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公开(公告)号：US5891972A
公开(公告)日：1999-04-06
申请号：US897572
申请日：1997-07-21
IPC分类号： C09K8/24 , B01D61/04 , B01D61/16 , B01D65/06 , B01D65/08 , B01F17/52 , C02F5/10 , C08F2/00 , C08F2/10 , C08F2/38 , C08F2/44 , C08F4/30 , C08F20/00 , C08F20/06 , C08F22/00 , C08L33/02 , C09D133/00 , C09K8/00 , C09K8/02 , C09K8/035 , C11D3/37
CPC分类号： C11D3/3757 , B01D61/025 , B01D61/145 , B01D61/16 , B01D65/02 , B01D65/08 , C08F2/10 , C08F2/38 , C11D3/3746 , B01D2311/04 , B01D2321/168 , C02F5/10
摘要： Homopolymers and/or copolymers are manufactured by polymerizing ethylenically monounsaturated monomer(s) in an aqueous solution in a reaction vessel containing compounds which contain a phosphorus atom of degree of oxidation less than 5, phosphorous compounds being introduced in amounts of 0.005-0.49 gram-atom phosphorus per mol of unsaturation in said ethylenically unsaturated monomer(s) in the presence of hydrogen peroxide and in the absence of any agent(s) which decomposes hydrogen peroxide thereby forming free radicals, in the absence of any other generator of free radicals, and in the absence of any per salt and/or any other transfer agent.
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2.发明授权Method of manufacturing water-soluble polymers, polymers manufactured thereby, and uses of said polymers 失效制造水溶性聚合物的方法，由此制备的聚合物以及所述聚合物的用途公开(公告)号：US06184321B2
公开(公告)日：2001-02-06
申请号：US09348666
申请日：1999-07-06
IPC分类号： C08F238
CPC分类号： C11D3/3757 , B01D61/025 , B01D61/145 , B01D61/16 , B01D65/02 , B01D65/08 , B01D2311/04 , B01D2321/168 , C02F5/10 , C08F2/10 , C08F2/38 , C11D3/3746
摘要： Homopolymers and/or copolymers are manufactured by polymerizing ethylenically monounsaturated monomer(s) in an aqueous solution in a reaction vessel containing compounds which contain a phosphorus atom of degree of oxidation less than 5, phosphorous compounds being introduced in amounts of 0.005-0.49 gram-atom phosphorus per mol of unsaturation in said ethylenically unsaturated monomer(s) in the presence of hydrogen peroxide and in the absence of any agent(s) which decomposes hydrogen peroxide thereby forming free radicals, in the absence of any other generator of free radicals, and in the absence of any per salt and/or any other transfer agent.
摘要翻译： 均聚物和/或共聚物通过在含有氧化度小于5的磷原子的化合物的反应容器中的水溶液中聚合烯属单不饱和单体来制备，磷化合物的引入量为0.005-0.49克， 在过氧化氢存在下，在不存在分解过氧化氢，从而形成自由基的任何试剂的情况下，在不存在任何其它自由基产生剂的情况下，所述烯键式不饱和单体中的不饱和键的摩尔数为原子磷， 并且在不存在任何盐和/或任何其它转移剂的情况下。
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3.发明授权Method of manufacturing water-soluble polymers, polymers manufactured thereby, and uses of said polymers 失效制造水溶性聚合物的方法，由此制备的聚合物以及所述聚合物的用途
公开(公告)号：US6063884A
公开(公告)日：2000-05-16
申请号：US219887
申请日：1998-12-24
IPC分类号： C09K8/24 , B01D61/04 , B01D61/16 , B01D65/06 , B01D65/08 , B01F17/52 , C02F5/10 , C08F2/00 , C08F2/10 , C08F2/38 , C08F2/44 , C08F4/30 , C08F20/00 , C08F20/06 , C08F22/00 , C08L33/02 , C09D133/00 , C09K8/00 , C09K8/02 , C09K8/035 , C11D3/37
CPC分类号： C11D3/3757 , B01D61/025 , B01D61/145 , B01D61/16 , B01D65/02 , B01D65/08 , C08F2/10 , C08F2/38 , C11D3/3746 , B01D2311/04 , B01D2321/168 , C02F5/10
摘要： Homopolymers and/or copolymers are manufactured by polymerizing ethylenically monounsaturated monomer(s) in an aqueous solution in a reaction vessel containing compounds which contain a phosphorus atom of degree of oxidation less than 5, phosphorous compounds being introduced in amounts of 0.005-0.49 gram-atom phosphorus per mol of unsaturation in said ethylenically unsaturated monomer(s) in the presence of hydrogen peroxide and in the absence of any agent(s) which decomposes hydrogen peroxide thereby forming free radicals, in the absence of any other generator of free radicals, and in the absence of any per salt and/or any other transfer agent.
