Li ion conductor and process for producing same

    公开(公告)号:US11649172B2

    公开(公告)日:2023-05-16

    申请号:US17886011

    申请日:2022-08-11

    Inventor: Kazuaki Kanai

    Abstract: A Li ion conductor having a composition different from a conventional composition is provided. The Li ion conductor contains at least one selected from a group Q consisting of Ga, V, and Al, Li, La and O. A part of an Li site is optionally substituted with a metal element D, a part of an La site is optionally substituted with a metal element E, and parts of Ga, V and Al sites are optionally substituted with a metal element J. A mole ratio of an amount of Li to a total amount of La, the element E, Ga, V, Al, and the element J is not lower than 8.1/5 and not higher than 9.5/5. A mole ratio of a total amount of Ga, V, and Al to a total amount of La and the element E is not lower than 1.1/3 and not higher than 2/3.

    GARNET-TYPE COMPOSITE METAL OXIDE AND METHOD FOR PRODUCING SAME

    公开(公告)号:US20210151793A1

    公开(公告)日:2021-05-20

    申请号:US17163804

    申请日:2021-02-01

    Abstract: One or more embodiments of the present invention are to provide a method for producing a composite metal oxide having an excellent crystallinity by a mechanochemical method. One or more embodiments of the present invention relate to a method for producing a garnet-type composite metal oxide containing Li, La, Zr and O. The method includes a step of treating a mixture containing raw material powders and a flux by a mechanochemical method to react the raw material powders, and the raw material powders contain a Li source powder, a La source powder and a Zr source powder. The raw material powders may further contain at least one selected from an Al source powder and a Ga source powder.

    SOLID ELECTROLYTE
    4.
    发明申请

    公开(公告)号:US20220376294A1

    公开(公告)日:2022-11-24

    申请号:US17880195

    申请日:2022-08-03

    Abstract: A solid electrolyte which contains a garnet-type composite metal oxide phase (L) and shows an excellent lithium ion conductivity is provided. The solid electrolyte contains a garnet-type composite metal oxide phase (L) and a phase (D) different from the phase (L). The phase (L) contains Li, La, Zr, O, and Ga, and an Li site in the phase (L) is substituted with the Ga. A lattice constant of the solid electrolyte is not smaller than 12.96 Å. The phase (D) contains at least one of LiF, BaZrO3, YF3, SrF2, and ScF3.

    Oxide, solid electrolyte and all-solid-state lithium ion secondary battery

    公开(公告)号:US12249686B2

    公开(公告)日:2025-03-11

    申请号:US17703087

    申请日:2022-03-24

    Abstract: An LLZ oxide may be a garnet-type oxide that contains Li, La, Zr and O as main constituent elements, and further contains substituent elements such as Zn in addition to the main constituent elements. The substituent elements may contain Bi, Nb, Hf and the like in addition to Zn. The LLZ-type oxide may be used, for example, as a solid electrolyte for an all-solid-state lithium ion secondary battery. The all-solid-state lithium ion secondary battery includes a positive electrode, a negative electrode, and a solid electrolyte layer that is disposed between the positive electrode and the negative electrode.

    LITHIUM ION-CONDUCTING GARNET TYPE OXIDE

    公开(公告)号:US20230064947A1

    公开(公告)日:2023-03-02

    申请号:US18047277

    申请日:2022-10-18

    Inventor: Kazuaki Kanai

    Abstract: An oxide-based solid electrolyte with a high lithium ion conductance is provided. A lithium ion-conducting garnet type oxide includes Li, La, Ga, Zr, a halogen element, and oxygen. A lithium ion conductivity at room temperature is not lower than 1.0×10−3 S/cm. A proportion of Ga with respect to 1 mole of the oxide may be not larger than 0.5 moles.
    The halogen element may be at least one type selected from the group consisting of Cl, Br, and I, and a proportion of Li with respect to 1 mole of the oxide may be not smaller than 6.1 moles and smaller than 6.5 moles.

    LI ION CONDUCTOR AND PROCESS FOR PRODUCING SAME

    公开(公告)号:US20220388859A1

    公开(公告)日:2022-12-08

    申请号:US17886011

    申请日:2022-08-11

    Inventor: Kazuaki Kanai

    Abstract: A Li ion conductor having a composition different from a conventional composition is provided. The Li ion conductor contains at least one selected from a group Q consisting of Ga, V, and Al, Li, La and O. A part of an Li site is optionally substituted with a metal element D, a part of an La site is optionally substituted with a metal element E, and parts of Ga, V and Al sites are optionally substituted with a metal element J. A mole ratio of an amount of Li to a total amount of La, the element E, Ga, V, Al, and the element J is not lower than 8.1/5 and not higher than 9.5/5. A mole ratio of a total amount of Ga, V, and Al to a total amount of La and the element E is not lower than 1.1/3 and not higher than 2/3.

    LI ION CONDUCTOR AND METHOD FOR PRODUCING SAME

    公开(公告)号:US20220359098A1

    公开(公告)日:2022-11-10

    申请号:US17686782

    申请日:2022-03-04

    Abstract: A Li ion conductor includes a garnet-type composite metal oxide phase (L) containing Li, La, Zr, and O. The Li ion conductor has a diffraction peak at least one of at 2θ=13.8° ±1° and at 2θ=15.2° ±1° in X-ray diffraction measurement using CuKa rays. The Li ion conductor may have a metal-containing phase (K) different from the garnet-type composite metal oxide phase (L), and the metal-containing phase (K) contains a halogen element and Li.

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