公开(公告)号：US10300461B2

公开(公告)日：2019-05-28

申请号：US15113279

申请日：2015-01-23

Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY

Inventor： Juergen Bauer ,  Ralf Dotzel ,  Joerg Walter Jodlauk ,  Rainer Leppelt ,  Joerg Werner Muench

IPC: B01D53/94 ,  B01J21/08 ,  B01J21/16 ,  B01J23/30 ,  B01J29/06 ,  B01J35/04 ,  B01J35/06 ,  B01J23/847 ,  B01J23/22 ,  B01J29/00 ,  B01J29/04 ,  B01J29/08 ,  B01J29/16 ,  B01J29/40 ,  B01J29/48 ,  B01J29/70 ,  B01J29/78 ,  B01J29/83 ,  B01J29/85 ,  B01J37/00 ,  C04B38/08 ,  C04B111/00

Abstract: In order to specify a catalytic converter, especially SCR catalytic converter, with maximum catalytic activity, this catalytic converter has at least one catalytically active component and additionally at least one porous inorganic filler component having meso- or macroporosity. The organic porous filler component has a proportion of about 5 to 50% by weight. More particularly, a diatomaceous earth or a pillared clay material is used as the porous inorganic filler component.

公开(公告)号：US09987619B2

公开(公告)日：2018-06-05

申请号：US14404763

申请日：2013-05-31

Applicant: Johnson Matthey Public Limited Company

Inventor： Kaneshalingam Arulraj ,  Ralf Dotzel ,  Rainer Leppelt ,  Jorg Werner Muench ,  Alexandra Tsami Goodwin ,  Gudmund Smedler

IPC: B01J23/847 ,  B01D53/94 ,  B01J37/04 ,  B01J37/08 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02 ,  B01J21/06 ,  B01J21/08 ,  B01J21/16 ,  B01J23/30 ,  B01J27/24 ,  B01J35/00 ,  B01J23/00 ,  F01N3/20 ,  F01N3/035

CPC classification number: B01J23/8472 ,  B01D53/9418 ,  B01D53/9431 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2047 ,  B01D2255/206 ,  B01D2255/2068 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2255/20792 ,  B01D2255/209 ,  B01D2255/2092 ,  B01D2255/2096 ,  B01D2255/30 ,  B01D2255/9155 ,  B01D2257/406 ,  B01J21/063 ,  B01J21/08 ,  B01J21/16 ,  B01J23/002 ,  B01J23/30 ,  B01J27/24 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/04 ,  B01J37/08 ,  F01N3/035 ,  F01N3/2066 ,  F01N2330/06 ,  Y02T10/24

Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.

公开(公告)号：US08815190B2

公开(公告)日：2014-08-26

申请号：US14077549

申请日：2013-11-12

Applicant: Johnson Matthey Public Limited Company

Inventor： Ralf Dotzel ,  Rainer Leppelt ,  Jörg Werner Münch ,  Hubert Schedel

IPC: B01D46/00 ,  B01D53/94 ,  F01N3/021 ,  F01N3/035 ,  B01J29/00 ,  B01J29/04 ,  B01J29/072 ,  B01J29/78 ,  C04B35/82 ,  B01J35/04 ,  B01J23/83 ,  B01J23/30 ,  C04B35/50 ,  C04B38/00 ,  C04B35/634 ,  B01J29/74 ,  C04B35/80 ,  C04B35/636 ,  B01J23/888 ,  B01J37/00 ,  C04B111/00

CPC classification number: B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

Abstract: A wall-flow filter comprises a catalyst for converting oxides of nitrogen in the presence of a reducing agent, which wall-flow filter comprising an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilized ceria, which catalyst comprising at least one metal, wherein: the at least one metal is present throughout the extruded solid body alone or in combination with: is also present in a higher concentration at a surface of the extruded solid body; is also carried in one or more coating layer(s) on a surface of the extruded solid body; or both.

