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公开(公告)号：US5344852A
公开(公告)日：1994-09-06
申请号：US21716
申请日：1993-02-24
申请人： Gary T. Brooks , Harold R. Edwards, Jr. , Kathy J. Thrash , Donald E. Rubis , David P. Sinclair
发明人： Gary T. Brooks , Harold R. Edwards, Jr. , Kathy J. Thrash , Donald E. Rubis , David P. Sinclair
CPC分类号： C08G18/68 , C08G18/6529 , C08G2101/0025 , C08G2101/0041 , C08G2101/0075 , C08G2101/0083
摘要： Water blown, thermosetting unsaturated polyester-polyurethane hybrid foam compositions are formed by the reaction of an A side composition and a B side composition. The A side composition comprises a polyfunctional isocyanate compound and a free radical initiator. The B side composition comprises a mixture of: (i) an ethylenically unsaturated monomer solution having dissolved therein about 30-90 weight percent of a polyester polyol having at least one ethylenically unsaturated group per molecule which has predominantly hydroxyl end groups; (ii) an amine compound having two or more primary or secondary amine groups in an amount effective to react with the A side composition to form small urea domains finely dispersed within a continuous polyester-polyurethane hybrid phase; and (iii) about 25 to about 150 equivalents water based on 100 equivalents of active hydrogen in the B side. When the A and B side compositions are reacted, the composition will have a ratio of active NCO groups of the isocyanate to active NH groups of the amine compound of between about 10:1 and about 50:1. and an isocyanate index, NCO:(NH+OH+COOH+HOH), of between about 0.5 and about 2.0.
摘要翻译： 通过A侧组合物和B侧组合物的反应形成水吹塑，热固性不饱和聚酯 - 聚氨酯混合泡沫组合物。 A侧组合物包含多官能异氰酸酯化合物和自由基引发剂。 B侧组合物包含以下混合物：（i）其中溶解有约30-90重量％的具有主要为羟基端基的每分子具有至少一个烯键式不饱和基团的聚酯多元醇的烯属不饱和单体溶液; （ii）具有两个或更多个伯胺基或仲胺基团的胺化合物，其有效量与A侧组合物反应以形成细分散在连续聚酯 - 聚氨酯混合相中的小脲区; 和（iii）基于B侧的100当量活性氢的约25至约150当量的水。 当A和B侧组合物反应时，组合物将具有约10:1至约50:1之间的异氰酸酯的活性NCO基团与胺化合物的活性NH基团的比例。 和异氰酸酯指数NCO：（NH + OH + COOH + HOH）为约0.5至约2.0。
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2.发明授权公开(公告)号：US06462107B1
公开(公告)日：2002-10-08
申请号：US09218998
申请日：1998-12-22
申请人： David P. Sinclair , Douglas E. Fjare , John T. Hoback , Terre L. VanKirk , Donald E. Rubis , David A. Wargowski , Wen-Feng Liu , Paul A. Sanchez
发明人： David P. Sinclair , Douglas E. Fjare , John T. Hoback , Terre L. VanKirk , Donald E. Rubis , David A. Wargowski , Wen-Feng Liu , Paul A. Sanchez
IPC分类号： C08K500
CPC分类号： H05K3/4673 , C08L63/00 , G03F7/0233 , G03F7/0236 , G03F7/038 , H01L23/49894 , H01L2924/0002 , H01L2924/09701 , H05K3/0023 , H05K3/4644 , H05K2201/0195 , H05K2203/066 , C08L2666/02 , H01L2924/00
摘要： Compositions for forming polymeric layers useful in the manufacture printed wiring boards and other electrical interconnecting devices are disclosed. The compositions typically are processable in aqueous base and can be made photosensitive with the addition of a positive acting photosensitive compound. The compositions are particularly useful in the manufacture of laminable films used to make printed wiring boards. Multilayer printed wiring boards made using such films, and methods for making and using the films and boards, also are disclosed.
