公开(公告)号：US5252418A

公开(公告)日：1993-10-12

申请号：US567180

申请日：1990-08-14

申请人： Fuminori Ishikawa ,  Akira Sato ,  Kunihiro Tamahashi ,  Masatoshi Wakagi ,  Katsumi Tamura ,  Masanobu Hanazono ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Motoo Akagi ,  Masaaki Imamura

发明人： Fuminori Ishikawa ,  Akira Sato ,  Kunihiro Tamahashi ,  Masatoshi Wakagi ,  Katsumi Tamura ,  Masanobu Hanazono ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Motoo Akagi ,  Masaaki Imamura

IPC分类号： G03G5/147 ,  G03G5/14

CPC分类号： G03G5/14704

摘要： An electrophotographic photoreceptor comprising a photoconductive layer comprising a photoconductor, a support for the photoconductive layer and a surface layer formed on the photoconductive layer and comprising a curable resin film and an inorganic insulator pieces having a size larger than the film thickness of the curable resin film. In order to prevent the image blurring of an a-Si:H photoreceptor, on the outermost surface of the photoreceptor was formed a surface layer having a structure in which inorganic insulator pieces have protruded from the curable resin film. Since the curable resin is of high resistance and shows no quality change by corona irradiation, and besides the protruding inorganic insulator pieces prevent the abrasion of the resin, the surface layer having a long life and excellent humidity resistance, durability for corona irradiation and abrasion resistance can be realized. Further, by covering the surface layer with a fluorine-containing lubricant, the surface layer having a low friction coefficient and excellent cleaning characteristics is obtained, and besides the resin constituting the surface layer absorbs little moisture. As a result, it becomes possible to use the a-Si:H photoreceptors without a heater. Also, the surface layer of the present invention can be removed and then re-formed.

公开(公告)号：US5073466A

公开(公告)日：1991-12-17

申请号：US394657

申请日：1989-08-16

申请人： Fuminori Ishikawa ,  Kunihiro Tamahashi ,  Shigeharu Onuma ,  Masatoshi Wakagi ,  Masanobu Hanazono ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Yasuo Shimamura ,  Chiaki Yamagishi

发明人： Fuminori Ishikawa ,  Kunihiro Tamahashi ,  Shigeharu Onuma ,  Masatoshi Wakagi ,  Masanobu Hanazono ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Yasuo Shimamura ,  Chiaki Yamagishi

IPC分类号： G03G5/147

CPC分类号： G03G5/1476 ,  G03G5/147 ,  G03G5/14708 ,  G03G5/14786

摘要： An electrophotographic member comprising a support, a photoconductive layer formed thereon, and a surface layer formed thereon, said surface layer including or attaching a lubricating agent having a perfluoropolyoxyalkyl or perfluoropolyoxyalkylene group to form an organic surface protective lubricating layer, and a fixing group to be fixed to the surface layer, is excellent in moisture resistance, wear resistance and cleaning properties and thus useful in an electrophotographic apparatus with a long life and high reliability.

公开(公告)号：US5204202A

公开(公告)日：1993-04-20

申请号：US494527

申请日：1990-03-16

申请人： Fuminori Ishikawa ,  Kunihiro Tamahashi ,  Shigeharu Onuma ,  Masatoshi Wakagi ,  Masanobu Hanazono ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Chiaki Yamabishi

发明人： Fuminori Ishikawa ,  Kunihiro Tamahashi ,  Shigeharu Onuma ,  Masatoshi Wakagi ,  Masanobu Hanazono ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Chiaki Yamabishi

IPC分类号： G03G5/00 ,  G03G5/08 ,  G03G5/147

CPC分类号： G03G5/005 ,  G03G5/14704

摘要： An electrophotographic photosensitive element, e.g. for a photocopier or laser printer, comprises a substrate and a plurality of layers on the substrate including a photoconductive layer of a-Si:H and a protective and lubricating layer which is outermost from said substrate. To provide wear resistance and long life-time of the protective and lubricating layer, this layer comprises a microporous solid material having a pore structure which extends substantially over the whole thickness of the material and a hydrophobic lubricant carried by said solid material. The lubricant includes a liquid film and often times a non-particulate solid film, and provides at least part of the outer surface of the element and is present also in the pores of said microporous solid material.

