摘要:
Zeolite EU-2 having a molar composition expressed by the formula: 0.5 to 1.5 R.sub.2 O: Y.sub.2 O.sub.3 : at least 70 XO.sub.2 : 0 to 100 H.sub.2 O wherein R is a monovalent cation or .sup.1 /n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, or boron, and H.sub.2 O is water of hydration additional to water notionally present where R is H, and having an X-ray pattern substantially as set out in Table 1 is prepared from a reaction mixture containing XO.sub.2 (preferably silica), Y.sub.2 O.sub.3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The zeolite is useful in catalytic processes, especially for the conversion of methanol to hydrocarbons.
摘要:
Zeolite EU-2 having a molar composition expressed by the formula:0.5 to 1.5 R.sub.2 O:Y.sub.2 O.sub.3 : at least 70 XO.sub.2 :0 to 100 H.sub.2 Owherein R is a monovalent cation or 1/n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having an X-ray pattern substantially as set out in Table 1 is prepared from a reaction mixture containing XO.sub.2 (preferably silica), Y.sub.2 O.sub.3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The zeolite is useful in catalytic processes, especially for the conversion of methanol to hydrocarbons.
摘要翻译:具有由下式表示的摩尔组成的沸石EU-2:R 2 O:Y 2 O 3:至少70XO 2:0至100H 2 O其中R是一价阳离子或1价n价阳离子,X是硅和 /或锗,Y是铝,铁,镓或硼中的一种或多种,并且当R是H时,H 2 O是额外的水的水合水,并且具有基本上如表1所示的X射线图案 来自含有XO 2(优选二氧化硅),Y 2 O 3(优选氧化铝)和阳离子烷基化聚亚甲基二胺的反应混合物。 沸石可用于催化过程,特别是用于将甲醇转化为烃。
摘要:
Zeolite EU-2 having a molar composition expressed by the formula: 0.5 to 1.5 R.sub.2 O:Y.sub.2 O.sub.3 : at least 70 XO.sub.2 :0 to 100 H.sub.2 O wherein R is a monovalent cation or .sup.1 /n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having an X-ray pattern substantially as set out in Table 1 is prepared from a reaction mixture containing XO.sub.2 (preferably silica), Y.sub.2 O.sub.3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The zeolite is useful in catalytic processes, especially for the conversion of methanol to hydrocarbons.
摘要翻译:具有由下式表示的摩尔组成的沸石EU-2:R 2 O:Y 2 O 3:至少70XO 2:0至100H 2 O其中R是一价阳离子或1价n价阳离子,X是硅和 /或锗,Y是铝,铁,镓或硼中的一种或多种,并且当R是H时,H 2 O是额外的水的水合水,并且具有基本上如表1所示的X射线图案 来自含有XO 2(优选二氧化硅),Y 2 O 3(优选氧化铝)和阳离子烷基化聚亚甲基二胺的反应混合物。 沸石可用于催化过程,特别是用于将甲醇转化为烃。
摘要:
Zeolite EU-2 having a molar composition expressed by the formula:0.5 to 1.5 R.sub.2 O: Y.sub.2 O.sub.3 : at least 70 XO.sub.2 : 0 to 100 H.sub.2 Owherein R is a monovalent cation or 1/n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having an X-ray pattern substantially as set out in Table 1 is prepared from a reaction mixture containing XO.sub.2 (preferably silica), Y.sub.2 O.sub.3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The zeolite is useful in catalytic processes, especially for the conversion of methanol to hydrocarbons.
摘要翻译:具有由下式表示的摩尔组成的沸石EU-2:R 2 O:Y 2 O 3:至少70XO 2:0至100H 2 O其中R是一价阳离子或1价n价阳离子,X是硅和 /或锗,Y是铝,铁,镓或硼中的一种或多种,并且当R是H时,H 2 O是额外的水的水合水,并且具有基本上如表1所示的X射线图案 来自含有XO 2(优选二氧化硅),Y 2 O 3(优选氧化铝)和阳离子烷基化聚亚甲基二胺的反应混合物。 沸石可用于催化过程,特别是用于将甲醇转化为烃。
摘要:
A synthetic zeolite material, designated zeolite EU-4, having a molar composition expressed by the formula:O to M.sub.2 O:aY.sub.2 O.sub.3 :at least 100 XO.sub.2 :0 to 35 H.sub.2 Owherein M is a monovalent cation or 1/n of a cation of valency n, a is from 0 to 9, X is silicon and/or germanium, Y is one or more of aluminum, iron, chromium, vanadium, molybdenum, arsenic, antimony, manganese, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when M is H, and having a defined X-ray diffraction pattern is prepared from an aqueous reaction mixture containing the oxide XO.sub.2, optionally the oxide Y.sub.2 O.sub.3 and an alkyltrimethylammonium or dialkyldimethylammonium compound.Zeolite EU-4 is a useful catalyst for methanol conversion and the like.