摘要翻译： 公开了用于形成用于制造印刷线路板和其它电互连装置的聚合物层的组合物。 组合物通常在碱性水溶液中是可加工的，并且可以通过加入正性光敏化合物使其变得光敏。 该组合物特别可用于制造用于制造印刷线路板的层压薄膜。 还公开了使用这种膜制造的多层印刷线路板以及制造和使用薄膜和板的方法。
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公开(公告)号：US06863988B2
公开(公告)日：2005-03-08
申请号：US10028167
申请日：2001-10-25
申请人： James M. Tibbitt , Paul J. Cahill , George E. Rotter , David P. Sinclair , Gary T. Brooks , Raymond T. Behrends
发明人： James M. Tibbitt , Paul J. Cahill , George E. Rotter , David P. Sinclair , Gary T. Brooks , Raymond T. Behrends
IPC分类号： B65D1/00 , B65D1/02 , B65D81/26 , C08L53/00 , C08L67/02 , C09D153/00 , B32B27/18 , B32B27/36
CPC分类号： C09D153/00 , C08L53/00 , C08L53/005 , C08L67/02 , C09D153/005 , Y10T428/1334 , Y10T428/1341 , Y10T428/1345 , Y10T428/1352 , Y10T428/1379 , Y10T428/1397 , Y10T428/31786 , C08L2666/02
摘要： Monolayer packages comprised of an oxygen scavenging composition suitable for direct contact with package contents and recycle with other polyester bottles are disclosed. The oxygen scavenging composition is comprised of a modified copolymer which is comprised of predominantly polyester segments and an oxygen scavenging amount of oxygen scavenging segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. Use of these oxygen scavenging copolymers in bottles provides a clear and rigid monolayer bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolymers of this invention are over 99 wt % PET and contain less than 50 ppb of extractable components.
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公开(公告)号：US07214415B2
公开(公告)日：2007-05-08
申请号：US11053284
申请日：2005-02-08
申请人： James M. Tibbitt , Paul J. Cahill , George E. Rotter , David P. Sinclair , Gary T. Brooks , Raymond T. Behrends
发明人： James M. Tibbitt , Paul J. Cahill , George E. Rotter , David P. Sinclair , Gary T. Brooks , Raymond T. Behrends
CPC分类号： C09D153/00 , C08L53/00 , C08L53/005 , C08L67/02 , C09D153/005 , Y10T428/1334 , Y10T428/1341 , Y10T428/1345 , Y10T428/1352 , Y10T428/1379 , Y10T428/1397 , Y10T428/31786 , C08L2666/02
摘要： Monolayer packages comprised of an oxygen scavenging composition suitable for direct contact with package contents and recycle with other polyester bottles are disclosed. The oxygen scavenging composition is comprised of a modified copolymer which is comprised of predominantly polyester segments and an oxygen scavenging amount of oxygen scavenging segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. Use of these oxygen scavenging copolymers in bottles provides a clear and rigid monolayer bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolymers of this invention are over 99 wt % PET and contain less than 50 ppb of extractable components.
摘要翻译： 公开了由适于与包装内容物直接接触并且与其它聚酯瓶循环的除氧组合物组成的单层包装。 除氧组合物由改性共聚物组成，其主要由聚酯链段和除氧量的除氧段组成。 聚酯片段包含衍生自典型装瓶和包装聚酯如PET和PEN的片段。 在瓶中使用这些除氧共聚物提供了与未改性的聚酯瓶相似的透明且刚性的单层瓶。 在一系列优选实施方案中，用本发明的除氧共聚物制造的瓶子超过99重量％的PET并且含有少于50ppb的可萃取组分。
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公开(公告)号：US5264544A
公开(公告)日：1993-11-23
申请号：US913870
申请日：1992-07-15
IPC分类号： C08G69/26
CPC分类号： C08G69/265
摘要： Amorphous polyamide compositions are provided which are transparent and have improved glass transition and thermal decomposition temperatures. The polyamide compositions of the present invention can be prepared as the polymeric condensation product of a diamine component comprising neopentyldiamine, and a diacid component comprising an aromatic dicarboxylic acid.