Abstract translation: 壁流式过滤器包括用于在还原剂存在下转化氮氧化物的催化剂，所述壁流式过滤器包括挤出固体，其包含：10-95重量％的至少一种粘合剂/基质组分; 5-90重量％的沸石分子筛，非沸石分子筛或其任何两种或更多种的混合物; 和0-80重量％的任选稳定的二氧化铈，所述催化剂包含至少一种金属，其中：所述至少一种金属单独存在于整个挤出的固体中或与以下组合一起存在：在 挤出的固体; 也被承载在挤出的固体的表面上的一个或多个涂层中; 或两者。

公开(公告)号：US11225895B2

公开(公告)日：2022-01-18

申请号：US16361450

申请日：2019-03-22

Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY

Inventor： Kaneshalingam Arulraj ,  Guy Richard Chandler ,  Rainer Leppelt ,  Andrew Newman

IPC: B01J21/04 ,  B01J21/06 ,  B01J21/08 ,  B01J21/12 ,  B01J23/10 ,  B01J23/22 ,  B01J23/40 ,  B01J23/42 ,  B01J23/44 ,  B01J23/56 ,  B01J23/64 ,  B01J23/72 ,  B01J23/745 ,  B01J23/89 ,  B01J29/46 ,  B01J29/76 ,  B01J35/00 ,  B01J35/04 ,  B01J37/00 ,  B01J37/02 ,  B01J37/03 ,  B01J37/08 ,  F01N3/035 ,  F01N3/10 ,  F01N3/20 ,  F01N3/28 ,  B01D53/94

Abstract: A catalyst article for treating a flow of a combustion exhaust gas comprises: a catalytically active substrate comprising one or more channels extending along an axial length thereof through which, in use, a combustion exhaust gas flows, the one or more channels having a first surface for contacting a flow of combustion exhaust gas; wherein the substrate is formed of an extruded vanadium-containing SCR catalyst material, wherein a first layer is disposed on at least a portion of the first surface, wherein the first layer comprises a washcoat of an ammonia slip catalyst composition comprising one or more platinum group metals supported on a particulate metal oxide support material, and wherein a layer comprising a washcoat of SCR catalyst composition is disposed on a surface in the one or more channels, wherein at least the portion of the first surface on which the first layer is disposed comprises a compound of copper, iron, cerium or zirconium or a mixture of any two or more thereof.

公开(公告)号：US20200306734A1

公开(公告)日：2020-10-01

申请号：US16811819

申请日：2020-03-06

Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY

Inventor： Zuharia Arshad ,  Kaneshalingam Arulraj ,  Guy Chandler ,  Rainer Leppelt ,  Andrew Newman ,  Paul Phillips ,  Oliver Rowe ,  Christopher Smith ,  Nicholas Spencer ,  Isabel Tingay ,  Rob Walker ,  Oliver Hemming ,  Agnes Raj

IPC: B01J23/887 ,  B01J37/02 ,  B01J6/00 ,  F01N3/20

Abstract: Methods and compositions related to a selective catalytic reduction catalyst comprising iron and vanadium, wherein the vanadium is present as (1) one or more vanadium oxides, and (2) metal vanadate of the form FexMyVO4 where x=0.2 to 1 and y=1−x, and where M comprises one or more non-Fe metals when y>0.

公开(公告)号：US20150190787A1

公开(公告)日：2015-07-09

申请号：US14404763

申请日：2013-05-31

Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY

Inventor： Kaneshalingam Arulraj ,  Ralf Dotzel ,  Rainer Leppelt ,  Jorg Werner Muench ,  Alexandra Tsami Goodwin ,  Gudmund Smedler

IPC: B01J23/847 ,  B01J21/06 ,  B01J27/24 ,  B01J21/16 ,  B01J21/08 ,  B01D53/94 ,  B01J23/30

CPC classification number: B01J23/8472 ,  B01D53/9418 ,  B01D53/9431 ,  B01D2255/2042 ,  B01D2255/2045 ,  B01D2255/2047 ,  B01D2255/206 ,  B01D2255/2068 ,  B01D2255/20707 ,  B01D2255/20723 ,  B01D2255/20738 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2255/20792 ,  B01D2255/209 ,  B01D2255/2092 ,  B01D2255/2096 ,  B01D2255/30 ,  B01D2255/9155 ,  B01D2257/406 ,  B01J21/063 ,  B01J21/08 ,  B01J21/16 ,  B01J23/002 ,  B01J23/30 ,  B01J27/24 ,  B01J35/0006 ,  B01J35/04 ,  B01J37/0009 ,  B01J37/0215 ,  B01J37/04 ,  B01J37/08 ,  F01N3/035 ,  F01N3/2066 ,  F01N2330/06 ,  Y02T10/24

Abstract: A filter incorporates a catalyst for the Selective Catalytic Reduction (SCR) of NOx gases and removal of particulate matter from the exhaust gas of a lean burn combustion engine, wherein the catalyst includes a vanadate component having an alkaline earth metal, a transition metal, a rare earth metal, or combinations thereof. The vanadate component may be iron vanadate. The filter includes a supported vanadate component disposed on a wall-flow filter. The method of making the filter includes applying an aqueous mixture of the supported vanadate component as a washcoat on the wall-flow filter or extruding a composition containing the supported vanadate component. The method of treating exhaust gases from an engine includes contacting the exhaust gas with the catalyst including the vanadate component.