公开(公告)号：US5128435A

公开(公告)日：1992-07-07

申请号：US552514

申请日：1990-07-16

申请人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Toshikazu Narahara

发明人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Toshikazu Narahara

IPC分类号： G11B5/72 ,  C08G18/58 ,  C08G18/77 ,  C08G18/80 ,  C08G59/40 ,  C09D163/00 ,  C10M105/18 ,  C10M105/50 ,  C10N40/18 ,  G11B5/66 ,  G11B5/725

CPC分类号： G11B5/725 ,  C08G18/58 ,  C08G18/773 ,  C08G18/8054 ,  C08G18/8087 ,  C08G59/4028 ,  C09D163/00 ,  Y10S428/90 ,  Y10T428/31511 ,  Y10T428/31547

摘要： A resin composition comprising an epoxy resin and an isocyanate group-containing fluorine compound is particularly suitable for covering a magnetic recording medium comprising a non-magnetic substrate and formed thereon a thin magnetic film so as to give excellent sliding durability.

摘要翻译： 包含环氧树脂和含异氰酸酯基的氟化合物的树脂组合物特别适用于覆盖包含非磁性基底并在其上形成薄磁性膜的磁记录介质，以提供优异的滑动耐久性。

公开(公告)号：US5549835A

公开(公告)日：1996-08-27

申请号：US545908

申请日：1995-10-19

申请人： Takao Uematsu ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Shigeki Komatsuzaki ,  Yutaka Ito ,  Atsushi Morihara ,  Koji Sato ,  Shizuo Zushi ,  Hiroshi Go

发明人： Takao Uematsu ,  Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Shigeki Komatsuzaki ,  Yutaka Ito ,  Atsushi Morihara ,  Koji Sato ,  Shizuo Zushi ,  Hiroshi Go

IPC分类号： C10M131/12 ,  C10M131/08 ,  C10M133/10 ,  C10M133/16 ,  C10M139/04 ,  C10M147/04 ,  C10M169/00 ,  C10N30/00 ,  C10N40/02 ,  C10N40/06 ,  C10N40/14 ,  C10N50/10 ,  H01L23/433 ,  C10M141/12 ,  C10M157/10

CPC分类号： C10M139/04 ,  C10M131/08 ,  C10M133/16 ,  C10M147/04 ,  C10M169/00 ,  H01L23/4338 ,  C10M2201/00 ,  C10M2201/06 ,  C10M2201/061 ,  C10M2201/062 ,  C10M2201/10 ,  C10M2201/103 ,  C10M2201/105 ,  C10M2201/16 ,  C10M2201/18 ,  C10M2203/10 ,  C10M2203/1006 ,  C10M2203/1025 ,  C10M2203/1045 ,  C10M2203/1065 ,  C10M2203/1085 ,  C10M2205/00 ,  C10M2205/0206 ,  C10M2207/1225 ,  C10M2207/1245 ,  C10M2207/125 ,  C10M2207/1265 ,  C10M2207/1285 ,  C10M2207/129 ,  C10M2207/166 ,  C10M2207/186 ,  C10M2207/206 ,  C10M2207/246 ,  C10M2211/042 ,  C10M2211/044 ,  C10M2211/06 ,  C10M2213/00 ,  C10M2213/04 ,  C10M2213/06 ,  C10M2215/08 ,  C10M2215/082 ,  C10M2215/086 ,  C10M2215/12 ,  C10M2215/122 ,  C10M2215/28 ,  C10M2217/042 ,  C10M2217/043 ,  C10M2227/04 ,  C10M2229/025 ,  C10M2229/0405 ,  C10M2229/041 ,  C10M2229/0415 ,  C10M2229/0425 ,  C10M2229/0435 ,  C10M2229/0445 ,  C10M2229/0455 ,  C10M2229/0465 ,  C10M2229/0475 ,  C10M2229/0485 ,  C10M2229/0505 ,  C10M2229/0515 ,  C10M2229/0525 ,  C10M2229/0535 ,  C10M2229/0545 ,  C10N2210/01 ,  C10N2220/00 ,  C10N2220/02 ,  H01L2224/16 ,  H01L2224/73253 ,  H01L2924/01014 ,  H01L2924/01019 ,  H01L2924/12044 ,  H01L2924/15312 ,  H01L2924/16152

摘要： Disclosed are an apparatus having sliding parts and a compound for preventing diffusion or separation of a base oil; and a compound for preventing diffusion or separation of the base oil used for the apparatus: an electronic or electric appliance using a joul heat generating source, means for taking out joul heat to the outside by sliding with said heat generating source, and heat conducting compound intervenient between said heat taking out means and heat generating source; and the heat conducting compound used for the appliance.

