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1.发明授权公开(公告)号：US08398949B2
公开(公告)日：2013-03-19
申请号：US12208468
申请日：2008-09-11
申请人： Helmut Meyer , Heiko Hocke , Ralph Weber , Martin Schmid , Elmar Bramer-Weger , Matthias Voetz , Leslaw Mleczko , Reiner Rudolf , Aurel Wolf , Sigurd Buchholz
发明人： Helmut Meyer , Heiko Hocke , Ralph Weber , Martin Schmid , Elmar Bramer-Weger , Matthias Voetz , Leslaw Mleczko , Reiner Rudolf , Aurel Wolf , Sigurd Buchholz
CPC分类号： A61K33/44 , B01J21/185 , B01J23/8892 , B01J37/0036 , B01J37/03 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/30 , C01B2202/34 , C01B2202/36 , Y10T428/2982
摘要： A novel carbon nanotube powder containing carbon nanotubes which have a roll-like structure, also novel carbon nanotubes having a roll-like structure, novel processes for the production of the carbon nanotube powders and of the carbon nanotubes, and their use as an additive or substrate for various applications are described.
摘要翻译： 包含具有卷状结构的碳纳米管的新型碳纳米管粉末，还有具有卷状结构的新型碳纳米管，用于生产碳纳米管粉末和碳纳米管的新方法及其作为添加剂或 描述各种应用的基板。
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2.发明申请公开(公告)号：US20090124705A1
公开(公告)日：2009-05-14
申请号：US12208468
申请日：2008-09-11
申请人： Helmut Meyer , Heiko Hocke , Ralph Weber , Martin Schmid , Elmar Bramer-Weger , Matthias Voetz , Leslaw Mleczko , Reiner Rudolf , Aurel Wolf , Sigurd Buchholz
发明人： Helmut Meyer , Heiko Hocke , Ralph Weber , Martin Schmid , Elmar Bramer-Weger , Matthias Voetz , Leslaw Mleczko , Reiner Rudolf , Aurel Wolf , Sigurd Buchholz
CPC分类号： A61K33/44 , B01J21/185 , B01J23/8892 , B01J37/0036 , B01J37/03 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/30 , C01B2202/34 , C01B2202/36 , Y10T428/2982
摘要： A novel carbon nanotube powder containing carbon nanotubes which have a roll-like structure, also novel carbon nanotubes having a roll-like structure, novel processes for the production of the carbon nanotube powders and of the carbon nanotubes, and their use as an additive or substrate for various applications are described.
摘要翻译： 包含具有卷状结构的碳纳米管的新型碳纳米管粉末，还有具有卷状结构的新型碳纳米管，用于生产碳纳米管粉末和碳纳米管的新方法及其作为添加剂或 描述各种应用的基板。
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3.发明授权Catalyst for producing carbon nanotubes by means of the decomposition of gaseous carbon compounds on a heterogeneous catalyst 有权通过在非均相催化剂上分解气态碳化合物制备碳纳米管的催化剂公开(公告)号：US09409779B2
公开(公告)日：2016-08-09
申请号：US11719152
申请日：2005-11-08
申请人： Sigurd Buchholz , Daniel Gordon Duff , Volker Michele , Leslaw Mleczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
发明人： Sigurd Buchholz , Daniel Gordon Duff , Volker Michele , Leslaw Mleczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
IPC分类号： B01J21/10 , B01J23/889 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B31/02 , D01F9/10 , D01F9/127 , H01L51/00
CPC分类号： C01B31/0233 , B01J21/10 , B01J23/8892 , B01J23/8898 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/34 , C01B2202/36 , D01F9/127 , H01L51/0048 , H01L51/0052
摘要： The present invention relates to a process for the production of carbon nanotubes, in particular those having a diameter of 3-150 nm and an aspect ratio of length:diameter (L:D)>100, by decomposition of hydrocarbons on a heterogeneous catalyst which comprises Mn, Co, preferably also molybdenum, and an inert support material, and the catalyst and the carbon nanotubes themselves and the use thereof.
摘要翻译： 本发明涉及一种生产碳纳米管的方法，特别是直径为3-150nm，长径比（L：D）≥100的碳纳米管的方法，通过在非均相催化剂上分解烃， 包括Mn，Co，优选还有钼，以及惰性载体材料，以及催化剂和碳纳米管本身及其用途。
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公开(公告)号：US09050572B2
公开(公告)日：2015-06-09
申请号：US11735023
申请日：2007-04-13
申请人： Sigurd Buchholz , Maziar Kakhi , Volker Michele , Leslaw Mleczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
发明人： Sigurd Buchholz , Maziar Kakhi , Volker Michele , Leslaw Mleczko , Christian Münnich , Reiner Rudolf , Aurel Wolf
CPC分类号： B01J8/18 , B01J8/24 , B01J2208/00548 , B01J2208/00575 , B01J2208/00584 , B01J2208/00672 , B01J2208/00681 , B01J2208/00725 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/36
摘要： The present invention relates to a process for the production of carbon nanotubes by decomposition of hydrocarbons on a heterogeneous catalyst in a fluidized bed reactor, wherein the reactor can be operated batchwise or continuously, and in the case of continuous operation discharge can take place with sifting or without sifting.
