed bed reactor, wherein the reactor is packed with a hydrogenation catalyst characterized in that the hydrogenation catalyst comprises a Group VIII metal component and at least one deactivation resistant component.
摘要翻译： 本发明是用于氢化不饱和聚合物的连续方法，包括：在固定床反应器中使不饱和聚合物与氢化剂接触，其中反应器装有氢化催化剂，其特征在于氢化催化剂包含第VIII族金属组分和 至少一种失活抗性组分。
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公开(公告)号：US5484862A
公开(公告)日：1996-01-16
申请号：US402297
申请日：1995-03-10
CPC分类号： B01J19/18 , C08F12/04 , B01J2219/182 , C08F2420/04 , Y10S526/902
摘要： A liquid phase, powder bed polymerization process for preparing syndiotactic polymers of vinylaromatic monomers comprising:A) continuously introducing one or more vinylaromatic monomers and one or more catalyst systems to a horizontally disposed, continuously agitated, cylindrically shaped reactor containing a particulated solid, the contents of which are maintained in an agitated state at a Froude Number in the range from 0.1 to 10, andB) continuously removing polymerized product therefrom.
摘要翻译： 一种用于制备乙烯基芳族单体的间同立构聚合物的液相，粉末床聚合方法，包括：A）将一种或多种乙烯基芳族单体和一种或多种催化剂体系连续引入到包含微粒固体的水平设置的连续搅拌的圆柱形反应器中， 其保持在弗劳德数的搅拌状态，范围为0.1至10，B）连续地从其中除去聚合产物。
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公开(公告)号：US4833222A
公开(公告)日：1989-05-23
申请号：US111229
申请日：1987-10-22
IPC分类号： C08F2/10 , A61L15/60 , C08F2/00 , C08F220/04
CPC分类号： C08F220/04 , A61L15/60
摘要： A process for the preparation of an absorbent polymeric composition is disclosed. The process involves the polymerization of an aqueous solution of carboxylic acid monomers in a neutralized or partially neutralized form in the presence of a dispersing agent which aids in the even dispersion of the crosslinking agent. The polymers prepared exhibit high absorptive capacities and low water-soluble polymer content.
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4.发明授权On-line synthesis and regeneration of a catalyst used in autothermal oxidation 有权用于自热氧化的催化剂的在线合成和再生公开(公告)号：US06624116B1
公开(公告)日：2003-09-23
申请号：US09706464
申请日：2000-11-03
IPC分类号： B01J2396
CPC分类号： C07C5/48 , B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/626 , B01J23/6445 , B01J23/70 , B01J23/76 , B01J23/8926 , B01J23/8966 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/0201 , B01J37/0207 , B01J37/0238 , B01J37/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2527/224 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y10S502/514 , C07C11/04 , C07C11/02
摘要： An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.
摘要翻译： 合成或再生用于自热氧化方法的催化剂的在线方法，具体地，将链烷烃如乙烷，丙烷和石脑油氧化成烯烃，例如乙烯和丙烯。 催化剂在载体上，优选整料载体上包含8B族金属，例如铂族金属和任选的助催化剂，例如锡，锑或铜。 在线合成或再生包括在点燃或自热条件下将挥发性第8B族金属化合物和/或挥发性促进剂化合物与链烷烃和氧共同进料到氧化反应器中。
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公开(公告)号：US06566573B1
公开(公告)日：2003-05-20
申请号：US09388219
申请日：1999-09-01
申请人： Sameer S. Bharadwaj , Joseph J. Maj , Jonathan H. Siddall , Mark D. Bearden , Craig B. Murchison , Gerald E. Lazaruk
发明人： Sameer S. Bharadwaj , Joseph J. Maj , Jonathan H. Siddall , Mark D. Bearden , Craig B. Murchison , Gerald E. Lazaruk
IPC分类号： C07C5333
CPC分类号： C07C5/48 , B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/626 , B01J23/6445 , B01J23/70 , B01J23/76 , B01J23/8926 , B01J23/8966 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/0201 , B01J37/0207 , B01J37/0238 , B01J37/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2527/224 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y10S502/514 , C07C11/04 , C07C11/02
摘要： A process and catalyst for the partial oxidation of paraffinic hydrocarbons, such as ethane, propane, naphtha, and natural gas condensates, to olefins, such as ethylene and propylene. The process involves contacting a paraffinic hydrocarbon with oxygen in the presence of hydrogen and a catalyst under autothermal process conditions. Preheating the feed decreases oxygen consumption and increases the net hydrogen balance. The catalyst comprises a Group 8B metal, preferably, a platinum group metal, and at least one promoter selected from Groups 1B, 6B, 3A, 4A, and 5A, optionally supported on a catalytic support, such as magnesia or alumina. In preferred embodiments, the support is pretreated with a support modifier selected from Groups 1A, 2A, 3B, 4B, 5B, 6B, 1B, 3A, 4A, 5A, the rare earth lanthanides, and the actinides. A modified fluidized bed reactor is disclosed for the process.