摘要翻译： 公开了一种具有滑动部件和用于防止基础油扩散或分离的化合物的装置; 以及用于防止用于该设备的基础油的扩散或分离的化合物：使用joul发热源的电子或电器具，用于通过与所述发热源滑动而将热量取出到外部的装置，以及导热化合物 介于所述取热装置和发热源之间; 和用于该器具的导热化合物。

公开(公告)号：US5830834A

公开(公告)日：1998-11-03

申请号：US620710

申请日：1996-03-21

申请人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Hiroshi Sasaki ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Hiroyuki Matsumoto

发明人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Hiroshi Sasaki ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Hiroyuki Matsumoto

IPC分类号： C07D213/20 ,  C07D215/00 ,  C07D219/10 ,  C07D239/24 ,  C08G65/32 ,  C09D5/00 ,  C09D171/00 ,  C09D171/02 ,  C09K3/00 ,  C09K3/18 ,  C10M105/64 ,  C10M105/70 ,  C10M107/38 ,  C10M107/44 ,  C10N40/18 ,  C10N50/08 ,  G11B5/64 ,  G11B5/71 ,  G11B5/72 ,  G11B5/725 ,  G11B5/73 ,  C10M131/00

CPC分类号： C10M105/70 ,  C10M105/64 ,  G11B5/72 ,  G11B5/725 ,  C10M2213/00 ,  C10M2213/04 ,  C10M2213/06 ,  C10N2240/00 ,  C10N2240/20 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2240/203 ,  C10N2240/204 ,  C10N2240/205 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  Y10S428/90 ,  Y10T428/30 ,  Y10T428/3154 ,  Y10T428/31544

摘要： A magnetic recording medium is produced by coating a body having (a) a non-magnetic substrate, (b) at least one magnetic substance layer formed on the non-magnetic substrate and (c) at least one protective layer formed on the magnetic substance layer which contains at least one member selected from the group consisting of inorganic oxides, graphite and amorphous allotropes of carbon, with a solid surface modifier containing (i) an ammonium carboxylate type fluorine-containing compound having the formula, (R.sub.f --COO.sup.- H.sup.+).sub.n --R, wherein R.sub.f is a perfluoropolyoxyalkyl chain having a number average molecular weight of at least 800, n is a number of 1-2, and R is a residue selected from the group consisting of an aromatic ammonium which may have one or more substituents at the nucleus, benzylammonium which may have one or more substituents at the nucleus, dibenzylammonium which may have one or more substituents at the nucleus, tribenzylammonium which may have one or more substituents at the nucleus and an aromatic inium which may have one or more substituents at the nucleus, and (ii) an alcohol or fluorine-containing solvent and optionally water, on the surface of the protective layer (c), to form a coat, and then removing the solvent, or alcohol and water from the coat.

摘要翻译： 通过涂布具有（a）非磁性基底的物体，（b）形成在非磁性基底上的至少一个磁性物质层和（c）形成在磁性物质上的至少一个保护层， 包含选自无机氧化物，石墨和非晶同型异形体碳中的至少一种的固体表面改性剂，其含有（i）具有下式的（I-1）羧酸铵型含氟化合物：（Rf-COO-H + ）n R，其中Rf是数均分子量为至少800的全氟聚氧烷基链，n是1-2的数，R是选自可以具有一个或多个取代基的芳族铵的残基 在核处，在核处可能具有一个或多个取代基的苄基铵，在核处可以具有一个或多个取代基的二苄基铵，在核心a上可以具有一个或多个取代基的三苄基铵 并且在保护层（c）的表面上可以具有在核处具有一个或多个取代基的芳香族鎓鎓盐，和（ii）在保护层（c）的表面上的醇或含氟溶剂和任选的水，形成外涂层，然后除去 溶剂，或醇和水。