摘要翻译： 本发明涉及通过在流化床反应器中在非均相催化剂上分解碳氢化合物来生产碳纳米管的方法，其中反应器可以间歇或连续地操作，并且在连续操作的情况下，可以通过筛分 或不筛选。
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公开(公告)号：US20110224357A1
公开(公告)日：2011-09-15
申请号：US12994116
申请日：2009-05-20
申请人： Torsten Ziser , Thomas Früh , Werner Obrecht , Reiner Rudolf , Sigurd Buchholz , Volker Michele , Leslaw Mleczko , Christian Münnich , Aurel Wolf , Daniel Gordon Duff
发明人： Torsten Ziser , Thomas Früh , Werner Obrecht , Reiner Rudolf , Sigurd Buchholz , Volker Michele , Leslaw Mleczko , Christian Münnich , Aurel Wolf , Daniel Gordon Duff
CPC分类号： C08J5/005 , B82Y30/00 , C08G18/672 , C08G18/673
摘要： The invention relates to a composition containing at least one microgel, at least one carbon nanotube and at least one organic medium. Said organic medium can be cross-linked or non cross-linked.
摘要翻译： 本发明涉及含有至少一种微凝胶，至少一种碳纳米管和至少一种有机介质的组合物。 所述有机介质可以是交联的或非交联的。
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6.发明申请公开(公告)号：US20090140215A1
公开(公告)日：2009-06-04
申请号：US11719152
申请日：2005-11-08
申请人： Sigurd Buchholz , Daniel Gordon Duff , Volker Michele , Leslaw Mleczko , Christian Munnich , Reiner Rudolf , Aurel Wolf
发明人： Sigurd Buchholz , Daniel Gordon Duff , Volker Michele , Leslaw Mleczko , Christian Munnich , Reiner Rudolf , Aurel Wolf
CPC分类号： C01B31/0233 , B01J21/10 , B01J23/8892 , B01J23/8898 , B82Y10/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/34 , C01B2202/36 , D01F9/127 , H01L51/0048 , H01L51/0052
摘要： The present invention relates to a process for the production of carbon nanotubes, in particular those having a diameter of 3-150 nm and an aspect ratio of length:diameter (L:D)>100, by decomposition of hydrocarbons on a heterogeneous catalyst which comprises Mn, Co, preferably also molybdenum, and an inert support material, and the catalyst and the carbon nanotubes themselves and the use thereof.
摘要翻译： 本发明涉及一种生产碳纳米管的方法，特别是直径为3-150nm，长径比（L：D）≥100的碳纳米管的方法，通过在非均相催化剂上分解烃， 包括Mn，Co，优选还有钼，以及惰性载体材料，以及催化剂和碳纳米管本身及其用途。
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公开(公告)号：US08592512B2
公开(公告)日：2013-11-26
申请号：US12994116
申请日：2009-05-20
申请人： Torsten Ziser , Thomas Früh , Werner Obrecht , Reiner Rudolf , Sigurd Buchholz , Volker Michele , Leslaw Mleczko , Christian Münnich , Aurel Wolf , Daniel Gordon Duff
发明人： Torsten Ziser , Thomas Früh , Werner Obrecht , Reiner Rudolf , Sigurd Buchholz , Volker Michele , Leslaw Mleczko , Christian Münnich , Aurel Wolf , Daniel Gordon Duff
CPC分类号： C08J5/005 , B82Y30/00 , C08G18/672 , C08G18/673
摘要： The invention relates to a composition containing at least one microgel, at least one carbon nanotube and at least one organic medium. Said organic medium can be cross-linked or non cross-linked.
摘要翻译： 本发明涉及含有至少一种微凝胶，至少一种碳纳米管和至少一种有机介质的组合物。 所述有机介质可以是交联的或非交联的。
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公开(公告)号：US20100276644A1
公开(公告)日：2010-11-04
申请号：US12743721
申请日：2008-12-09
申请人： Aurel Wolf , Volker Michele , Leslaw Mleczko , Jens Assmann , Sigurd Buchholz
发明人： Aurel Wolf , Volker Michele , Leslaw Mleczko , Jens Assmann , Sigurd Buchholz
CPC分类号： B01J37/031 , B01J23/002 , B01J23/8892 , B01J35/023 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01P2002/52 , C01P2004/04 , C01P2004/13 , C01P2004/54 , C01P2004/62 , C01P2004/64 , C01P2004/80 , B01J2523/22 , B01J2523/31 , B01J2523/72 , B01J2523/845
摘要： Process for producing nitrogen-doped carbon nanotubes (NCNTs) in a fluidized bed.
