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公开(公告)号：US08932453B2
公开(公告)日：2015-01-13
申请号：US13150863
申请日：2011-06-01
CPC分类号： B01J38/04 , B01J23/96 , C10G3/45 , C10G3/46 , C10G3/47 , C10G3/50 , C10G45/08 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/104 , C10G2300/1044 , C10G2300/1051 , C10G2300/1055 , C10G2300/1059 , C10G2300/202 , C10G2300/703 , Y02P30/20
摘要： This invention relates to a hydroprocessing process with improved catalyst activity when hydroprocessing petroleum based feedstock or an oxygen containing feedstock. This invention also relates to a hydrotreating process with improved hydrodesulfurization (HDS) activity of a hydrotreating catalyst such as Co/Mo by co-feeding carbon monoxide or its precursors. Such inventive process confirms that adding a small amount of CO to H2 in a hydrotreater for a few days leads to an increase in product sulfur due to the inhibition of CO on the hydrotreating catalyst such as Co/Mo. However, it has been unexpectedly found that after the CO was removed from the hydrogen stream, product sulfur levels decreased to values below they were before CO addition which means the activity of the hydrotreating catalyst increased after the CO treatment.
摘要翻译： 本发明涉及当加氢处理基于石油的原料或含氧原料时具有改进的催化剂活性的加氢处理方法。 本发明还涉及通过共同进料一氧化碳或其前体的加氢处理催化剂例如Co / Mo的加氢脱硫（HDS）活性的加氢处理方法。 这样的发明方法证实，在加氢处理机中加入少量的CO至H 2几天导致产物硫的增加，这是由于在加氢处理催化剂如Co / Mo上的CO的抑制。 然而，已经意外地发现，在从氢气流中除去CO之后，产物硫含量降低到低于在CO加入之前的值，这意味着加氢处理催化剂的活性在CO处理后增加。
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公开(公告)号：US09371256B2
公开(公告)日：2016-06-21
申请号：US14230835
申请日：2014-03-31
IPC分类号： C07C1/20 , C07C1/22 , C07C5/02 , C10L1/08 , C10G3/00 , C10G45/02 , C10G69/06 , C10G9/00 , C07C1/00 , C07C1/06 , C07C1/213
CPC分类号： C07C1/22 , C07C5/02 , C10G3/42 , C10G3/46 , C10G3/50 , C10G9/00 , C10G45/02 , C10G69/06 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/301 , C10G2400/04 , C10L1/08 , Y02E50/13 , Y02P30/20
摘要： A heated petroleum-derived hydrocarbon is contacted with a triglyceride feed in a thermal cracking zone to decompose and remove impurities prior to hydrotreating the mixture to fuel range hydrocarbon. This process allows the use of a variety of low cost triglyceride feeds while reducing fouling of process equipment and catalyst. The process also reduces the use of chemicals required for conventional degumming of triglyceride feeds.
摘要翻译： 将加热的石油衍生的烃与热裂解区中的甘油三酯进料接触以在将混合物加氢处理至燃料范围的烃之前分解和除去杂质。 该方法允许使用各种低成本甘油三酯饲料，同时减少工艺设备和催化剂的结垢。 该方法还减少了甘油三酯饲料常规脱胶所需的化学品的使用。
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3.发明申请HYDROTREATING AND CATALYTIC DEWAXING PROCESS FOR MAKING DIESEL FROM OILS AND/OR FATS 有权用于从油和/或脂肪制造柴油的加氢和催化脱蜡方法公开(公告)号：US20090019763A1
公开(公告)日：2009-01-22
申请号：US11778295
申请日：2007-07-16
IPC分类号： C10L1/16
CPC分类号： C10G45/64 , C10G3/46 , C10G3/49 , C10G2300/1014 , C10G2300/1018 , C10G2300/1048 , C10G2300/107 , C10G2300/304 , C10G2300/4018 , C10G2300/802 , C10G2400/04 , Y02P30/20
摘要： Methods for producing C10-C30 hydrocarbons from fatty materials, such as triglyceride compounds, are provided. Hydrocarbon compounds, particularly those boiling in the temperature range of between about 80° F. to about 1000° F., are produced by contacting a fatty material with at least one catalyst comprising cobalt and molybdenum on a zeolite support under hydrotreating conditions. Additional hydrotreating catalysts may also be used to further improve the properties of the hydrocarbon product.