公开(公告)号：US5536578A

公开(公告)日：1996-07-16

申请号：US381277

申请日：1995-01-31

申请人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Hiroshi Sasaki ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Hiroyuki Matsumoto

发明人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Hiroshi Sasaki ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Hiroyuki Matsumoto

IPC分类号： C07D213/20 ,  C07D215/00 ,  C07D219/10 ,  C07D239/24 ,  C08G65/32 ,  C09D5/00 ,  C09D171/00 ,  C09D171/02 ,  C09K3/00 ,  C09K3/18 ,  C10M105/64 ,  C10M105/70 ,  C10M107/38 ,  C10M107/44 ,  C10N40/18 ,  C10N50/08 ,  G11B5/64 ,  G11B5/71 ,  G11B5/72 ,  G11B5/725 ,  G11B5/73 ,  G11B5/00

CPC分类号： C10M105/70 ,  C10M105/64 ,  G11B5/72 ,  G11B5/725 ,  C10M2213/00 ,  C10M2213/04 ,  C10M2213/06 ,  C10N2240/00 ,  C10N2240/20 ,  C10N2240/201 ,  C10N2240/202 ,  C10N2240/203 ,  C10N2240/204 ,  C10N2240/205 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66 ,  Y10S428/90 ,  Y10T428/30 ,  Y10T428/3154 ,  Y10T428/31544

摘要： A magnetic recording medium is produced by coating a body having (a) a non-magnetic substrate, (b) at least one magnetic substance layer formed on the non-magnetic substrate and (c) at least one protective layer formed on the magnetic substance layer which contains at least one member selected from the group consisting of inorganic oxides, graphite and amorphous allotropes of carbon, with a solid surface modifier containing (i) an ammonium carboxylate type fluorine-containing compound having the formula,(R.sub.f --COO.sup.- H.sup.+).sub.n --R,wherein R.sub.f is a perfluoropolyoxyalkyl chain having a number average molecular weight of at least 800, n is a number of 1-2, and R is a residue selected from the group consisting of an aromatic ammonium which may have one or more substituents at the nucleus, benzylammonium which may have one or more substituents at the nucleus, dibenzylammonium which may have one or more substituents at the nucleus, tribenzylammonium which may have one or more substituents at the nucleus and an aromatic inium which may have one or more substituents at the nucleus, and (ii) an alcohol or fluorine-containing solvent and optionally water, on the surface of the protective layer (c), to form a coat, and then removing the solvent, or alcohol and water from the coat.

摘要翻译： 通过涂布具有（a）非磁性基底的物体，（b）形成在非磁性基底上的至少一个磁性物质层和（c）形成在磁性物质上的至少一个保护层， 包含选自无机氧化物，石墨和非晶同型异形体碳中的至少一种的固体表面改性剂，其含有（i）具有下式的（I-1）羧酸铵型含氟化合物：（Rf-COO-H + ）n R，其中Rf是数均分子量为至少800的全氟聚氧烷基链，n是1-2的数，R是选自可以具有一个或多个取代基的芳族铵的残基 在核处，可能在核处具有一个或多个取代基的苄基铵，在核处可能具有一个或多个取代基的二苄基铵，在核处可能具有一个或多个取代基的三苄基铵 以及可以在核处具有一个或多个取代基的芳香族鎓盐，和（ii）在保护层（c）的表面上的醇或含氟溶剂和任选的水，形成外涂层，然后除去 溶剂，或醇和水。

公开(公告)号：US5157066A

公开(公告)日：1992-10-20

申请号：US724724

申请日：1991-07-02

申请人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Akio Mukoh

发明人： Mitsuyoshi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Akio Mukoh

IPC分类号： C08G65/333 ,  C09D171/02 ,  G03G5/147 ,  G11B5/725

CPC分类号： G11B5/725 ,  C08G65/33313 ,  C09D171/02 ,  G03G5/14708 ,  G03G5/1476 ,  G03G5/14786

摘要： A solid surface modifying composition comprising a film forming material and a fluoroalkyl ether ((Rf).sub.m (CONH--X--NHCO--Y).sub.m (m=1 or 2; Rf: perfluoropolyether chain; X: ##STR1## etc.; ##STR2## etc.) provides surfaces with such improvements as durable water and oil repellency, lubricity and lowered surface energy. The lubricating protective coating is applicable for coatings of recording mediums, photoreceptors and wirings.