Abstract translation: 一种过滤器包括用于NOx气体的选择性催化还原（SCR）的催化剂和从贫燃燃烧发动机的废气中除去颗粒物质，其中催化剂包括具有碱土金属的钒酸盐组分，过渡金属， 稀土金属或其组合。 钒酸盐组分可以是铁钒酸盐。 过滤器包括设置在壁流过滤器上的负载的钒酸盐组分。 制造过滤器的方法包括将负载的钒酸盐组分的水性混合物作为修补基面涂层施加在壁流过滤器上或挤出含有负载的钒酸盐组分的组合物。 处理来自发动机的废气的方法包括使废气与包含钒酸盐成分的催化剂接触。

公开(公告)号：US10252252B2

公开(公告)日：2019-04-09

申请号：US14422074

申请日：2013-08-16

Applicant: Johnson Matthey Public Limited Company

Inventor： Juergen Bauer ,  Ralf Dotzel ,  Joerg Jodlauk ,  Rainer Leppelt ,  Joerg Muench ,  Irene Piras ,  Gudmund Smedler

IPC: B01J29/88 ,  B01J29/076 ,  B01J37/02 ,  B01J37/04 ,  B01J23/847 ,  B01J35/00 ,  B01J29/46 ,  B01J29/65 ,  B01J29/68 ,  B01J29/70 ,  B01J29/76 ,  B01J37/00 ,  B01D53/94 ,  B01J23/22 ,  B01J23/30 ,  B01J29/48 ,  B01J29/69 ,  B01J29/78 ,  B01J35/04 ,  B01J23/40 ,  B01J29/40

Abstract: Provided is a catalyst composition for treating exhaust gas comprising a blend of a first component and second component, wherein the first component is an aluminosilicate or ferrosilicate molecular sieve component wherein the molecular sieve is either in H+ form or is ion exchanged with one or more transition metals, and the second component is a vanadium oxide supported on a metal oxide support selected from alumina, titania, zirconia, cella, silica, and combinations thereof. Also provided are methods, systems, and catalytic articles incorporating or utilizing such catalyst blends.

公开(公告)号：US09782721B2

公开(公告)日：2017-10-10

申请号：US15009978

申请日：2016-01-29

Applicant: Johnson Matthey Public Limited Company

Inventor： Rodney Foo ,  Rainer Leppelt ,  Joerg Werner Muench ,  Ralf Dotzel ,  Maria Brandmair

IPC: B01D53/86 ,  B01D53/90 ,  B01D53/94 ,  F01N3/20

CPC classification number: B01D53/8609 ,  B01D53/8625 ,  B01D53/8671 ,  B01D53/8696 ,  B01D53/90 ,  B01D53/9409 ,  B01D2251/2067 ,  B01D2251/40 ,  B01D2255/20723 ,  B01D2255/9155 ,  B01D2257/404 ,  B01D2258/0283 ,  F01N3/208 ,  F01N2570/04 ,  F01N2610/01 ,  F01N2610/02 ,  F01N2900/1404 ,  F01N2900/1602 ,  Y02T10/24

Abstract: Systems and methods of continuous operation of a urea-SCR system at low temperatures (200-350° C.) in the presence of high SOx containing flue gas are described. The methods comprise introducing a solution of urea and an NO2 forming compound, preferably an alkaline earth metal nitrate, into an exhaust stream before the exhaust stream contacts an SCR catalyst.