摘要翻译： 用于将链烷烃（例如乙烷，丙烷，石脑油和天然气）部分氧化的方法和催化剂冷凝成烯烃，例如乙烯和丙烯。 该方法包括在自热过程条件下在氢气和催化剂存在下使链烷烃与氧接触。 饲料预热会减少氧气消耗，并增加净氢平衡。 该催化剂包含8B族金属，优选铂族金属和至少一种选自1B，6B，3A，4A和5A族的助催化剂，任选负载在催化载体如氧化镁或氧化铝上。 在优选的实施方案中，载体用选自组1A，2A，3B，4B，5B，6B，1B，3A，4A，5A，稀土镧系元素和锕系元素的载体改性剂预处理。 公开了改进的流化床反应器。
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6.发明授权On-line synthesis and regenerating of a catalyst used in autothermal oxidation 有权用于自热氧化的催化剂的在线合成和再生
公开(公告)号：US6166283A
公开(公告)日：2000-12-26
申请号：US388220
申请日：1999-09-01
IPC分类号： B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/62 , B01J23/644 , B01J23/70 , B01J23/755 , B01J23/76 , B01J23/89 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/02 , B01J37/16 , B01J37/18 , C07B61/00 , C07C4/06 , C07C5/48 , C07C11/04 , C07C11/06 , C07C11/09 , C07C11/167 , C10G11/02 , C10G11/22 , C10G27/04 , C07C5/327 , C07C5/333 , C07C5/373
CPC分类号： C07C5/48 , B01J21/04 , B01J21/10 , B01J23/40 , B01J23/54 , B01J23/56 , B01J23/626 , B01J23/6445 , B01J23/70 , B01J23/76 , B01J23/8926 , B01J23/8966 , B01J23/96 , B01J35/04 , B01J35/06 , B01J37/0201 , B01J37/0207 , B01J37/0238 , B01J37/18 , C07C2521/02 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/10 , C07C2521/12 , C07C2521/14 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/42 , C07C2523/44 , C07C2523/50 , C07C2523/72 , C07C2527/224 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y10S502/514 , C07C11/04 , C07C11/02
摘要： An on-line method of synthesizing or regenerating catalysts for autothermal oxidation processes, specifically, the oxidation of paraffinic hydrocarbons, for example, ethane, propane, and naphtha, to olefins, for example, ethylene and propylene. The catalyst comprises a Group 8B metal, for example, a platinum group metal and, optionally, a promoter, such as tin, antimony, or copper, on a support, preferably a monolith support. On-line synthesis or regeneration involves co-feeding a volatile Group 8B metal compound and/or a volatile promoter compound with the paraffinic hydrocarbon and oxygen into the oxidation reactor under ignition or autothermal conditions.
摘要翻译： 合成或再生用于自热氧化方法的催化剂的在线方法，具体地，将链烷烃如乙烷，丙烷和石脑油氧化成烯烃，例如乙烯和丙烯。 催化剂在载体上，优选整料载体上包含8B族金属，例如铂族金属和任选的助催化剂，例如锡，锑或铜。 在线合成或再生包括在点燃或自热条件下将挥发性第8B族金属化合物和/或挥发性促进剂化合物与链烷烃和氧共同进料到氧化反应器中。
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