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    Epoxy resin pre-advanced with carboxyl-containing polyester and advanced with bisphenol
    1.
    发明授权
    Epoxy resin pre-advanced with carboxyl-containing polyester and advanced with bisphenol 失效
    环氧树脂预先用含羧基的聚酯和先进的双酚

    公开(公告)号：US6103825A

    公开(公告)日：2000-08-15

    申请号：US70662

    申请日：1998-04-30

    申请人： Isabelle Frischinger ,  Jurgen Finter ,  Christine Poget ,  Philippe-Guilhaume Gottis

    发明人： Isabelle Frischinger ,  Jurgen Finter ,  Christine Poget ,  Philippe-Guilhaume Gottis

    IPC分类号： C08G59/24 ,  C08G59/06 ,  C08G59/12 ,  C08G59/42 ,  C08G59/62 ,  C09D133/00 ,  C09D163/00 ,  C08G59/14 ,  C08L33/02 ,  C08L63/02 ,  C08L67/03

    CPC分类号： C08G59/12 ,  C08G59/066 ,  C09D163/00

    摘要： Epoxy resins which are obtainable by a process in which, first of all(a) by reacting(A1) at least one substance selected from the substances of the formula (I) and of the formula (II): ##STR1## in which Alc is the radical of a diol which has been freed fromI ts hydroxyl groups and comprises 2 to 20 carbon atoms,Ac is the radical of a dicarboxylic acid which has been freed from its carboxyl groups and comprises 2 to 20 carbon atoms,[Ph] is the radical of a difunctional phenolic compound which has been freed from its phenolic hydroxyl groups and has 6 to 20 carbon atoms, andc is a number greater than 1 but not more than 2, with(A2) at least one liquid diglycidyl ether based on a first bisphenol compound in an amount chosen so that there are more than two equivalents of glycidyl groups of component (A2) for a total of one equivalent of carboxyl and phenolic hydroxyl groups of component (A1),a pre-advanced diglycidyl ether resin is formed in dispersion in the liquid diglycidyl ether of which there is at least one, and subsequently(b) the resin dispersion obtained in accordance with (a) is reacted with a phenol component comprising at least one bisphenol compound which is identical to or different from the first bisphenol compound, the amount of the phenol component being chosen so that in the mixture of the resin dispersion and the phenol component the glycidyl groups prior to the reaction are in a stoichiometric excess over the phenolic hydroxyl groups.

    摘要翻译： 环氧树脂可以通过以下方法获得：首先（a）通过（A1）选自式（I）和式（II）的物质中的至少一种物质：其中Alc是基团 的二醇，其已经脱离了羟基并且包含2至20个碳原子，Ac是已经脱离其羧基并且包含2至20个碳原子的二羧酸的基团，[Ph]是基团 的二官能酚类化合物，其已经脱离其酚羟基并且具有6至20个碳原子，c是大于1但不大于2的数，其中（A2）基于第一个（A2）的至少一种液体二缩水甘油醚 双酚化合物的量选择为使得组分（A2）的总共1当量的羧基和酚羟基具有多于2当量的缩水甘油基，组分（A1）的羧基和酚羟基的总数，预先的二缩水甘油醚树脂形成在 分散在液体中的二缩水甘油醚 h中至少有一个，随后（b）将根据（a）获得的树脂分散体与包含至少一种与第一双酚化合物相同或不同的双酚化合物的酚组分反应， 苯酚组分的选择使得在树脂分散体和酚组分的混合物中，反应前的缩水甘油基的化学计量过量超过酚羟基。

    Powder coating composition of epoxy resin mixture and carboxyl-containing polyester
    2.
    发明授权
    Powder coating composition of epoxy resin mixture and carboxyl-containing polyester 失效
    环氧树脂混合物和含羧基聚酯的粉末涂料组合物

    公开(公告)号：US6117952A

    公开(公告)日：2000-09-12

    申请号：US19636

    申请日：1998-02-06

    申请人： Jurgen Finter ,  Isabelle Frischinger ,  Christine Poget

    发明人： Jurgen Finter ,  Isabelle Frischinger ,  Christine Poget

    IPC分类号： C08G59/06 ,  C08G59/32 ,  C08G59/38 ,  C08G59/42 ,  C09D5/03 ,  C09D5/46 ,  C09D163/00 ,  C09D167/00 ,  C08L63/02 ,  C08L63/04 ,  C08L67/02