公开(公告)号：US09040003B2

公开(公告)日：2015-05-26

申请号：US14079210

申请日：2013-11-13

Applicant: Johnson Matthey Public Limited Company

Inventor： Paul Joseph Andersen ,  Ralf Dotzel ,  Kwangmo Koo ,  Rainer Leppelt ,  Jörg Werner Münch ,  Jeffery Scott Rieck ,  Hubert Schedel ,  Duncan John William Winterborn ,  Todd Howard Ballinger ,  Julian Peter Cox

IPC: B01D53/94 ,  B01J29/00 ,  F01N3/28 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J35/04 ,  B01J37/00 ,  C04B35/50 ,  C04B35/634 ,  C04B35/636 ,  C04B35/80 ,  C04B35/82 ,  C04B38/00 ,  B01J29/74 ,  B01J29/78 ,  F01N3/035 ,  C04B111/00

CPC classification number: B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

Abstract: A three way catalyst includes an extruded solid body having by weight: 10-100% of at least one binder/matrix component; 5-90% of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% optionally stabilised ceria. The catalyst also includes at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on the body surface; (ii) at least one metal is present throughout the body and at least one precious metal is carried in one or more coating layer(s) on a body surface; or (iii) at least one metal is present throughout the body, is present in a higher concentration at a body surface, and at least one precious metal is carried in one or more coating layer(s) on the body surface.

Abstract translation: 三元催化剂包括具有重量的挤出固体：10-100％的至少一种粘合剂/基质组分; 5-90％的沸石分子筛，非沸石分子筛或其任何两种或更多种的混合物; 和0-80％的任选稳定的二氧化铈。 所述催化剂还包括至少一种贵金属和任选的至少一种非贵金属，其中：（i）所述至少一种贵金属承载在所述体表面上的一个或多个涂层中; （ii）至少一种金属存在于整个身体中，并且至少一种贵金属被携带在身体表面上的一个或多个涂层中; 或（iii）至少一种金属存在于整个身体中，在身体表面以更高的浓度存在，并且至少一种贵金属被携带在身体表面上的一个或多个涂层中。

公开(公告)号：US20140065042A1

公开(公告)日：2014-03-06

申请号：US14079210

申请日：2013-11-13

Applicant: Johnson Matthey Public Limited Company

Inventor： Paul Joseph Andersen ,  Ralf Dotzel ,  Kwangmo Koo ,  Rainer Leppelt ,  Jörg Werner Münch ,  Jeffery Scott Rieck ,  Hubert Schedel ,  Duncan John William Winterborn ,  Todd Howard Ballinger ,  Julian Peter Cox

IPC: B01J29/78 ,  B01D53/94 ,  B01J29/74

CPC classification number: B01D53/9413 ,  B01D53/9418 ,  B01D53/945 ,  B01D2255/20738 ,  B01D2255/20776 ,  B01D2255/9155 ,  B01J23/30 ,  B01J23/83 ,  B01J23/888 ,  B01J29/7415 ,  B01J29/7815 ,  B01J35/04 ,  B01J37/0009 ,  C04B35/50 ,  C04B35/63488 ,  C04B35/6365 ,  C04B35/803 ,  C04B35/82 ,  C04B38/0006 ,  C04B2111/00793 ,  C04B2111/0081 ,  C04B2235/3218 ,  C04B2235/322 ,  C04B2235/3229 ,  C04B2235/6021 ,  C04B2235/606 ,  F01N3/035 ,  Y02A50/2325 ,  Y02T10/22 ,  Y02T10/24 ,  Y10S55/30 ,  Y10T29/49345 ,  C04B38/0074

Abstract: A three way catalyst includes an extruded solid body having by weight: 10-100% of at least one binder/matrix component; 5-90% of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% optionally stabilised ceria. The catalyst also includes at least one precious metal and optionally at least one non-precious metal, wherein: (i) the at least one precious metal is carried in one or more coating layer(s) on the body surface; (ii) at least one metal is present throughout the body and at least one precious metal is carried in one or more coating layer(s) on a body surface; or (iii) at least one metal is present throughout the body, is present in a higher concentration at a body surface, and at least one precious metal is carried in one or more coating layer(s) on the body surface.

Abstract translation: 三元催化剂包括具有重量的挤出固体：10-100％的至少一种粘合剂/基质组分; 5-90％的沸石分子筛，非沸石分子筛或其任何两种或更多种的混合物; 和0-80％的任选稳定的二氧化铈。 所述催化剂还包括至少一种贵金属和任选的至少一种非贵金属，其中：（i）所述至少一种贵金属承载在所述体表面上的一个或多个涂层中; （ii）至少一种金属存在于整个身体中，并且至少一种贵金属被携带在身体表面上的一个或多个涂层中; 或（iii）至少一种金属存在于整个身体中，在身体表面以更高的浓度存在，并且至少一种贵金属被携带在身体表面上的一个或多个涂层中。