摘要翻译： 提供了从脂肪材料如甘油三酯化合物制备C10-C30烃的方法。 通过在加氢处理条件下使脂肪材料与至少一种包含钴和钼的催化剂在沸石载体上接触来制备烃化合物，特别是在约80°F至约1000°F温度范围内沸腾的烃化合物。 另外的加氢处理催化剂也可用于进一步改进烃产物的性质。
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公开(公告)号：US20110126449A1
公开(公告)日：2011-06-02
申请号：US12915502
申请日：2010-10-29
申请人： Xiaochun XU , Yun BAO , Jianhua Yao , Dhananjay B. Ghonasgi , Edward L. SUGHRUE, II , Lisa L. MYERS
发明人： Xiaochun XU , Yun BAO , Jianhua Yao , Dhananjay B. Ghonasgi , Edward L. SUGHRUE, II , Lisa L. MYERS
CPC分类号： C10L10/14 , C10G3/42 , C10G3/50 , C10G2300/1014 , C10G2300/1018 , C10G2300/1022 , C10G2300/1051 , C10G2300/1055 , C10G2300/301 , C10G2300/304 , C10G2400/04 , C10L1/04 , C10L1/08 , C10L1/1616 , C10L1/18 , C10L1/1802 , C10L1/1822 , C10L1/19 , C10L1/191 , C10L2200/043 , C10L2200/0438 , C10L2200/0446 , C10L2200/0469 , C10L2200/0476 , C10L2200/0484 , C10L2200/0492 , Y02E50/13 , Y02P30/20
摘要： There is provided a fuel composition comprising petroleum based component and a renewable based component, wherein at least 20% of the compounds in said petroleum based component having boiling point range equal or greater than the boiling point of said renewable based component.
摘要翻译： 提供了一种包含石油基组分和可再生基组分的燃料组合物，其中所述石油基组分中的至少20％的化合物的沸点范围等于或大于所述可再生基组分的沸点。
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公开(公告)号：US20090266743A1
公开(公告)日：2009-10-29
申请号：US12109766
申请日：2008-04-25
IPC分类号： C10G45/34
CPC分类号： C10L1/08 , C10G3/46 , C10G3/50 , C10G31/06 , C10G45/02 , C10G67/02 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2400/04 , Y02E50/13 , Y02P30/20
摘要： A triglyceride or a triglyceride/hydrocarbon combination can be heated to produce thermally treated feeds. The thermally treated feeds can then be contacted with a hydrotreating catalyst in a reaction zone.
摘要翻译： 可以加热甘油三酯或甘油三酯/烃组合以产生热处理的进料。 然后可以将经热处理的进料与反应区中的加氢处理催化剂接触。
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公开(公告)号：US20120157742A1
公开(公告)日：2012-06-21
申请号：US13332000
申请日：2011-12-20
申请人： Yun Bao , Dhananjay B. Ghonasgi , Joseph E. Bares , Sundararajan Uppili , Jianhua Yao , Xiaochun Xu , Edward L. Sughrue , Lisa L. Myers
发明人： Yun Bao , Dhananjay B. Ghonasgi , Joseph E. Bares , Sundararajan Uppili , Jianhua Yao , Xiaochun Xu , Edward L. Sughrue , Lisa L. Myers
IPC分类号： C07C7/148
CPC分类号： C10G45/08 , C10G3/46 , C10G3/50 , C10G2300/1011 , C10G2300/1014 , C10G2300/202 , C10G2300/4006 , C10G2400/04 , Y02P30/20
摘要： The present disclosure relates to a process for the conversion of oxygen-containing hydrocarbons into long-chain hydrocarbons suitable for use as a fuel. These hydrocarbons may be derived from biomass, and may optionally be mixed with petroleum-derived hydrocarbons prior to conversion. The process utilizes a catalyst comprising Ni and Mo to convert a mixture comprising oxygenated hydrocarbons into product hydrocarbons containing from ten to thirty carbons. Hydro-conversion can be performed at a significantly lower temperature than is required for when utilizing a hydrotreating catalyst comprising Co and Mo (CoMo), while still effectively removing sulfur compounds (via hydrodesulfurization) to a level of 10 ppm (by weight) or less.