    CPC分类号： C09D167/00 ,  C08G59/38 ,  C09D163/00 ,  Y10S525/934

    摘要： A powder coating composition comprising(A) a solid epoxy resin mixture that comprises at least one epoxy resin component (A1) and one epoxy resin component (A2) and(B) a free-carboxyl-group-containing polyester in an amount sufficient for the full cure of the composition,in which the epoxy resin component (A1) consists of one or more epoxy resins and has overall a mean epoxy functionality that is greater than 2,wherein the epoxy resin component (A2) consists of one or more advanced epoxy resins each of which has a mean epoxy functionality of at least 1.2 but less than 1.95 and is the product of a reaction in which (i) at least one diglycidyl compound is simultaneously reacted with (ii) at least one bisphenol compound and (iii) at least one monophenol as starting materials, and the difference between the mean epoxy functionality of the epoxy resin mixture (A) and the mean epoxy functionality of component (A2) of the mixture is at least 0.05 but less than 0.8.

    摘要翻译： 一种粉末涂料组合物，其包含（A）固体环氧树脂混合物，其包含至少一种环氧树脂组分（A1）和一种环氧树脂组分（A2）和（B）含游离羧基的聚酯，其量足以 组合物的完全固化，其中环氧树脂组分（A1）由一种或多种环氧树脂组成并且具有大于2的平均环氧官能度，其中环氧树脂组分（A2）由一种或多种先进的 环氧树脂各自具有至少1.2但小于1.95的平均环氧官能度，并且是其中（i）至少一种二缩水甘油基化合物同时与（ii）至少一种双酚化合物反应的反应的产物，和（iii） ）至少一种单酚作为原料，并且环氧树脂混合物（A）的平均环氧官能度与组分（A2）的平均环氧官能度之间的差异为至少0.05但小于0.8。

    Solid epoxy resin compositions crosslinkable with UV rays
    3.
    发明授权
    Solid epoxy resin compositions crosslinkable with UV rays 失效
    用紫外线交联的固体环氧树脂组合物

    公开(公告)号：US6001428A

    公开(公告)日：1999-12-14

    申请号：US630738

    申请日：1996-04-10

    申请人： Jurgen Finter ,  Philippe-Guilhaume Gottis ,  Alfred Mockli

    发明人： Jurgen Finter ,  Philippe-Guilhaume Gottis ,  Alfred Mockli

    IPC分类号： C08G59/18 ,  C08G59/00 ,  C08G59/20 ,  C08G59/68 ,  C08L63/00 ,  C09D5/03 ,  C09D163/00 ,  B05D7/24

    CPC分类号： C08G59/68 ,  C08G59/687 ,  C09D163/00

    摘要： 1. A solid composition comprising(a) a solid oligomeric, cationically polymerisable polyglycidyl ether or polyglycidyl ester, a mixture of a solid oligomeric, cationically polymerisable polyglycidyl ether or polyglycidyl ester and a liquid or crystalline monomeric mono-, di- or polyepoxy resin, or a mixture of a solid oligomeric, cationically polymerisable polyglycidyl ether or polyglycidyl ester and a cyclic acetal, said oligomeric polyglycidyl ether or polyglycidyl ester and the mixtures containing the oligomeric polyglycidyl ether or polyglycidyl ester having a glass transition temperature (T.sub.G) higher than 35.degree. C.,(b) a multifunctional nucleophilic chain transfer agent,(c) 0.05 to 3% by weight, based on component (a), of a photoinitiator for the cationic polymerisation and, as optional components,(d) customary additives for powder coating compositions, which compositions are free from compounds containing a primary, secondary or tertiary nitrogen atom or contain such compounds only in an amount which at most is 50% of the amount of component (c), based on the molar concentration.