摘要翻译： 均聚物和/或共聚物通过在含有氧化度小于5的磷原子的化合物的反应容器中的水溶液中聚合烯属单不饱和单体来制备，磷化合物的引入量为0.005-0.49克， 在过氧化氢存在下，在不存在分解过氧化氢，从而形成自由基的任何试剂的情况下，在不存在任何其它自由基产生剂的情况下，所述烯键式不饱和单体中的不饱和键的摩尔数为原子磷， 并且在不存在任何盐和/或任何其它转移剂的情况下。
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4.发明授权Copolymer dispersants for providing improved water resistance to filled and/or pigmented films 失效用于为填充和/或着色膜提供改善的耐水性的共聚物分散剂
公开(公告)号：US5905110A
公开(公告)日：1999-05-18
申请号：US628112
申请日：1996-04-09
CPC分类号： C09D5/027
摘要： Copolymer dispersants for use in an aqueous emulsion containing fillers pigments or both where the copolymer has the formula (I)--(A).sub.a --(B).sub.b --(C).sub.c -- (I)whereinA represents units resulting from acrylic or methacrylic acid monomers,B represents units resulting from styrene monomers or a derivative thereof,C represents units resulting from C.sub.1 -C.sub.4 alkyl acrylate or methacrylate monomers,a, b and c represent the percentages by weight of A, B and C, respectively with respect to total weight of the monomers,wherein the copolymer yields a homogeneous solution which is clear to cloudy in a medium of neutral or alkaline pH and wherein the copolymer has a specific viscosity of less than or equal to 15, which imparts increased water resistance to dry or drying films made from aqeuous emulsion compositions containing the copolymer dispersant. The resulting aqueous compositions are useful as textured coatings, coatings, aqueous paints and coating compositions.
摘要翻译： 共聚物分散剂，用于含有填料颜料或两者的水性乳液，其中共聚物具有式（I） - （A）a-（B）b-（C）c-（I），其中A表示由丙烯酸或甲基丙烯酸 酸单体，B表示由苯乙烯单体或其衍生物得到的单元，C表示由C1-C4烷基丙烯酸酯或甲基丙烯酸酯单体得到的单元，a，b和c分别表示A，B和C的重量百分比，相对于 单体的总重量，其中共聚物产生均匀的溶液，其在中性或碱性pH的介质中清澈至浑浊，并且其中所述共聚物的比粘度小于或等于15，这赋予了耐干燥性或耐水性的增加的耐水性 由含有共聚物分散剂的均匀乳液组合物制成的干燥膜。 所得含水组合物可用作织构涂层，涂层，水性涂料和涂料组合物。
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公开(公告)号：US5569702A
公开(公告)日：1996-10-29
申请号：US383991
申请日：1995-02-06
CPC分类号： C08K9/08 , C09C1/021 , C09C3/041 , C09D17/004 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/22
摘要： A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed.A grinding agent composed of polymers and/or copolymers having a specific viscosity of between 0.3 and 0.8 and obtained by treatment, using one or several solvents, of a polymer and/or copolymer resulting from polymerization and/or copolymerization of acrylic and/or vinyl monomers comprising acid groups whose active acid sites are partially or completely neutralized to a degree of neutralization of 40 to 60%, including terminals, of the active acid sites using a neutralizing agent containing magnesium ions, and a degree of neutralization reaching 60% using a neutralizing agent containing sodium ions is disclosed.A procedure for grinding in an aqueous suspension using said agent, as well as aqueous suspensions produced using said procedure and their applications to the fields of weight fillers, paper coating, paints, and plastics is also disclosed.
