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    Solid support dirhodium catalyst compositions and methods for making and using same
    3.
    发明授权
    Solid support dirhodium catalyst compositions and methods for making and using same 有权
    固体支撑二铑催化剂组合物及其制备和使用方法

    公开(公告)号：US06962891B2

    公开(公告)日：2005-11-08

    申请号：US10229392

    申请日：2002-08-27

    申请人： Huw M. L. Davies ,  Tadamichi Nagashima

    发明人： Huw M. L. Davies ,  Tadamichi Nagashima

    IPC分类号： B01J23/46 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  C07F15/00 ,  B01J31/00

    CPC分类号： C07F15/008 ,  B01J23/464 ,  B01J31/1658 ,  B01J31/181 ,  B01J31/2239 ,  B01J31/2243 ,  B01J2231/325 ,  B01J2531/0219 ,  B01J2531/822 ,  C07B2200/11

    摘要： Disclosed are dirhodium catalyst compositions. One such dirhodium catalyst composition includes a dirhodium catalyst and a solid support. The dirhodium catalyst includes a Rh—Rh moiety and four bridging ligand moieties. The dirhodium catalyst and the solid support are bound together, but they are not covalently bound together via one or more of the bridging ligand moieties. Another such dirhodium catalyst composition includes a dirhodium tetracarboxylate catalyst and a solid support, and the dirhodium tetracarboxylate catalyst and the solid support are bound together. Yet another such dirhodium catalyst composition includes a dirhodium catalyst and a solid support, where the dirhodium catalyst includes a Rh—Rh moiety and where the dirhodium catalyst and the solid support are bound together via at least one of the rhodiums' axial positions. The compositions can be used in a number of reactions, including insertion reactions (e.g., C—H insertions, Si—H insertions, O—H insertions, and N—H insertions), cyclopropanation reactions, annulations (e.g., [3+2] annulations and [3+4] annulations), and ω,ω-diarylalkanoate synthesis. Methods for making the dirhodium catalyst compositions are also disclosed.

    摘要翻译： 公开了二铑催化剂组合物。 一种这样的二铑催化剂组合物包括二铑催化剂和固体载体。 铑催化剂包括Rh-Rh部分和四个桥连配体部分。 二铑催化剂和固体载体结合在一起，但它们不通过一个或多个桥连配体部分共价结合在一起。 另一种这样的二铑催化剂组合物包括四羧酸铑催化剂和固体载体，并且四羧酸铑催化剂和固体载体结合在一起。 另一种这样的铑催化剂组合物包括铑催化剂和固体载体，其中二铑催化剂包括Rh-Rh部分，并且其中铑催化剂和固体载体通过铑的至少一个轴向位置结合在一起。 组合物可以用于许多反应，包括插入反应（例如，CH插入，Si-H插入，OH插入和NH插入），环丙烷化反应，环状（例如[3 + 2]环和[3+ 4]环）和ω，ω-二芳基烷酸酯合成。 还公开了制备二铑催化剂组合物的方法。