摘要翻译： 提供无定形聚酰胺组合物，其是透明的并且具有改善的玻璃化转变和热分解温度。 本发明的聚酰胺组合物可以制备为包含新戊基二胺的二胺组分和包含芳族二羧酸的二酸组分的聚合缩合产物。
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公开(公告)号：US5153250A
公开(公告)日：1992-10-06
申请号：US718202
申请日：1991-06-20
申请人： David P. Sinclair
发明人： David P. Sinclair
CPC分类号： C08K3/346 , C08G69/265 , C08K7/02
摘要： Improved polyphthalamide compositions, particularly for injection molding applications, comprise a polyphthalamide component with at least two recurring units selected from terephthalamide, isophthalamide and adipamide units and having high heat deflection temperature when filled with glass fibers; reinforcing fibers; and effective amounts of particulate talc. Molded articles prepared from such compositions exhibit excellent mechanical and thermal properties, including high heat deflection temperature, even when molded using molds heated below Tg of the polyphthalamide component, often facilitating molding using steam or hot water-heated molds.
摘要翻译： 改进的聚邻苯二甲酰胺组合物，特别是用于注塑应用的聚邻苯二甲酰胺组合物包含具有至少两个选自对苯二甲酰胺，间苯二甲酰胺和己二酰胺单元的重复单元的聚邻苯二甲酰亚胺组分，并且在填充玻璃纤维时具有高的热变形温度; 增强纤维; 和有效量的滑石粉。 由这种组合物制备的模制品即使在使用加热到聚邻苯二甲酰亚胺组分Tg以下的模具进行模塑时也能表现出优异的机械和热性能，包括高的热变形温度，通常有助于使用蒸汽或热水加热的模具进行模塑。
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公开(公告)号：US5643995A
公开(公告)日：1997-07-01
申请号：US478717
申请日：1995-06-07
摘要： A method for improving the processability of a crystalline polyphthalamide having high heat deflection temperature when filled with glass fibers by compounding with an amount of a polyarylene sulfide sufficient to reduce melt viscosity.
摘要翻译： 通过与足够降低熔融粘度的聚芳硫醚的量混合来填充玻璃纤维时，提高具有高热变形温度的结晶聚邻苯二甲酰胺的加工性能的方法。
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公开(公告)号：US5464919A
公开(公告)日：1995-11-07
申请号：US241185
申请日：1994-05-11
申请人： David P. Sinclair
发明人： David P. Sinclair
CPC分类号： C08G18/683
摘要： The invention relates to polyester-polyurethane hybrid resins containing halogenated aromatic polycarboxylate moieties to obtain flame retardance without significantly affect the preparation, processing and physical properties of the hybrid resins.
摘要翻译： 本发明涉及含有卤代芳族聚羧酸酯部分的聚酯 - 聚氨酯混合树脂，以获得阻燃性，而不显着影响杂化树脂的制备，加工和物理性能。
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9.再颁专利Crystalline polyamide composition from dicarboxylic acid mixture and diamine 失效来自二羧酸混合物和二胺的结晶聚酰胺组合物
公开(公告)号：USRE34447E
公开(公告)日：1993-11-16
申请号：US222160
申请日：1988-07-21
CPC分类号： C08G69/265 , B32B27/34 , C08K7/04
摘要： Novel crystalline polyamides having high heat deflection temperatures when filled are prepared from aliphatic diamines and either mixtures of terephthalic acid and adipic acid or mixtures of terephthalic acid, isophthalic acid and adipic acid. The mole ratio of aliphatic diamine to terephthalic acid, isophthalic acid, and adipic acid is in the range of about 100:65-95:25-0:35-5. The polyamides can be filled with about 10 to about 60 parts by weight of a filler. The mechanical properties of these polyamides are largely unaffected by absorbed water.
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公开(公告)号：US5081223A
公开(公告)日：1992-01-14
申请号：US485623
申请日：1990-02-27
IPC分类号： C08G69/26
CPC分类号： C08G69/265
摘要： Amorphous polyamide compositions are provided which are transparent and have improved glass transition and thermal decomposition temperatures. The polyamide compositions of the present invention can be prepared as the polymeric condensation product of a diamine component comprising neopentyldiamine, and a diacid component comprising an aromatic dicarboxylic acid.
摘要翻译： 提供无定形聚酰胺组合物，其是透明的并且具有改善的玻璃化转变和热分解温度。 本发明的聚酰胺组合物可以制备为包含新戊基二胺的二胺组分和包含芳族二羧酸的二酸组分的聚合缩合产物。
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