摘要翻译： 本公开涉及将含氧烃转化为适合用作燃料的长链烃的方法。 这些烃可以衍生自生物质，并且可以任选地在转化之前与石油衍生的烃混合。 该方法利用包含Ni和Mo的催化剂将含有氧化烃的混合物转化为含有10至30个碳的产物烃。 可以在比使用包含Co和Mo（CoMo）的加氢处理催化剂所需的温度低得多的温度下进行水力转化，同时仍然有效地将硫化合物（通过加氢脱硫）除去至10ppm（重量）以下的水平 。
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公开(公告)号：US08017819B2
公开(公告)日：2011-09-13
申请号：US12109766
申请日：2008-04-25
IPC分类号： C10G45/34
CPC分类号： C10L1/08 , C10G3/46 , C10G3/50 , C10G31/06 , C10G45/02 , C10G67/02 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2400/04 , Y02E50/13 , Y02P30/20
摘要： A triglyceride or a triglyceride/hydrocarbon combination can be heated to produce thermally treated feeds. The thermally treated feeds can then be contacted with a hydrotreating catalyst in a reaction zone.
摘要翻译： 可以加热甘油三酯或甘油三酯/烃组合以产生热处理的进料。 然后可以将经热处理的进料与反应区中的加氢处理催化剂接触。
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公开(公告)号：US07626063B2
公开(公告)日：2009-12-01
申请号：US11747380
申请日：2007-05-11
IPC分类号： C07C5/02
CPC分类号： C10G3/52 , C10G3/46 , C10G3/49 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , Y02P30/20
摘要： Methods for producing C10-C30 hydrocarbons from fatty compounds are provided in which at least a portion of the hydrogen required to accomplish the conversion is generated from by-products of the conversion process. Light hydrocarbons, especially propane, produced during the conversion of triglyceride compounds are used to generate hydrogen which is used in the conversion process thereby reducing the need for outside hydrogen sources.
摘要翻译： 提供从脂肪族化合物制备C10-C30烃的方法，其中由转化过程的副产物产生完成转化所需的至少一部分氢。 在甘油三酸酯化合物转化过程中产生的轻质烃，特别是丙烷用于产生用于转化过程中的氢气，从而减少对外部氢源的需求。
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公开(公告)号：US20080281134A1
公开(公告)日：2008-11-13
申请号：US11747380
申请日：2007-05-11
IPC分类号： C10G3/00
CPC分类号： C10G3/52 , C10G3/46 , C10G3/49 , C10G2300/1014 , C10G2300/1018 , C10G2300/1037 , Y02P30/20
摘要： Methods for producing C10-C30 hydrocarbons from fatty compounds are provided in which at least a portion of the hydrogen required to accomplish the conversion is generated from by-products of the conversion process. Light hydrocarbons, especially propane, produced during the conversion of triglyceride compounds are used to generate hydrogen which is used in the conversion process thereby reducing the need for outside hydrogen sources.
摘要翻译： 提供从脂肪族化合物制备C10-C30烃的方法，其中由转化过程的副产物产生完成转化所需的至少一部分氢。 在甘油三酸酯化合物转化过程中产生的轻质烃，特别是丙烷用于产生用于转化过程中的氢气，从而减少对外部氢源的需求。
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公开(公告)号：US07678950B2
公开(公告)日：2010-03-16
申请号：US11303636
申请日：2005-12-16
申请人： Jianhua Yao , Edward L. Sughrue, II , James B. Kimble , Joseph B. Cross , Marvin M. Johnson , Dhananjay B. Ghonasgi
发明人： Jianhua Yao , Edward L. Sughrue, II , James B. Kimble , Joseph B. Cross , Marvin M. Johnson , Dhananjay B. Ghonasgi
IPC分类号： C07C1/00
CPC分类号： C07C51/377 , C08B30/12 , C10G3/45 , C10G3/47 , C10G3/49 , C10G3/50 , C10G2300/1014 , C10G2300/805 , C10G2400/02 , Y02P30/20 , C07C59/08
摘要： Processes for the conversion of carbohydrates to gasoline boiling range hydrocarbons, and processes for increasing the solubility of carbohydrates used in such processes are disclosed. The solubility of carbohydrates may be increased by contacting the carbohydrate with an ion-exchange resin. The dissolved product may be hydrogenated and reacted in the present of a catalyst to form a reaction product containing non-aromatic and aromatic gasoline boiling range hydrocarbons.
摘要翻译： 公开了将碳水化合物转化为汽油沸程烃的方法，以及用于增加在这些方法中使用的碳水化合物的溶解度的方法。 通过使碳水化合物与离子交换树脂接触可以提高碳水化合物的溶解度。 溶解的产物可以在催化剂的存在下氢化和反应，以形成含有非芳族和芳族汽油沸程烃的反应产物。
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