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6.发明授权Method for the controlled radical polymerisation of acrylic acid and the salts thereof, polymers thus obtained and applications thereof 失效用于丙烯酸及其盐的受控自由基聚合的方法，由此获得的聚合物及其应用公开(公告)号：US07462676B2
公开(公告)日：2008-12-09
申请号：US10522340
申请日：2003-07-24
申请人： Jean-Marc Suau , Jean-Bernard Egraz
发明人： Jean-Marc Suau , Jean-Bernard Egraz
IPC分类号： C08F20/06
CPC分类号： C08F2/38
摘要： The present invention concerns a process for controlled radical polymerisation of acrylic acid and its salts in a reactive medium constituted solely of water.The invention also concerns homopolymers and copolymers of acrylic acid obtained by the polymerisation process.Finally, the invention concerns the use of the said homopolymers and copolymers of acrylic acid in fields of industry such as the paper field and in particular the coating of paper and the mass-filling of paper, the oil field, or the fields of paint, water treatment, detergency, ceramics, cements or hydraulic binders, public works, inks and varnishes, sizing of textiles or the finishing of leather.
摘要翻译： 本发明涉及丙烯酸及其盐在仅由水构成的反应性介质中受控自由基聚合的方法。 本发明还涉及通过聚合方法获得的丙烯酸的均聚物和共聚物。 最后，本发明涉及所述丙烯酸均聚物和共聚物在诸如造纸领域的工业领域中的应用，特别是纸的涂布和纸的大量填充，油田或油漆领域的使用， 水处理，去污力，陶瓷，水泥或水硬性粘合剂，公共工程，油墨和清漆，纺织品的尺寸或皮革的整理。
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7.发明申请Method for obtaining water-soluble polymers, resulting polymers and uses thereof 审中-公开获得水溶性聚合物，所得聚合物及其用途的方法公开(公告)号：US20050159568A1
公开(公告)日：2005-07-21
申请号：US11080429
申请日：2005-03-16
CPC分类号： C08F2/10
摘要： A method of obtaining homopolymers and/or copolymers in aqueous solution by the use of phosphorous acid and/or its salts or sodium hypophosphite and by neutralisation during the polymerisation of the ethylenically unsaturated monomers by the continuous addition, first of all, of bases such as sodium hydroxide, potassium hydroxide or lithium hydroxide and then bases of alkaline earths such as calcium hydroxide, magnesium hydroxide, calcium oxide or magnesium oxide. The polymers obtained by the said method and uses thereof.
摘要翻译： 通过使用亚磷酸和/或其盐或次磷酸钠在水溶液中获得均聚物和/或共聚物的方法，并且通过连续添加在烯属不饱和单体的聚合过程中的中和，首先是碱例如 氢氧化钠，氢氧化钾或氢氧化锂，然后是碱土金属如氢氧化钙，氢氧化镁，氧化钙或氧化镁的碱。 通过所述方法获得的聚合物及其用途。
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8.发明授权Water-retaining and optical-brightner-activating polymer composition, paper coating colors and sheets of coated paper thus obtained 失效保水和光亮剂活化聚合物组合物，由此得到的纸涂层颜色和涂布纸片公开(公告)号：US06297317B1
公开(公告)日：2001-10-02
申请号：US09438045
申请日：1999-11-10
IPC分类号： C08L2904
CPC分类号： D21H19/60 , D21H19/58 , Y10T428/31591 , Y10T428/31895
摘要： A stable aqueous liquid polymer composition, which comprises: (i) at least one polyvinyl alcohol (PVA) which has an Ostwald viscosity less than 5 mPa·s corresponding to a degree of polymerization less than 600 and a molar percentage of hydrolysis ranging from 70 to 100 measured from the ester value (DIN 53401), corresponding to a molar percentage of vinyl acetate units from 30 to 0, and (ii) at least one water-soluble polymer at neutral or alkaline pH, the composition controlling the activation of optical brighteners, water retention and viscosities of paper coating colors.