摘要翻译： 在流化床中生产氮掺杂碳纳米管（NCNTs）的方法。
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9.发明申请PROCESS FOR THE PREPARATION OF A CATALYST FOR THE PRODUCTION OF CARBON NANOTUBES 审中-公开制备用于生产碳纳米管的催化剂的方法公开(公告)号：US20090087372A1
公开(公告)日：2009-04-02
申请号：US12212678
申请日：2008-09-18
CPC分类号： B01J23/8892 , B01J21/185 , B01J23/002 , B01J23/74 , B01J23/88 , B01J37/0036 , B01J37/0045 , B01J37/009 , B01J37/14 , B01J37/18 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , D01F9/127 , D01F9/1271 , D01F9/1273 , Y02P20/582 , B01J2523/22 , B01J2523/31 , B01J2523/72 , B01J2523/845
摘要： A process for the preparation of a catalyst for the production of carbon nanotubes, the use of the catalyst for the production of carbon nanotubes, and the carbon nanotubes obtained by this production process. The catalyst is prepared on the basis of at least two metals from the group: cobalt, manganese, iron, nickel and molybdenum from soluble precursor compounds by spray drying or spray granulation of the precursor compounds dissolved in a solvent, and subsequent calcination.
摘要翻译： 制备碳纳米管制备催化剂的方法，用于生产碳纳米管的催化剂的使用以及通过该制备方法得到的碳纳米管。 基于来自可溶性前体化合物的钴，锰，铁，镍和钼中的至少两种金属，通过喷雾干燥或溶解在溶剂中的前体化合物的喷雾造粒，然后煅烧来制备催化剂。
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公开(公告)号：US20100247944A1
公开(公告)日：2010-09-30
申请号：US12679038
申请日：2008-09-09
申请人： Leslaw Mleczko , Juergen Kintrup , Ralph Weber , Andre Dammann , Rafael Warsitz , Aurel Wolf
发明人： Leslaw Mleczko , Juergen Kintrup , Ralph Weber , Andre Dammann , Rafael Warsitz , Aurel Wolf
CPC分类号： B22F1/025 , B01D67/0041 , B01D67/0076 , B01D67/0093 , B01D69/12 , B01D71/022 , B01D2323/225 , B01D2325/30 , B22F2998/10 , B22F2999/00 , C01B3/501 , C01B2203/0405 , Y10T428/12014 , Y10T428/12181 , Y10T428/12479 , B22F1/0081 , B22F3/02 , B22F3/17 , B22F3/15 , B22F9/24 , B22F9/26 , B22F2201/013
摘要： The invention relates to a metal matrix material made of a hydrogen-permeable metal 1 and a chemically stable metal 2 that is also hydrogen permeable, said matrix material having a structure comprised of a plurality of centers made of the metal 2 surrounded by the metal 1. The invention further relates to a method for the production of said matrix material, having the following steps: a. optionally pretreating the metal 1 and/or 2 b. coating metal 1 with a metal 2 to form a composite metal powder c. pressing the composite metal powder into the metal matrix material according to the invention in the form of a pressed body d. optionally deforming the pressed body thus obtained to form a molded body. The metal matrix material has a greater mechanical stability as compared to a conventionally coated metal film by virtue of a more homogeneous stress distribution during the change in volume of the metal phases as a result of hydrogen absorption and thermal expansion. At the same time, said material is considerably more chemically stable than conventional coated metal membranes. The metal matrix material is particularly suitable for producing hydrogen-permeable membranes that separate hydrogen from gas mixtures by selective diffusion.
摘要翻译： 本发明涉及由氢可渗透金属1和化学稳定的金属2制成的金属基质材料，其也是氢可渗透的，所述基体材料具有由金属2制成的多个中心构成的结构，金属2被金属1包围 本发明还涉及生产所述基质材料的方法，具有以下步骤：a。 任选地预处理金属1和/或2b。 用金属2涂覆金属1以形成复合金属粉末c。 将复合金属粉末按压制体形式按压本发明的金属基体材料d。 可选地使由此获得的压制体变形以形成模制体。 与常规涂覆的金属膜相比，由于氢吸收和热膨胀的结果，在金属相的体积变化期间由于更均匀的应力分布，金属基体材料具有更大的机械稳定性。 同时，所述材料比常规涂覆的金属膜更具有化学稳定性。 金属基质材料特别适用于生产通过选择性扩散将氢气与气体混合物分离的氢气渗透膜。
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