    摘要翻译： 1.一种固体组合物，其包含（a）固体低聚阳离子可聚合的聚缩水甘油醚或聚缩水甘油酯，固体低聚，可阳离子聚合的聚缩水甘油醚或多缩水甘油酯与液体或结晶单体单 - ，二 - 或聚环氧树脂的混合物， 或固体低聚阳离子聚合的聚缩水甘油醚或多缩水甘油酯与环状缩醛的混合物，所述低聚聚缩水甘油醚或多缩水甘油酯和含有玻璃化转变温度（TG）高于35℃的低聚聚缩水甘油醚或多缩水甘油酯的混合物 C.，（b）多功能亲核链转移剂，（c）基于组分（a）的0.05-3重量％的用于阳离子聚合的光引发剂，和作为任选组分，（d）粉末的常规添加剂 涂料组合物，该组合物不含含有伯，仲或叔氮原子或含有这些化合物的化合物 仅基于摩尔浓度，其量最多为组分（c）的量的50％。

    Carboxyl-containing polymer(s) with (2-oxo-1,3-dioxolan-4-yl)methyl groups-containing compound(s)
    4.
    发明授权
    Carboxyl-containing polymer(s) with (2-oxo-1,3-dioxolan-4-yl)methyl groups-containing compound(s) 失效
    含有（2-氧代-1,3-二氧戊环-4-基）甲基的化合物的含羧基的聚合物

    公开(公告)号：US6090891A

    公开(公告)日：2000-07-18

    申请号：US75639

    申请日：1998-05-11

    申请人： Isabelle Frischinger ,  Jacques-Alain Cotting ,  Jurgen Finter ,  Jacques Fran.cedilla.ois

    发明人： Isabelle Frischinger ,  Jacques-Alain Cotting ,  Jurgen Finter ,  Jacques Fran.cedilla.ois

    IPC分类号： C08G59/14 ,  C08G63/42 ,  C08G67/00 ,  C08L33/06 ,  C08L63/00 ,  C08L67/00 ,  C09D133/06 ,  C09D163/00 ,  C09D167/00 ,  C08L33/02 ,  C08L67/04 ,  C08L69/00

    CPC分类号： C09D167/00 ,  C08G59/1405 ,  C08L33/064 ,  C08L67/00 ,  C09D133/064 ,  C09D163/00 ,  C08L63/00

    摘要： Curable compositions, which comprise the following components:(A) a polymer component consisting of one or more than one of the following components:polymers based on acrylate monomers and/or methacrylate monomers containing free carboxyl groups, and carboxyl-terminated polyesters;(B) a crosslinker for component (A) selected from the group consisting of:(B1) one or more than one compound having a molecular weight of less than 800 and containing at least two (2-oxo-1,3-dioxolan-4-yl)methyl groups per molecule, and(B2) a mixture consisting of one or more than one compound having a molecular weight of less than 800 and containing at least two (2-oxo-1,3-dioxolan-4-yl)methyl groups per molecule, and of one or more than one epoxy resin, at least 60 percent of the total number of (2-oxo-1,3-dioxolan-4-yl)methyl groups and epoxy groups of the mixture being (2-oxo-1,3-dioxolan-4-yl)methyl groups;(C) a catalyst for accelerating the crosslinking reaction between the components (A) and (B), and(D) a solvent for the components (A), (B) and (C);the molar ratio of free carboxyl groups to the total number of (2-oxo-1,3-dioxolan-4-yl)methyl groups and epoxy groups in the composition being from 0.3:1 to 3:1,have particularly good storage stability and are therefore suitable for use in one-component form, for example as coating agents.

    摘要翻译： 可固化组合物，其包含以下组分：（A）由以下组分中的一种或多种组成的聚合物组分：基于丙烯酸酯单体和/或含有游离羧基的甲基丙烯酸酯单体的聚合物和羧基封端的聚酯; （B）组分（A）的交联剂，其选自：（B1）一种或多种分子量小于800的化合物，并且含有至少两个（2-氧代-1,3-二氧戊环 - （B2）由一种或多于一种分子量小于800的化合物组成的混合物，并含有至少两个（2-氧代-1,3-二氧戊环-4-基） ）甲基和一种或多于一种环氧树脂，（2-氧代-1,3-二氧戊环-4-基）甲基和环氧基的总数的至少60％为（ 2-氧代-1,3-二氧戊环-4-基）甲基; （C）用于促进组分（A）和（B）之间的交联反应的催化剂，和（D）组分（A），（B）和（C）的溶剂; 游离羧基与组合物中（2-氧代-1,3-二氧戊环-4-基）甲基和环氧基总数的摩尔比为0.3:1至3:1具有特别良好的储存稳定性 因此适用于单组分形式，例如作为涂层剂。

