High stability conductive polyacetylene material and process for the
production thereof
    4.
    发明授权
    High stability conductive polyacetylene material and process for the production thereof 失效
    高稳定性导电聚乙炔材料及其制备方法

    公开(公告)号:US4481132A

    公开(公告)日:1984-11-06

    申请号:US395294

    申请日:1982-07-06

    摘要: The invention relates to a doped polyacetylene film for forming an organic semiconductor or even a conductor of a metallic type. It serves to make the doping more homogeneous and improves the stability over a period of time. The process consists of using as the dopant a salt of an element such as chrome, nickel, iron, titanium, tungsten, or molybdenum belonging to the transition metals, or a salt of an element such as europium or ytterbium belonging to the lanthanides. Doping takes place by immersing the film in a solution having a low dopant concentration, e.g. in toluene, and maintaining the system at low pressure and ordinary temperature for a period of a few days, as a function of the desired doping level and conductivity.

    摘要翻译: 本发明涉及用于形成有机半导体或甚至金属型导体的掺杂聚乙炔膜。 它用于使掺杂更均匀,并且在一段时间内提高了稳定性。 该方法包括使用属于过渡金属的诸如铬,镍,铁,钛,钨或钼的元素的盐作为掺杂剂,或者属于镧系元素的元素如铕或镱的盐。 通过将膜浸入低掺杂剂浓度的溶液中来进行掺杂。 在甲苯中,并将系统保持在低压和常温下几天的时间,作为所需掺杂浓度和电导率的函数。

    Thienopyridinone derivatives and anti-bacterial compositions containing
them
    5.
    发明授权
    Thienopyridinone derivatives and anti-bacterial compositions containing them 失效
    噻吩并吡啶酮衍生物和含有它们的抗菌组合物

    公开(公告)号:US4663329A

    公开(公告)日:1987-05-05

    申请号:US730184

    申请日:1985-05-03

    CPC分类号: C07D495/04 C07D333/36

    摘要: Thienopyridinone derivatives of the general formula: ##STR1## in which Y represents hydrogen or a lower alkyl group and X represents: a hydroxy, lower alkanoyloxy, lower alkoxy unsubstituted or substituted by a hydroxy, lower alkoxy, di-(lower alkyl)-amino, piperidino, pyrrolidino, morpholino or N-(lower alkyl)-piperazino group,a group of formula: ##STR2## in which R' and R", which are the same or different, each represent hydrogen or a lower alkyl, W represents hydrogen or a lower alkyl radical or a vinyl or ethynyl group and Z represents hydrogen or a lower alkyl radical,a phenyl radical unsubstituted or substituted by an atom of fluorine, chlorine, bromine or iodine or by a hydroxy, lower alkoxy or nitro group,a group of formula: ##STR3## in which Z has the same meaning as above, an amino, lower alkylamino or --NHCOOZ group in which Z has the same meaning as above and pharmaceutically acceptable salts thereof.They possess antibacterial properties.

    摘要翻译: 其中Y表示氢或低级烷基,X表示:羟基,低级烷酰氧基,未取代的或被羟基,低级烷氧基,二 - (低级烷基) - 氨基取代的低级烷氧基的噻吩并吡啶酮衍生物 ,哌啶子基,吡咯烷子基,吗啉代或N-(低级烷基)哌嗪基,其中相同或不同的R'和R“'各自表示氢或 低级烷基,W表示氢或低级烷基或乙烯基或乙炔基,Z表示氢或低级烷基,未被取代或被氟,氯,溴或碘原子或羟基取代的苯基, 低级烷氧基或硝基,其中Z具有与上述相同的含义的下式的基团:其中Z具有与上述相同含义的氨基,低级烷基氨基或-NHCOOZ基团及其药学上可接受的盐。 它们具有抗菌性能。

    Highly pure alkyl 2-cyanoacrylates
    8.
    发明授权
    Highly pure alkyl 2-cyanoacrylates 有权
    高纯度2-氰基丙烯酸烷基酯

    公开(公告)号:US6057472A

    公开(公告)日:2000-05-02

    申请号:US129951

    申请日:1998-08-06

    CPC分类号: C07C253/30

    摘要: A process for the preparation of a highly pure alkyl 2-cyanoacrylate, wherein alkyl has 1-10 C atoms, characterized in thata) formaldehyde is reacted with an alkyl cyanoacetate ester by means of a catalyst in a solvent mixture selected from the group comprising ethylacetate, diglyme, dichloroethane and benzene, yielding an oligo-(alkyl 2-cyanoacrylate);b) the product of (a) is separated in the form of a solid;c) the product of (b) is depolymerized under sulfur dioxide atmosphere free from other polymerization inhibitors to yield an alkyl 2-cyanoacrylate with a purity of 98-100%

    摘要翻译: 一种制备高纯度2-氰基丙烯酸烷基酯的方法,其中烷基具有1-10个C原子,其特征在于:a)使甲醛与氰基乙酸烷基酯反应,在催化剂中以选自以下的溶剂混合物: 乙酸乙酯,二甘醇二甲醚,二氯乙烷和苯,得到低聚(2-氰基丙烯酸烷基酯); b)(a)的产物以固体形式分离; c)(b)的产物在没有其它聚合抑制剂的二氧化硫气氛下解聚,得到纯度为98-100%的2-氰基丙烯酸烷基酯,

    Intermediates for anti-bacterial thienopyridinones
    10.
    发明授权
    Intermediates for anti-bacterial thienopyridinones 失效
    中间体用于抗菌噻吩并吡啶酮

    公开(公告)号:US4739065A

    公开(公告)日:1988-04-19

    申请号:US545

    申请日:1987-01-05

    CPC分类号: C07D495/04 C07D333/36

    摘要: Thienopyridinone derivatives of the general formula: ##STR1## in which Y represents hydrogen or a lower alkyl group and X represents: a hydroxy, lower alkanoyloxy, lower alkoxy unsubstituted or substituted by a hydroxy, lower alkoxy, di-(lower alkyl)-amino, piperidino, pyrrolidino, morpholino or N-(lower alkyl)-piperazino group,a group of formula: ##STR2## in which R' and R", which are the same or different, each represent hydrogen or a lower alkyl, W represents hydrogen or a lower alkyl radical or a vinyl or ethynyl group and Z represents hydrogen or a lower alkyl radical,a phenyl radical unsubstituted or substituted by an atom of fluorine, chlorine, bromine or iodine or by a hydroxy, lower alkoxy or nitro group,a group of formula: ##STR3## in which Z has the same meaning as above, an amino, lower alkylamino or --NHCOOZ group in which Z has the same meaning as above and pharmaceutically acceptable salts thereof.They possess antibactericidal properties.

    摘要翻译: 其中Y表示氢或低级烷基,X表示:羟基,低级烷酰氧基,未取代的或被羟基,低级烷氧基,二 - (低级烷基) - 氨基取代的低级烷氧基的噻吩并吡啶酮衍生物 ,哌啶子基,吡咯烷子基,吗啉代或N-(低级烷基)哌嗪基,其中相同或不同的R'和R“'各自表示氢或 低级烷基,W表示氢或低级烷基或乙烯基或乙炔基,Z表示氢或低级烷基,未被取代或被氟,氯,溴或碘原子或羟基取代的苯基, 低级烷氧基或硝基,其中Z具有与上述相同的含义的下式的基团:其中Z具有与上述相同含义的氨基,低级烷基氨基或-NHCOOZ基团及其药学上可接受的盐。 它们具有抗菌性。