摘要翻译:具有由下式表示的摩尔组成的合成沸石材料EU-4:O至M 2 O:aY 2 O 3:至少100XO 2:0至35H 2 O,其中M是一价阳离子或1 / n的化合物阳离子 n,a为0至9,X为硅和/或锗,Y为铝,铁,铬,钒,钼,砷,锑,锰,镓或硼中的一种或多种,H 2 O为水合水 当M为H时,以含有氧化物XO2,任选的氧化物Y 2 O 3和烷基三甲基铵或二烷基二甲基铵化合物的水性反应混合物制备具有规定的X射线衍射图样的水。 沸石EU-4是甲醇转化等的有用催化剂。
摘要:
A new zeolite material designated EU-1 having a molar composition expressed by the formula:0.5 to 1.5 R.sub.2 O : Y.sub.2 O.sub.3 : at least 10 XO.sub.2 : O to 100 H.sub.2 O wherein R is a monovalent cation or 1/n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminium, iron, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having an X-ray pattern substantially as set out in Tables 1 and 2 is prepared from a reaction mixture containing XO.sub.2 (preferably silica), Y.sub.2 O.sub.3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The new zeolite is useful in catalytic processes, especially xylenes isomerisation.
摘要:
A new zeolite material designated EU-1 having a molar composition expressed by the formula:0.5 to 1.5 R.sub.2 O:Y.sub.2 O.sub.3 : at least 10 XO.sub.2 :0 to 100 H.sub.2 Owherein R is a monovalent cation or .sup.1 /n of a cation of valency n, X is silicon and/or germanium, Y is one or more of aluminum, iron, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having an X-ray pattern substantially as set out in Tables 1 and 2 is prepared from a reaction mixture containing XO.sub.2 (preferably silica), Y.sub.2 O.sub.3 (preferably alumina) and a dicationic alkylated polymethylene diamine. The new zeolite is useful in catalytic processes, especially xylenes isomerization.
摘要翻译:名称为EU-1的新型沸石材料,其具有由下式表示的摩尔组成:0.5至1.5 R 2 O:Y 2 O 3:至少10XO 2:0至100H 2 O,其中R是一价阳离子或1 / n的化合价n的阳离子, X是硅和/或锗,Y是铝,铁,镓或硼中的一种或多种,并且当R是H时,H 2 O是额外地存在的水的水合水,并且具有基本上如 表1和表2由含有XO 2(优选二氧化硅),Y 2 O 3(优选氧化铝)和阳离子烷基化聚亚甲基二胺的反应混合物制备。 新的沸石可用于催化过程,特别是二甲苯异构化。
摘要:
A zeolite, designated NU-85, is an intergrowth of zeolites EU-1 and NU-87. The zeolite is a useful catalyst in a wide variety of hydrocarbon conversion reactions including isomerisation and alkylation.
摘要:
A catalyst washcoat is provided having a molecular sieve with a CHA crystal structure; about 0.5 to about 5.0 mol % phosphorus; and SiO2 and Al2O3 in a mole ratio of about 5 to about 40. The washcoat includes one or more promoters or stabilizers, and may be applied to a monolith substrate to produce a catalytically active article.
摘要:
A method of preparing a catalyst support is described comprising washing a precipitated metal oxide material with water and/or an aqueous solution of acid and/or base such that contaminant levels in said precipitated metal oxide are reduced. The method may be applied to precipitated alumina materials to reduce contaminants selected from sulphur, chlorine, Group 1A and Group 2A metals. The catalyst supports may be used to prepare catalysts for the Fischer-Tropsch synthesis of hydrocarbons.