    EPOXY GROUP-TERMINATED POLYMERS, THE COMPOSITIONS THEREOF AND THE USE THEREOF AS IMPACT RESISTANCE MODIFIERS
    6.
    发明申请
    EPOXY GROUP-TERMINATED POLYMERS, THE COMPOSITIONS THEREOF AND THE USE THEREOF AS IMPACT RESISTANCE MODIFIERS 有权
    环氧基封端聚合物，其组合物及其作为抗冲击改性剂的用途

    公开(公告)号：US20100087567A1

    公开(公告)日：2010-04-08

    申请号：US12450091

    申请日：2008-03-20

    申请人： Jurgen Finter ,  Andreas Kramer

    发明人： Jurgen Finter ,  Andreas Kramer

    IPC分类号： C08L63/00 ,  C08G18/32

    CPC分类号： C08G18/6674 ,  C08G18/12 ,  C08G59/18 ,  C09J163/00 ,  C08G18/3218

    摘要： The present invention relates to epoxy group-terminated polymers of the formula (I). Said epoxy group-terminated polymers are suited extremely well as impact resistance modifiers, particularly in epoxy resin compostions. They are particularly suited for use in heat-curing epoxy resin adhesives. It has been found that such epoxy resin compostions not only have excellent mechanical properties and high glass transition temperatures, but also above all improved impact resistance properties, both at room temperature and at low temperatures.

    摘要翻译： 本发明涉及式（I）的环氧基封端的聚合物。 所述环氧基封端的聚合物非常适合作为抗冲击改性剂，特别是在环氧树脂组合物中。 它们特别适用于热固化环氧树脂粘合剂。 已经发现，这样的环氧树脂组合物不仅在室温和低温下都具有优异的机械性能和高的玻璃化转变温度，而且还具有优异的耐冲击性能。

    Electrically conductive thermoplastic polymer formulations and the use thereof
    8.
    发明授权
    Electrically conductive thermoplastic polymer formulations and the use thereof 失效
    导电热塑性聚合物配方及其用途

    公开(公告)号：US5482655A

    公开(公告)日：1996-01-09

    申请号：US075658

    申请日：1993-06-11

    申请人： Thomas Vogel ,  Jurgen Finter ,  Hartmut Bleier ,  Patrice Bujard

    发明人： Thomas Vogel ,  Jurgen Finter ,  Hartmut Bleier ,  Patrice Bujard

    IPC分类号： C08G61/10 ,  C08G61/12 ,  C08L41/00 ,  C08L65/00 ,  H01B1/12 ,  H01B1/00 ,  H01B1/06

    CPC分类号： C08G61/126 ,  C08L65/00 ,  H01B1/127 ,  H01G11/48 ,  H01G11/56 ,  C08G2261/1424 ,  C08G2261/3223 ,  Y02E60/13

    摘要： A formulation comprisinga) at least one polythiophene in oxidised polycationic form and containing structural repeating units of formula I ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other linear or branched C.sub.1 -C.sub.18 alkyl or C.sub.2 -C.sub.18 alkoxyalkyl; or are C.sub.3 -C.sub.8 cycloalkyl, phenyl or benzyl which are unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy or halogen; or R.sub.1 and R.sub.2, taken together, are linear C.sub.1 -C.sub.8 alkylene which is unsubstituted or substituted by C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, halogen, C.sub.3 -C.sub.8 cycloalkyl, phenyl, benzyl, C.sub.1 -C.sub.4 alkylphenyl, C.sub.1 -C.sub.4 alkoxyphenyl, halophenyl, C.sub.1 -C.sub.4 alkylbenzyl, C.sub.1 -C.sub.4 alkoxybenzyl or halobenzyl; andb) at least one polyanion of a film-forming thermoplastic polymer containing sulfated alcohol groups ##STR2## and/or sulfonatoalkylated alcohol groups ##STR3## in structural repeating units, wherein the group --(C.sub.n H.sub.2n)-- is linear or branched C.sub.2 -C.sub.12 alkylene which contains 2 to 5 carbon atoms in the carbon chain and is unsubstituted or substituted by C.sub.1 -C.sub.4 alkoxy. The formulation is an intrinsically electrically conductive themoformable material.