摘要翻译： 一种稳定的水性液体聚合物组合物，其包含：（i）至少一种聚乙烯醇（PVA），其具有小于5mPa.s的Ostwald粘度，其对应于小于600的聚合度，水解的摩尔百分比为70 至100，根据酯值（DIN 53401）测量，对应于乙酸乙烯酯单元的摩尔百分数为30至0，和（ii）至少一种中性或碱性pH下的水溶性聚合物，控制光学活化的组成 增白剂，保水性和纸涂层颜色的粘度。
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公开(公告)号：US5736601A
公开(公告)日：1998-04-07
申请号：US637301
申请日：1996-04-24
CPC分类号： C08K9/08 , C09C1/021 , C09C3/041 , C09D17/004 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/22
摘要： A grinding agent containing polymers and/or copolymers partially neutralized by magnesium, for aqueous suspensions of mineral substances to be used in pigmentary applications is disclosed. A grinding agent composed of polymers and/or copolymers having a specific viscosity of between 0.3 and 0.8 and obtained by treatment, using one or several solvents, of a polymer and/or copolymer resulting from polymerization and/or copolymerization of acrylic and/or vinyl monomers comprising acid groups whose active acid sites are partially or completely neutralized to a degree of neutralization of 40 to 60%, including terminals, of the active acid sites using a neutralizing agent containing magnesium ions, and a degree of neutralization reaching 60% using a neutralizing agent containing sodium ions is disclosed. A procedure for grinding in an aqueous suspension using said agent, as well as aqueous suspensions produced using said procedure and their applications to the fields of weight fillers, paper coating, paints, and plastics is also disclosed.
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10.发明授权Acrylic copolymer which is water-soluble or moderately water-soluble and may be crosslinked; and its use 失效丙烯酸共聚物，其为水溶性或中等水溶性且可交联; 及其用途
公开(公告)号：US5294693A
公开(公告)日：1994-03-15
申请号：US083257
申请日：1993-06-29
IPC分类号： A61K8/81 , A61Q5/02 , A61Q19/00 , C08F220/04 , C08F220/14 , C08F220/28 , C09D7/00 , C09D17/00 , C09K8/24 , C09K8/88 , C11D3/12 , C11D3/37 , D06P1/52 , D06P1/613 , C08F20/26
CPC分类号： C08F220/18 , A61K8/8152 , A61Q19/00 , A61Q5/02 , C08F220/04 , C08F220/06 , C08F220/14 , C08F220/28 , C08F290/062 , C09D17/00 , C09D7/002 , C09K8/24 , C09K8/885 , C11D3/1286 , C11D3/3726 , C11D3/3765 , C11D3/3773 , C11D3/3776 , D06P1/525 , D06P1/5257 , D06P1/6136 , A61K2800/548 , C08F222/20 , C08F2220/1808 , C08L33/02 , C08L33/08 , C08L33/10
摘要： A copolymer comprised of at least one monomer having ethylenic unsaturation and a carboxylic acid group, optionally at least one monomer having ethylenic unsaturation and not having a carboxylic acid group, at least one oxyalkylated monomer having ethylenic unsaturation and terminated by a fatty hydrophobic chain having at least 26 C atoms, and optionally at least one monomer having at least two sites of ethylenic unsaturation. The copolymer is employed as a modifier of rheological properties, stabilizing agent, and/or an antisedimentation or suspension agent for coarse mineral or organic materials, in applications such as drilling muds, textile printing pies, cosmetics, detergents, plant protection, and paints and coatings.
摘要翻译： 由至少一种具有烯属不饱和单体和羧酸基团的单体组成的共聚物，任选至少一种具有烯属不饱和基团且不具有羧酸基团的单体，至少一种具有烯键式不饱和键和通过脂肪疏水链终止的烷氧基化单体， 至少26个C原子，以及任选的至少一种具有至少两个烯属不饱和位点的单体。 该共聚物用作流变性质的稳定剂，和/或用于粗矿物或有机材料的抗沉降或悬浮剂的改性剂，例如钻井泥浆，纺织品印刷馅饼，化妆品，洗涤剂，植物保护剂和油漆，以及 涂料。
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