摘要翻译： 一种固体表面改性组合物，其包含成膜材料和氟烷基醚（（R f）m（CONH-X-NHCO-Y）m（m = 1或2; Rf：全氟聚醚链; X： IMAGE等）为表面提供了耐水，防油，润滑和降低表面能等方面的改进。润滑保护涂层适用于记录介质，光感受器和布线的涂层。

公开(公告)号：US5219651A

公开(公告)日：1993-06-15

申请号：US790084

申请日：1991-11-13

申请人： Mitsuyosi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Fumio Nakano

发明人： Mitsuyosi Shoji ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Fumio Nakano

IPC分类号： G11B5/00 ,  G11B5/40 ,  G11B5/725

CPC分类号： G11B5/00 ,  G11B5/40 ,  G11B5/725 ,  Y10S428/90 ,  Y10T428/25 ,  Y10T428/265

摘要： A magnetic recording medium which comprises a non-magnetic substrate, a thin film magnetic layer formed on the surface of the substrate and an organic thin film protective layer formed on the magnetic layer, the organic thin film protective layer having a thickness of not more than 100 nm and containing a filler having a particle size of not more than 50 nm, wherein the surface of the organic thin film protective layer is further coated with a fluorine-based compound represented by the following general formula:F(C.sub.3 F.sub.6 --I--).sub.x --C.sub.2 F.sub.4 --,F(C.sub.3 F.sub.6 --O--).sub.x --(CF.sub.2 O).sub.y --(CF.sub.2).sub.z --or--(C.sub.2 F.sub.4 --O--).sub.y --(CF.sub.2 --CF.sub.2 --, wherein x, y and z are integers of 1 or more, and a magnetic head whose surface is coated with a lubricant thin film having the same composition as that of the above organic thin film protective layer have an excellent sliding durability, and a magnetic recording apparatus using these magnetic recording medium and magnetic head has a high reliability.

摘要翻译： 一种磁记录介质，其包括非磁性基板，形成在所述基板的表面上的薄膜磁性层和形成在所述磁性层上的有机薄膜保护层，所述有机薄膜保护层的厚度不大于 100nm，并且含有粒径不大于50nm的填料，其中有机薄膜保护层的表面进一步涂覆有由以下通式表示的氟基化合物：F（C 3 F 6 -I） x-C2F4-，F（C3F6-O-）x-（CF2O）y-（CF2）z-或 - （C2F4-O-）y-（CF2-CF2-，其中x，y和z是1 以上的表面被涂覆有与上述有机薄膜保护层相同组成的润滑剂薄膜的磁头具有优异的滑动耐久性，并且使用这些磁记录介质和磁头的磁记录装置具有 高可靠性。

公开(公告)号：US4990418A

公开(公告)日：1991-02-05

申请号：US362047

申请日：1989-06-06

申请人： Akio Mukoh ,  Mitsuoshi Shoji ,  Shigeo Suzuki ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Ryuichi Shimizu ,  Hiroyoshi Kokaku ,  Tsuneaki Kawanishi ,  Atsushi Kakuta

发明人： Akio Mukoh ,  Mitsuoshi Shoji ,  Shigeo Suzuki ,  Takayuki Nakakawaji ,  Yutaka Ito ,  Shigeki Komatsuzaki ,  Ryuichi Shimizu ,  Hiroyoshi Kokaku ,  Tsuneaki Kawanishi ,  Atsushi Kakuta

IPC分类号： G03G5/05 ,  G03G5/147

CPC分类号： G03G5/14708 ,  G03G5/051 ,  G03G5/0514 ,  G03G5/147

摘要： Disclosed is an electrophotographic photoreceptor in which an organic lubricant is provided on the surface of an organic photoconductive layer or on a protective layer formed on the organic photoconductive layer. Elements of the organic lubricant are partly exposed from the surface of the organic photoconductive layer or the protective layer while the remainder portions of the elements are embedded or fixed by chemical reaction in the surface region of the photoconductive layer or the protective layer so that the exposed portions of the elements of the organic lubricant provides a lubricating surface layer. The lubricating surface layer supresses wear of the photoreceptor thereby enabling the photosensitive layer to withstand a long repeated use without impairing electrophotographic characteristics.