    摘要翻译： 一种制剂，其包含a）至少一种氧化聚阳离子形式的聚噻吩，并含有另一个直链或支链C 1 -C 18烷基或C 2 -C 18烷氧基烷基的结构式I重复单元; 或未取代或被C 1 -C 6烷基，C 1 -C 6烷氧基或卤素取代的C 3 -C 8环烷基，苯基或苄基; 或者R 1和R 2一起是未被取代或被C 1 -C 6烷基，C 1 -C 6烷氧基，卤素，C 3 -C 8环烷基，苯基，苄基，C 1 -C 4烷基苯基，C 1 -C 4烷氧基苯基，卤代苯基，C 1 -C 4烷基苄基 ，C 1 -C 4烷氧基苄基或卤代苄基; 和b）在结构重复单元中含有硫酸化醇基团和/或磺化烷基化醇基团的成膜热塑性聚合物的至少一种聚阴离子，其中 - （C n H 2n） - 为直链或支链C 2 -C 12亚烷基 其在碳链中含有2至5个碳原子且未被取代或被C 1 -C 4烷氧基取代。 制剂是本征导电的可变形材料。

    Photochromic benzothioxanthone oxides, process for their preparation and the use thereof
    10.
    发明授权
    Photochromic benzothioxanthone oxides, process for their preparation and the use thereof 失效
    光致变色二氧化硅氧化物，其制备方法及其用途

    公开(公告)号：US5177218A

    公开(公告)日：1993-01-05

    申请号：US814945

    申请日：1991-12-30

    申请人： Walter Fischer ,  Jurgen Finter ,  Heinz Spahni

    发明人： Walter Fischer ,  Jurgen Finter ,  Heinz Spahni

    IPC分类号： C07D335/16 ,  C07D335/04 ,  C09B57/14 ,  C09K9/00 ,  C09K9/02 ,  G03C1/73 ,  G03F7/09 ,  G03F7/095 ,  G11B7/244

    CPC分类号： G11B7/244 ,  C07D335/04 ,  C09B57/14 ,  G03C1/73 ,  G03F7/091 ,  G03F7/0952 ,  G11B7/2531 ,  G11B7/2533

    摘要： Compounds of formula I or III or mixtures thereof ##STR1## wherein R is unsubstituted C.sub.6 -C.sub.14 aryl or C.sub.6 -C.sub.14 aryl which is substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, C.sub.1 -C.sub.12 alkylthio, phenyl, benzyl, --CN, --CF.sub.3, halogen or --COOR.sub.3, x is 1 or 2, and R.sub.1 is H, linear or branched C.sub.1 -C.sub.12 alkyl, C.sub.2 -C.sub.12 alkenyl or C.sub.2 -C.sub.12 alkynyl, C.sub.7 -C.sub.16 aralkyl, C.sub.8 -C.sub.16 alkaralkyl, --CH.sub.2 COOR.sub.3 or C.sub.1 -C.sub.12 acyl, wherein R.sub.3 is H, C.sub.1 -C.sub.18 alkyl, cyclohexyl, cyclopentyl, phenyl, C.sub.1 -C.sub.12 alkylphenyl, benzyl or C.sub.1 -C.sub.12 alkylbenzyl, are reversible photochromic systems which can be used for contrast formation, light absorption or for the reversible optical storage of information.

    摘要翻译： 式I或III的化合物或其混合物其中R是被C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 12烷硫基，苯基，苄基，-CN - 取代的未取代的C 6 -C 14芳基或C 6 -C 14芳基， CF 3，卤素或-COOR 3，x是1或2，并且R 1是H，直链或支链C 1 -C 12烷基，C 2 -C 12烯基或C 2 -C 12炔基，C 7 -C 16芳烷基，C 8 -C 16烷基烷基，-CH 2 COOR 3或C 1 -C 12酰基，其中R 3 是H，C 1 -C 18烷基，环己基，环戊基，苯基，C 1 -C 12烷基苯基，苄基或C 1 -C 12烷基苄基，是可用于对比形成，光吸收或信息的可逆光学存储的可逆光致变色体系。